
ORGANIC CHEM. VOL.1+2-W/WILEYPLUS
12th Edition
ISBN: 9781119304241
Author: Solomons
Publisher: WILEY C
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Chapter 23, Problem 3LGP
Interpretation Introduction
Interpretation:
On the basis of given information, the structures of the required terpene and its isoprene unit are to be elucidated.
Concept introduction:
Terpenes are largely found as constituents of essential oils. They are mostly hydrocarbons.
The building block is a five-carbon isoprene unit
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Post Lab Questions.
1) Draw the mechanism of your Diels-Alder cycloaddition.
2) Only one isomer of product is formed in the Diels-Alder cycloaddition. Why?
3) Imagine that you used isoprene as diene - in that case you don't have to worry about assigning endo
vs exo. Draw the "endo" and "exo" products of the Diels-Alder reaction between isoprene and maleic
anhydride, and explain why the distinction is irrelevant here.
4) This does not hold for other dienes. Draw the exo and endo products of the reaction of cyclohexadiene
with maleic anhydride. Make sure you label your answers properly as endo or exo.
100 °C
Xylenes
???
5) Calculate the process mass intensity for your specific reaction (make sure to use your actual amounts
of reagent).
Chapter 23 Solutions
ORGANIC CHEM. VOL.1+2-W/WILEYPLUS
Ch. 23 - Prob. 1PPCh. 23 - Prob. 2PPCh. 23 - Prob. 3PPCh. 23 - Prob. 4PPCh. 23 - Prob. 5PPCh. 23 - Prob. 6PPCh. 23 - Prob. 7PPCh. 23 - Prob. 8PPCh. 23 - Prob. 9PPCh. 23 - Prob. 10PP
Ch. 23 - Prob. 11PPCh. 23 - Prob. 12PPCh. 23 - Prob. 13PPCh. 23 - Prob. 14PCh. 23 - 23.15 How would you transform tetradecanal into...Ch. 23 - Prob. 16PCh. 23 - Prob. 17PCh. 23 - When limonene (Section 23.3) is heated strongly,...Ch. 23 - Gadoleic acid (C20H38O2), a fatty acid that can be...Ch. 23 - 23.20 -Phellandrene and -phellandrene are isomeric...Ch. 23 - Prob. 21PCh. 23 - Prob. 22PCh. 23 - Prob. 23PCh. 23 - The initial steps of a laboratory synthesis of...Ch. 23 - Prob. 25PCh. 23 - Prob. 26PCh. 23 - Prob. 27PCh. 23 - 2. The biosynthesis of fatty acids is accomplished...Ch. 23 - Prob. 3LGPCh. 23 - Prob. 4LGP
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