The products obtained when the given terpenes are subjected to ozonolysis and then treated with dimethyl sulphide are to be determined. Concept Introduction: > The essential oils are odoriferous chemicals that are extracted from plants by heating or distillation. These essential oils have important chemical composition of hydrocarbons called terpenes and oxygen-containing compounds called terpenoids . The monoterpene unit is made up of two or more 5-Carbon atoms. > The ozone is a powerful oxidant and the terpenoid alkenes (or any other alkenes) undergo cleavage with ozone to produce a range of byproducts. The reaction cleaves the alkene into two carbonyl products with the formation of an ozonide as an intermediate. This ozonide undergoes reduction with dimethyl sulphide ( (CH 3 ) 2 S ) to yield aldehyde (s). > The ozonolysis of myrcene produces 1 mol of monoterpene, 2 mols of formaldehyde, and 1 mol of acetone. > The limonene undergoes ozonolysis and reduction process to yield the products, 1 mol of formaldehyde and 1 mol of monoterpene. > The α − Farnesene undergoes ozonolysis, and reduction reaction by dimethyl sulphide, to give the products, 1 mol of a primary carbonyl (acetone), 1 mol of a secondary carbonyl (aldehyde-keto group), 1 mol of an aldol (hydroxy butanal), 1 mol of glyoxal (ethanediol), and 1 mol of formaldehyde > The geraniol undergoes ozonolysis followed by reduction reaction by dimethyl sulphide to produce 1 mol of a primary carbonyl (acetone), 1 mol of a secondary carbonyl (aldehyde-keto group), and 1 mol of glyoxal (ethanediol). > The products formed by the reaction of ozone and dimethyl sulphide with squalene are 2 mols of acetone, 1 mol of hydroxy-aldehyde, and 4 mols of a ketal.

Question

Want to see the full answer?

Answer 1

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 23, Problem 3PP

Interpretation Introduction

Interpretation:

The products obtained when the given terpenes are subjected to ozonolysis and then treated with dimethyl sulphide are to be determined.

Concept Introduction:
>
The essential oils are odoriferous chemicals that are extracted from plants by heating or distillation. These essential oils have important chemical composition of hydrocarbons called terpenes and oxygen-containing compounds called terpenoids. The monoterpene unit is made up of two or more 5-Carbon atoms.
>
The ozone is a powerful oxidant and the terpenoid alkenes (or any other alkenes) undergo cleavage with ozone to produce a range of byproducts. The reaction cleaves the alkene into two carbonyl products with the formation of an ozonide as an intermediate. This ozonide undergoes reduction with dimethyl sulphide ( (CH3)2S ) to yield aldehyde(s).
>
The ozonolysis of myrcene produces 1 mol of monoterpene, 2 mols of formaldehyde, and 1 mol of acetone.
>
The limonene undergoes ozonolysis and reduction process to yield the products, 1 mol of formaldehyde and 1 mol of monoterpene.
>
The α−Farnesene undergoes ozonolysis, and reduction reaction by dimethyl sulphide, to give the products, 1 mol of a primary carbonyl (acetone), 1 mol of a secondary carbonyl (aldehyde-keto group), 1 mol of an aldol (hydroxy butanal), 1 mol of glyoxal (ethanediol), and 1 mol of formaldehyde
>
The geraniol undergoes ozonolysis followed by reduction reaction by dimethyl sulphide to produce 1 mol of a primary carbonyl (acetone), 1 mol of a secondary carbonyl (aldehyde-keto group), and 1 mol of glyoxal (ethanediol).
>
The products formed by the reaction of ozone and dimethyl sulphide with squalene are 2 mols of acetone, 1 mol of hydroxy-aldehyde, and 4 mols of a ketal.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

Draw the structures of the following.

Write the structure of the principal organic product obtained on nitration of each of the following: (a) p-Methylbenzoic acid (d) p-Methoxyacetophenone (b) m-Dichlorobenzene (e) p-Methylanisole (c) m-Dinitrobenzene (f ) 2,6-Dibromoanisole

Each of the following reactions has been carried out under conditions such that disubstitution or trisubstitution occurred. Identify the principal organic product in each case. (a) Nitration of p-chlorobenzoic acid (dinitration) (b) Bromination of aniline (tribromination) (c) Bromination of o-aminoacetophenone (dibromination) (d) Bromination of p-nitrophenol (dibromination) (e) Reaction of biphenyl with tert-butyl chloride and iron(III) chloride (dialkylation) (f) Sulfonation of phenol (disulfonation)

Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 23, Problem 3PP

Interpretation Introduction

Interpretation:

The products obtained when the given terpenes are subjected to ozonolysis and then treated with dimethyl sulphide are to be determined.

Concept Introduction:
>
The essential oils are odoriferous chemicals that are extracted from plants by heating or distillation. These essential oils have important chemical composition of hydrocarbons called terpenes and oxygen-containing compounds called terpenoids. The monoterpene unit is made up of two or more 5-Carbon atoms.
>
The ozone is a powerful oxidant and the terpenoid alkenes (or any other alkenes) undergo cleavage with ozone to produce a range of byproducts. The reaction cleaves the alkene into two carbonyl products with the formation of an ozonide as an intermediate. This ozonide undergoes reduction with dimethyl sulphide ( (CH3)2S ) to yield aldehyde(s).
>
The ozonolysis of myrcene produces 1 mol of monoterpene, 2 mols of formaldehyde, and 1 mol of acetone.
>
The limonene undergoes ozonolysis and reduction process to yield the products, 1 mol of formaldehyde and 1 mol of monoterpene.
>
The α−Farnesene undergoes ozonolysis, and reduction reaction by dimethyl sulphide, to give the products, 1 mol of a primary carbonyl (acetone), 1 mol of a secondary carbonyl (aldehyde-keto group), 1 mol of an aldol (hydroxy butanal), 1 mol of glyoxal (ethanediol), and 1 mol of formaldehyde
>
The geraniol undergoes ozonolysis followed by reduction reaction by dimethyl sulphide to produce 1 mol of a primary carbonyl (acetone), 1 mol of a secondary carbonyl (aldehyde-keto group), and 1 mol of glyoxal (ethanediol).
>
The products formed by the reaction of ozone and dimethyl sulphide with squalene are 2 mols of acetone, 1 mol of hydroxy-aldehyde, and 4 mols of a ketal.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 23, Problem 3PP

Interpretation Introduction

Interpretation:

The products obtained when the given terpenes are subjected to ozonolysis and then treated with dimethyl sulphide are to be determined.

Concept Introduction:
>
The essential oils are odoriferous chemicals that are extracted from plants by heating or distillation. These essential oils have important chemical composition of hydrocarbons called terpenes and oxygen-containing compounds called terpenoids. The monoterpene unit is made up of two or more 5-Carbon atoms.
>
The ozone is a powerful oxidant and the terpenoid alkenes (or any other alkenes) undergo cleavage with ozone to produce a range of byproducts. The reaction cleaves the alkene into two carbonyl products with the formation of an ozonide as an intermediate. This ozonide undergoes reduction with dimethyl sulphide ( (CH3)2S ) to yield aldehyde(s).
>
The ozonolysis of myrcene produces 1 mol of monoterpene, 2 mols of formaldehyde, and 1 mol of acetone.
>
The limonene undergoes ozonolysis and reduction process to yield the products, 1 mol of formaldehyde and 1 mol of monoterpene.
>
The α−Farnesene undergoes ozonolysis, and reduction reaction by dimethyl sulphide, to give the products, 1 mol of a primary carbonyl (acetone), 1 mol of a secondary carbonyl (aldehyde-keto group), 1 mol of an aldol (hydroxy butanal), 1 mol of glyoxal (ethanediol), and 1 mol of formaldehyde
>
The geraniol undergoes ozonolysis followed by reduction reaction by dimethyl sulphide to produce 1 mol of a primary carbonyl (acetone), 1 mol of a secondary carbonyl (aldehyde-keto group), and 1 mol of glyoxal (ethanediol).
>
The products formed by the reaction of ozone and dimethyl sulphide with squalene are 2 mols of acetone, 1 mol of hydroxy-aldehyde, and 4 mols of a ketal.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 23, Problem 3PP

Interpretation Introduction