Organic Chemistry
Organic Chemistry
12th Edition
ISBN: 9781118875766
Author: T. W. Graham Solomons, Craig B. Fryhle, Scott A. Snyder
Publisher: WILEY
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Chapter 23, Problem 25P
Interpretation Introduction

Interpretation:

The mechanism thataccounts for each step of the given synthesis is to be written.

Concept introduction:

Cyperone derives its name from the Cyperusrotundus, a nut grass found in tropical, subtropical and temperate regions. It can exist in both αand β forms. It is majorly used in the medication of androgen-, estrogen-, and progestin-related hormonal diseases. Its molecular formula is C15H22O. Chemically, it is a terpene.

Robinson annulation process is an effective process for the ring formation of six-membered polycyclic compounds, such as lipids and steroids. It works with three important steps, which are as follows: conjugate addition of resonance-stabilized carbanion, aldol condensation, and elimination of hydroxyl ion (OH).

Aldol condensation involves the addition of the aldol (aldehyde and alcohol) group, followed by condensation of the product. In this reaction, the enolate of an aldehyde or a ketone reacts at the αcarbon with the carbonyl part of the other molecule to produce an βhydroxy aldehyde or a ketone.

Michael addition is a reaction that involves the conjugate addition of a resonance-stabilized carbanion for the formation of an enolate.

The reaction thatinvolves the removal of an αproton through a base is known as E1 elimination reaction.

The reaction thatinvolves the removal of the OH group through dehydration is known as E2 elimination reaction.

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Predict the organic products that form in the reaction below: OH H+ H+ + ☑ Y Note: You may assume you have an excess of either reactant if the reaction requires more than one of those molecules to form the products. In the drawing area below, draw the skeletal ("line") structures of the missing organic products X and Y. You may draw the structures in any arrangement that you like, so long as they aren't touching. Click and drag to start drawing a structure. ✓ m
Determine the structures of the missing organic molecules in the following reaction: + H₂O +H H+ Y Z ☑ ☑ Note: Molecules that share the same letter have the exact same structure. In the drawing area below, draw the skeletal ("line") structures of the missing organic molecules X, Y, and Z. You may draw the structures in any arrangement that you like, so long as they aren't touching. Molecule X shows up in multiple steps, but you only have to draw its structure once. Click and drag to start drawing a structure. AP +
Please help, this is all the calculations i got!!! I will rate!!!Approx mass of KMnO in vial: 3.464 4 Moss of beaker 3×~0. z Nax200: = 29.9219 Massof weacerv after remosimgain N2C2O4. Need to fill in all the missing blanks. ง ง Approx mass of KMnO4 in vials 3.464 Mass of beaker + 3x ~0-304: 29.9219 2~0.20 Miss of beaker + 2x- 29.7239 Mass of beaker + 1x~0.2g Naz (204 29-5249 Mass of beaver after removing as qa Na₂ C₂O T1 T2 T3 Final Buiet reading Initial butet reading (int)) Hass of NaOr used for Titration -reading (mL) calculation Results: 8.5ml 17mL 27.4mL Oml Om Oml T1 T2 T3 Moles of No CO Moles of KMO used LOF KM. O used Molenty of KMNO Averagem Of KMOWL
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