ORGANIC CHEMISTRY-PACKAGE >CUSTOM<
ORGANIC CHEMISTRY-PACKAGE >CUSTOM<
10th Edition
ISBN: 9781260028355
Author: Carey
Publisher: MCG CUSTOM
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Chapter 23, Problem 36DSP
Interpretation Introduction

Interpretation:

The major product of the methylation of 2-methoxy benzoic acid isto be determined.

Concept Introduction:

Substitutents attached to an aromatic ring promote metalation andcontrol its regioselectivity.

Lithiation usually occurs at the carbon atom ortho to the substituent.

These ortho-lithiated derivatives undergo the normal reactions similar to organolithium reagents.

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sketch the nature of the metal-alkylidene bonding interactions.
Part C The perspective formula of isoleucine, an amino acid, is provided below. HOOC H₂NIC H 川 CH3 CH,CH3 Draw the Newman projection in staggered conformation for isoleucine by viewing the molecule along the C-2-C-3 bond. 1. Edit the Newman projection on the canvas. 2. Replace the appropriate hydrogens with the appropriate -CH3 or other groups. 3. If you need to start over, Undo or choose a Newman projection from the Templates toolbar (bottom). Important: Never delete the hydrogen atoms or bonds directly attached to the template, and do not move them by dragging or dropping them. That will break the projections structures. Only replace them! ▸ View Available Hint(s) 0 2 H± 3D EXP. L ד י CONT. 2 H 0 N о
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