Chapter 23, Problem 61E

Interpretation Introduction

Interpretation:

The crystal field energy level diagram showing placement of electrons in $d$ orbital for given complexes is to be shown.

Concept Introduction: The splitting of the $d$ orbital occurs when orbital of metal center comes in contact with orbital of incoming ligand. The electron-electron repulsion causes the splitting of $d$ orbital. The nature of complex depends upon the geometry of the complex and nature of the ligand. Weak field ligands lead to the formation of high spin complexes.

(a)

To determine:

The crystal-field energy-level diagram and placement of electrons in the $d$ orbital.

(b)

Interpretation Introduction

To determine:

The crystal-field energy-level diagram and placement of electrons in the $d$ orbital.

(c)

Interpretation Introduction

To determine:

The crystal-field energy-level diagram and placement of electrons in the $d$ orbital.

(d)

Interpretation Introduction

To determine:

The crystal-field energy-level diagram and placement of electrons in the $d$ orbital.

(e)

Interpretation Introduction

To determine:

The crystal-field energy-level diagram and placement of electrons in the $d$ orbital.

(f)

Interpretation Introduction

To determine:

The crystal-field energy-level diagram and placement of electrons in the $d$ orbital.