ORG.CHEM EBOOK W/BBWILEY PLUS>CUSTOM<
ORG.CHEM EBOOK W/BBWILEY PLUS>CUSTOM<
2nd Edition
ISBN: 9781118872925
Author: Klein
Publisher: JOHN WILEY+SONS INC.CUSTOM
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Chapter 23, Problem 82IP
Interpretation Introduction

Interpretation: A mechanism for the formation of the product has to be provided.

Concept Introduction:

Diels-Alder reaction is a [4+2]-cycloaddition of a conjugated diene and a dienophile (an alkene or alkyne), an electrocyclic reaction that involves the 4 π-electrons of the diene and 2 π-electrons of the dienophile. The driving force of the reaction is the formation of new σ-bonds, which are energetically more stable than the π-bonds. Typically, Diels-Alder reaction works best when either the diene is substituted with electron-donating groups (like -OR, -NR2, etc) or when the dienophile is substituted with electron-withdrawing groups (like -NO2, -CN, -COR, etc).

ORG.CHEM EBOOK W/BBWILEY PLUS>CUSTOM<, Chapter 23, Problem 82IP , additional homework tip  1

To find: Provide a mechanism for the formation of the product

Derive the intermediate benzyne by heating

ORG.CHEM EBOOK W/BBWILEY PLUS>CUSTOM<, Chapter 23, Problem 82IP , additional homework tip  2

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Chapter 23 Solutions

ORG.CHEM EBOOK W/BBWILEY PLUS>CUSTOM<

Ch. 23.4 - Prob. 10CCCh. 23.4 - Prob. 11CCCh. 23.5 - Prob. 2LTSCh. 23.5 - Prob. 12PTSCh. 23.5 - Prob. 13PTSCh. 23.6 - Prob. 3LTSCh. 23.6 - Prob. 14PTSCh. 23.6 - Prob. 15ATSCh. 23.6 - Prob. 16ATSCh. 23.6 - Prob. 17ATSCh. 23.7 - Prob. 18PTSCh. 23.7 - Prob. 19PTSCh. 23.7 - Prob. 20PTSCh. 23.7 - Prob. 21ATSCh. 23.8 - Prob. 22CCCh. 23.8 - Prob. 23CCCh. 23.8 - Prob. 24CCCh. 23.9 - Prob. 5LTSCh. 23.9 - Prob. 25PTSCh. 23.9 - Prob. 26ATSCh. 23.9 - Prob. 27ATSCh. 23.9 - Prob. 28ATSCh. 23.10 - Prob. 29CCCh. 23.11 - Prob. 30CCCh. 23.11 - Prob. 6LTSCh. 23.11 - Prob. 31PTSCh. 23.11 - Prob. 32ATSCh. 23.11 - Prob. 33ATSCh. 23.12 - Prob. 34CCCh. 23.12 - Prob. 35CCCh. 23.13 - Prob. 36CCCh. 23.13 - Prob. 37CCCh. 23 - Prob. 38PPCh. 23 - Prob. 39PPCh. 23 - Prob. 40PPCh. 23 - Prob. 41PPCh. 23 - Prob. 42PPCh. 23 - Prob. 43PPCh. 23 - Prob. 44PPCh. 23 - Prob. 45PPCh. 23 - Prob. 46PPCh. 23 - Prob. 47PPCh. 23 - Prob. 48PPCh. 23 - Prob. 49PPCh. 23 - Prob. 50PPCh. 23 - Prob. 51PPCh. 23 - Prob. 52PPCh. 23 - Prob. 53PPCh. 23 - Prob. 54PPCh. 23 - Prob. 55PPCh. 23 - Prob. 56PPCh. 23 - Prob. 57PPCh. 23 - Prob. 58PPCh. 23 - Prob. 59PPCh. 23 - Prob. 60PPCh. 23 - Prob. 61PPCh. 23 - Prob. 62PPCh. 23 - Prob. 63PPCh. 23 - Prob. 64PPCh. 23 - Prob. 65PPCh. 23 - Prob. 66PPCh. 23 - Prob. 67PPCh. 23 - Prob. 68PPCh. 23 - Prob. 69PPCh. 23 - Prob. 70PPCh. 23 - Prob. 71PPCh. 23 - Prob. 72PPCh. 23 - Prob. 73PPCh. 23 - Prob. 74PPCh. 23 - Prob. 75PPCh. 23 - Prob. 76PPCh. 23 - Prob. 77IPCh. 23 - Prob. 78IPCh. 23 - Prob. 79IPCh. 23 - Prob. 80IPCh. 23 - Prob. 81IPCh. 23 - Prob. 82IPCh. 23 - Prob. 83IPCh. 23 - Prob. 84IPCh. 23 - Prob. 85IPCh. 23 - Prob. 86IPCh. 23 - Prob. 87IPCh. 23 - Prob. 88IPCh. 23 - Prob. 89IPCh. 23 - Prob. 90IPCh. 23 - Prob. 91CPCh. 23 - Prob. 92CPCh. 23 - Prob. 93CPCh. 23 - Prob. 94CPCh. 23 - Prob. 95CPCh. 23 - Prob. 96CPCh. 23 - Prob. 97CPCh. 23 - Prob. 98CP
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