ORGANIC CHEMISTRY-PACKAGE >CUSTOM<
ORGANIC CHEMISTRY-PACKAGE >CUSTOM<
10th Edition
ISBN: 9781260028355
Author: Carey
Publisher: MCG CUSTOM
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Chapter 23.4, Problem 3P
Interpretation Introduction

Interpretation:

The method for the separation of a mixture of phenol and benzoic acid present in diethyl ether solution is to be stated and also the method of separation of a mixture of phenol and cyclohexanol present in diethyl ether solutionis to be stated on the basis of their large difference in pKa values.

Concept Introduction:

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The acidity of phenols is higher than that of alcohols. But phenols are less acidic than a carboxylic acid.

>

The pKa value of carboxylic acid is approximately 5.

>

The range for the pKa values of alcohols is 1620.

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