Organic Chemistry
Organic Chemistry
12th Edition
ISBN: 9781118875766
Author: T. W. Graham Solomons, Craig B. Fryhle, Scott A. Snyder
Publisher: WILEY
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Chapter 23, Problem 9PP
Interpretation Introduction

Interpretation:

The three-dimensional formula for androsterone and norethynodrel is to be given.

Concept Introduction:

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Androsterone, a secondary male sex hormone, is an endogenous steroid hormone. It is a weak androgen with a molecular formula of C19H30O2.

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The structure of androsterone consists of four rings, three six membered carbon rings and one five membered carbon ring. It consists of a hydroxyl group at the third carbon atom, two methyl groups at the tenth and the thirteenth carbon positions respectively, and a ketone group at the seventeenth carbon position.

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Norethynodrel is a group of synthetic steroids having functions similar to those of progesterone. These are widely used as oral contraceptives; however, now have been discontinued. Its molecular formula is C20H26O2.

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The structure of norethynodrel consists of three six membered carbon ring and one five membered carbon ring. It consists of a hydroxyl group at the third carbon atom, two methyl groups at the tenth and the thirteenth carbon positions respectively, and a ketone group at the seventeenth carbon position.

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esc Write the systematic name of each organic molecule: structure CH3 CH3-C=CH2 CH3-CH2-C-CH2-CH3 CH-CH3 CH3 ☐ ☐ ☐ CI-CH-CH=CH2 Explanation Check F1 F2 name 80 F3 F4 F5 F6 A 7 ! 2 # 3 4 % 5 6 & 7 Q W E R Y FT 2025 Mc
Two reactants X and Z are required to convert the compound CH3-CH2-CH2Br to the compound CH3-CH2-CH=P(C6H5)3. State reactants X and Z.
2. Write a reasonable mechanism that converts the reactants into the products. Avoid issues A-U from the previous page. You can use any number of steps (it does not have to be a one-step mechanism). Do not use any other chemicals (solvents, acids, bases, etc.) in your mechanism. 2 2 H ΗΘ
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