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Chemistry
13th Edition
ISBN: 9781259911156
Author: Raymond Chang Dr., Jason Overby Professor
Publisher: McGraw-Hill Education
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Question
Chapter 23.4, Problem 1RCF
Interpretation Introduction
Interpretation:
The number of possible geometric isomers of the given complex compound has to be found.
Concept Introduction:
Isomers:
In general, isomers are compounds with the same molecular formula but with different structural forms.
Geometric isomers:
- Geometric isomers are type stereoisomers which have different spatial arrangements with the same structural formula.
- The geometric isomers can also be defined as the compounds that cannot be interconverted without breaking a
chemical bond . - Geometric isomers exist in pairs such as cis- and trans- isomers.
- Cis- isomer is the compound in which same type of atoms or groups lie on the same side.
- Trans- isomer is the compound in which same type of atoms or groups lie on the opposite sides.
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Students have asked these similar questions
Part I.
a) Elucidate
the structure of compound A using the following information.
• mass spectrum: m+ = 102, m/2=57
312=29
• IR spectrum:
1002.5
% TRANSMITTANCE
Ngg
50
40
30
20
90
80
70
60
MICRONS
5
8
9 10
12
13
14 15 16
19
1740 cm
M
10
0
4000
3600
3200
2800
2400
2000
1800
1600
13
• CNMR
'H
-NMR
Peak
8
ppm (H)
Integration
multiplicity
a
1.5 (3H)
triplet
b
1.3
1.5 (3H)
triplet
C
2.3
1 (2H)
quartet
d
4.1
1 (2H)
quartet
& ppm (c)
10
15
28
60
177 (C=0)
b) Elucidate the structure of compound B using the following information
13C/DEPT NMR 150.9 MHz
IIL
1400
WAVENUMBERS (CM-1)
DEPT-90
DEPT-135
85 80 75
70
65
60
55
50
45 40
35
30 25 20
ppm
1200
1000
800
600
400
•
Part II.
a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below:
• IR spectra
% TRANSMITTANCE
1002.5
90
80
70
60
50
40
30
20
10
0
4000
3600
3200
2800
2400
2000
1800
1600
• Information from 'HAMR
MICRONS
8 9 10
11
14 15 16
19
25
1400
WAVENUMBERS (CM-1)
1200
1000
800
600
400
peak
8 ppm
Integration
multiplicity
a
2.1
1.5 (3H)
Singlet
b
3.6
1 (2H)
singlet
с
3.8
1.5 (3H)
Singlet
d
6.8
1(2H)
doublet
7.1
1(2H)
doublet
Information from 13C-nmR
Normal carbon
29ppm
Dept 135
Dept -90
+
NO peak
NO peak
50 ppm
55 ppm
+
NO peak
114 ppm
t
126 ppm
No peak
NO peak
130 ppm
t
+
159 ppm
No peak
NO peak
207 ppm
по реак
NO peak
Could you redraw these and also explain how to solve them for me pleas
Chapter 23 Solutions
Chemistry
Ch. 23.1 - Identify the following transition metal atoms and...Ch. 23.3 - Write the oxidation numbers of the metals in the...Ch. 23.3 - Prob. 2PECh. 23.3 - Prob. 3PECh. 23.3 - Prob. 1RCFCh. 23.3 - What is the difference between these two...Ch. 23.3 - Prob. 3RCFCh. 23.4 - Prob. 1RCFCh. 23.5 - Prob. 4PECh. 23.5 - Prob. 1RCF
Ch. 23.5 - Determine the number of unpaired electrons in the...Ch. 23 - What distinguishes a transition metal from a...Ch. 23 - Why is zinc not considered a transition metal?Ch. 23 - Explain why atomic radii decrease very gradually...Ch. 23 - Without referring to the text, write the...Ch. 23 - Write the electron configurations of the following...Ch. 23 - Why do transition metals have more oxidation...Ch. 23 - Prob. 23.7QPCh. 23 - Prob. 23.8QPCh. 23 - Define the following terms: coordination compound,...Ch. 23 - Describe the interaction between a donor atom and...Ch. 23 - Prob. 23.11QPCh. 23 - Prob. 23.12QPCh. 23 - Prob. 23.13QPCh. 23 - Prob. 23.14QPCh. 23 - Prob. 23.15QPCh. 23 - What are the systematic names for the following...Ch. 23 - Prob. 23.17QPCh. 23 - Prob. 23.18QPCh. 23 - Define the following terms: stereoisomers,...Ch. 23 - Prob. 23.20QPCh. 23 - Prob. 23.21QPCh. 23 - Prob. 23.22QPCh. 23 - Prob. 23.23QPCh. 23 - Prob. 23.24QPCh. 23 - Draw structures of all the geometric and optical...Ch. 23 - Prob. 23.26QPCh. 23 - Briefly describe crystal field theory.Ch. 23 - Prob. 23.28QPCh. 23 - What is the origin of color in a coordination...Ch. 23 - Prob. 23.30QPCh. 23 - Prob. 23.31QPCh. 23 - Prob. 23.32QPCh. 23 - Prob. 23.33QPCh. 23 - Prob. 23.34QPCh. 23 - Prob. 23.35QPCh. 23 - The absorption maximum for the complex ion...Ch. 23 - Prob. 23.37QPCh. 23 - A solution made by dissolving 0.875 g of...Ch. 23 - Prob. 23.39QPCh. 23 - Prob. 23.40QPCh. 23 - Prob. 23.41QPCh. 23 - The [Fe(CN)6]3 complex is more labile than the...Ch. 23 - Aqueous copper(II) sulfate solution is blue in...Ch. 23 - When aqueous potassium cyanide is added to a...Ch. 23 - A concentrated aqueous copper(II) chloride...Ch. 23 - Prob. 23.46QPCh. 23 - As we read across the first-row transition metals...Ch. 23 - Prob. 23.48QPCh. 23 - Prob. 23.49QPCh. 23 - Prob. 23.50QPCh. 23 - Prob. 23.51QPCh. 23 - Chemical analysis shows that hemoglobin contains...Ch. 23 - Explain the following facts: (a) Copper and iron...Ch. 23 - A student in 1895 prepared three coordination...Ch. 23 - Prob. 23.55QPCh. 23 - From the standard reduction potentials listed in...Ch. 23 - Using the standard reduction potentials listed in...Ch. 23 - The Co2+-porphyrin complex is more stable than the...Ch. 23 - Prob. 23.59QPCh. 23 - Prob. 23.60QPCh. 23 - Hydrated Mn2+ ions are practically colorless (see...Ch. 23 - Which of the following hydrated cations are...Ch. 23 - Prob. 23.63QPCh. 23 - Prob. 23.64QPCh. 23 - Prob. 23.65QPCh. 23 - Prob. 23.66QPCh. 23 - The compound 1,1,1-trifluoroacetylacetone (tfa) is...Ch. 23 - Prob. 23.68QPCh. 23 - Prob. 23.69QPCh. 23 - Prob. 23.70QPCh. 23 - Prob. 23.71QPCh. 23 - Commercial silver-plating operations frequently...Ch. 23 - Draw qualitative diagrams for the crystal field...Ch. 23 - (a) The free Cu(I) ion is unstable in solution and...Ch. 23 - Prob. 23.75QPCh. 23 - Prob. 23.76QP
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