Chemistry
4th Edition
ISBN: 9780078021527
Author: Julia Burdge
Publisher: McGraw-Hill Education
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Question
Chapter 23, Problem 2SEPP
Interpretation Introduction
Interpretation:
The function of copper chaperones is to be discussed out of the given options.
Concept Introduction:
Copper chaperones are intracellular proteins that protect thecytoplasm from copper ions in transit and deliver the copper directly to cuproenzymes.
They are soluble copper binding proteins. Balancing of the copper ion concentration by these chaperones is presently not understood well and constitutes a problem in bioinorganic chemistry.
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(a
4 shows scanning electron microscope (SEM) images of extruded
actions of packing bed for two capillary columns of different diameters,
al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the
same stationary phase, spherical particles with 1-um diameter.
A) When the columns were prepared, the figure shows that the column with
the larger diameter has more packing irregularities. Explain this observation.
B) Predict what affect this should have on band broadening and discuss your
prediction using the van Deemter terms.
C) Does this figure support your explanations in application question 33?
Explain why or why not and make any changes in your answers in light of
this figure.
Figure 4 SEM images of
sections of packed columns
for a) 750 and b) 30-um-i.d.
capillary columns.³
fcrip
= ↓ bandwidth Il temp
32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual
components of the van Deemter equation and consequently, band broadening?
Increase temperature
Longer column
Using a gas mobile phase
instead of liquid
Smaller particle stationary phase
Multiple Paths
Diffusion
Mass Transfer
34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.).
A) Predict whether decreasing the column inner diameters increase or decrease bandwidth.
B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or
decreasing bandwidth as a function of i.d. and justify your answer.
Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was
obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles.
35
20
H(um)
큰 20
15
90
0+
1500
100
75
550
01
02
594
05
μ(cm/sec)
30
15
10
Chapter 23 Solutions
Chemistry
Ch. 23 - Prob. 1QPCh. 23 - Prob. 2QPCh. 23 - Prob. 3QPCh. 23 - Prob. 4QPCh. 23 - Prob. 5QPCh. 23 - Prob. 6QPCh. 23 - Prob. 7QPCh. 23 - Describe with examples the chemical and...Ch. 23 - Prob. 9QPCh. 23 - Prob. 10QP
Ch. 23 - Prob. 11QPCh. 23 - Prob. 12QPCh. 23 - Prob. 13QPCh. 23 - Prob. 14QPCh. 23 - Prob. 15QPCh. 23 - Prob. 16QPCh. 23 - Prob. 17QPCh. 23 - Prob. 18QPCh. 23 - Prob. 19QPCh. 23 - Although iron is only about two-thirds as abundant...Ch. 23 - Prob. 21QPCh. 23 - Prob. 22QPCh. 23 - Prob. 23QPCh. 23 - Prob. 24QPCh. 23 - Prob. 25QPCh. 23 - Prob. 26QPCh. 23 - Prob. 27QPCh. 23 - Prob. 28QPCh. 23 - Prob. 29QPCh. 23 - Prob. 30QPCh. 23 - Prob. 31QPCh. 23 - Prob. 32QPCh. 23 - Prob. 33QPCh. 23 - Prob. 34QPCh. 23 - Prob. 35QPCh. 23 - Prob. 36QPCh. 23 - Prob. 37QPCh. 23 - Prob. 38QPCh. 23 - Prob. 39QPCh. 23 - Describe two ways of preparing magnesium chloride.Ch. 23 - Prob. 41QPCh. 23 - Prob. 42QPCh. 23 - Prob. 43QPCh. 23 - Prob. 44QPCh. 23 - Prob. 45QPCh. 23 - Prob. 46QPCh. 23 - Prob. 47QPCh. 23 - With the Hall process, how many hours will it take...Ch. 23 - Prob. 49QPCh. 23 - Prob. 50QPCh. 23 - Prob. 51QPCh. 23 - Prob. 52QPCh. 23 - Prob. 53QPCh. 23 - Prob. 54QPCh. 23 - Prob. 55QPCh. 23 - Prob. 56QPCh. 23 - Prob. 57QPCh. 23 - Prob. 58APCh. 23 - Prob. 59APCh. 23 - Prob. 60APCh. 23 - Prob. 61APCh. 23 - 23.62 A 0.450-g sample of steel contains manganese...Ch. 23 - Given that Δ G ( Fe 2 O 3 ) f o = − 741.0 kJ/mol...Ch. 23 - Prob. 64APCh. 23 - Prob. 65APCh. 23 - Prob. 66APCh. 23 - Prob. 67APCh. 23 - Write balanced equations for the following...Ch. 23 - Prob. 69APCh. 23 - Prob. 70APCh. 23 - Prob. 71APCh. 23 - Prob. 72APCh. 23 - Prob. 73APCh. 23 - Prob. 74APCh. 23 - Prob. 75APCh. 23 - Prob. 76APCh. 23 - Prob. 77APCh. 23 - Prob. 78APCh. 23 - Prob. 79APCh. 23 - 23.80 The electrical conductance of copper metal...Ch. 23 - Prob. 81APCh. 23 - Prob. 82APCh. 23 - Prob. 1SEPPCh. 23 - Prob. 2SEPPCh. 23 - Prob. 3SEPPCh. 23 - Prob. 4SEPP
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