ORGANIC CHEM. VOL.1+2-W/WILEYPLUS
ORGANIC CHEM. VOL.1+2-W/WILEYPLUS
12th Edition
ISBN: 9781119304241
Author: Solomons
Publisher: WILEY C
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Chapter 23, Problem 20P

α -Phellandrene and β -phellandrene are isomeric compounds that are minor constituents of spearmint oil; they have the molecular formula C 10 H 16 . Each compound has a UV absorption maximum in the 230–270 nm range. On catalytic hydrogenation, each compound yields 1-isopropyl-4-methylcyclohexane. On vigorous oxidation with potassium permanganate, α -phellandrene yields

Chapter 23, Problem 20P, 23.20	-Phellandrene and -phellandrene are isomeric compounds that are minor constituents of

Propose structures for α -and β -phellandrene.

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Using reaction free energy to predict equilibrium composition Consider the following equilibrium: 2NOCI (g) 2NO (g) + Cl2 (g) AGº =41. kJ Now suppose a reaction vessel is filled with 4.50 atm of nitrosyl chloride (NOCI) and 6.38 atm of chlorine (C12) at 212. °C. Answer the following questions about this system: ? rise Under these conditions, will the pressure of NOCI tend to rise or fall? x10 fall Is it possible to reverse this tendency by adding NO? In other words, if you said the pressure of NOCI will tend to rise, can that be changed to a tendency to fall by adding NO? Similarly, if you said the pressure of NOCI will tend to fall, can that be changed to a tendency to rise by adding NO? yes no If you said the tendency can be reversed in the second question, calculate the minimum pressure of NO needed to reverse it. Round your answer to 2 significant digits. 0.035 atm ✓ G 00. 18 Ar
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