Chemistry
4th Edition
ISBN: 9780078021527
Author: Julia Burdge
Publisher: McGraw-Hill Education
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Chapter 23, Problem 35QP
Interpretation Introduction
Interpretation:
The working of sodium hydride (
Concept Introduction:
A drying agent is generally an anhydrous inorganic salt, which absorbs water when exposed to the atmosphere of moisture or a wet solution.
Sodium hydride is the most commonly used drying agent for organic solvents.
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A solution contains 0.097 M Ce3+, 1.55x10-3 M Ce4+, 1.55x10-3 M Mn2+, 0.097 M MnO4-, and 1.00 M HClO4 (F= 9.649 x 104 C/mol).
a) Write a balanced net reaction that can occur between species in this solution.
b) Calculate deltaG0 and K for the reaction.
c) Calculate E and deltaG for the conditions given.
Ce4+ + e- = Ce3+ E0= 1.70 V
MnO4- + 8H+ + 5e- = Mn2+ + 4H2O E0= 1.507 V
1. Provide a step-by-step mechanism for formation of ALL STEREOISOMERS in
the following reaction.
Na HCO3 (Sodium bicarbonate, baking soda) is not soluble in CH2Cl2. The powder is
a weak base used to neutralize strong acid (pKa < 0) produced by the reaction.
Redraw the product to show the configuration(s) that form at C-2 and C-4.
Br2
OH
CH2Cl2
Na* HCO3
Br
HO
OH
+ Na Br +
2. Specify the solvent and reagent(s) required to carry out each of the following FGI. If
two reagent sets must be used for the FGI, specify the solvent and reagent(s) for each
reagent set. If a reaction cannot be carried out with reagents (sets)
class, write NP (not possible) in the solvent box for reagent set #1.
Use the letter abbreviation for each solvent; use a number abbreviation for reagent(s).
Solvents: CH2Cl2 (A);
H₂O (B);
Reagents:
HBr (1);
R₂BH (6);
H2SO4 (2);
CH3OH (C);
Br₂ (3);
CH3CO₂H (D)
NaHCO3 (4);
Hg(OAc)2 (5);
H₂O2/HO (7);
NaBH4 (8)
Reagent Set #1
Reagent Set #2
FGI
+ enant
OH
Solvent Reagent(s) Solvent Reagent(s)
Chapter 23 Solutions
Chemistry
Ch. 23 - Prob. 1QPCh. 23 - Prob. 2QPCh. 23 - Prob. 3QPCh. 23 - Prob. 4QPCh. 23 - Prob. 5QPCh. 23 - Prob. 6QPCh. 23 - Prob. 7QPCh. 23 - Describe with examples the chemical and...Ch. 23 - Prob. 9QPCh. 23 - Prob. 10QP
Ch. 23 - Prob. 11QPCh. 23 - Prob. 12QPCh. 23 - Prob. 13QPCh. 23 - Prob. 14QPCh. 23 - Prob. 15QPCh. 23 - Prob. 16QPCh. 23 - Prob. 17QPCh. 23 - Prob. 18QPCh. 23 - Prob. 19QPCh. 23 - Although iron is only about two-thirds as abundant...Ch. 23 - Prob. 21QPCh. 23 - Prob. 22QPCh. 23 - Prob. 23QPCh. 23 - Prob. 24QPCh. 23 - Prob. 25QPCh. 23 - Prob. 26QPCh. 23 - Prob. 27QPCh. 23 - Prob. 28QPCh. 23 - Prob. 29QPCh. 23 - Prob. 30QPCh. 23 - Prob. 31QPCh. 23 - Prob. 32QPCh. 23 - Prob. 33QPCh. 23 - Prob. 34QPCh. 23 - Prob. 35QPCh. 23 - Prob. 36QPCh. 23 - Prob. 37QPCh. 23 - Prob. 38QPCh. 23 - Prob. 39QPCh. 23 - Describe two ways of preparing magnesium chloride.Ch. 23 - Prob. 41QPCh. 23 - Prob. 42QPCh. 23 - Prob. 43QPCh. 23 - Prob. 44QPCh. 23 - Prob. 45QPCh. 23 - Prob. 46QPCh. 23 - Prob. 47QPCh. 23 - With the Hall process, how many hours will it take...Ch. 23 - Prob. 49QPCh. 23 - Prob. 50QPCh. 23 - Prob. 51QPCh. 23 - Prob. 52QPCh. 23 - Prob. 53QPCh. 23 - Prob. 54QPCh. 23 - Prob. 55QPCh. 23 - Prob. 56QPCh. 23 - Prob. 57QPCh. 23 - Prob. 58APCh. 23 - Prob. 59APCh. 23 - Prob. 60APCh. 23 - Prob. 61APCh. 23 - 23.62 A 0.450-g sample of steel contains manganese...Ch. 23 - Given that Δ G ( Fe 2 O 3 ) f o = − 741.0 kJ/mol...Ch. 23 - Prob. 64APCh. 23 - Prob. 65APCh. 23 - Prob. 66APCh. 23 - Prob. 67APCh. 23 - Write balanced equations for the following...Ch. 23 - Prob. 69APCh. 23 - Prob. 70APCh. 23 - Prob. 71APCh. 23 - Prob. 72APCh. 23 - Prob. 73APCh. 23 - Prob. 74APCh. 23 - Prob. 75APCh. 23 - Prob. 76APCh. 23 - Prob. 77APCh. 23 - Prob. 78APCh. 23 - Prob. 79APCh. 23 - 23.80 The electrical conductance of copper metal...Ch. 23 - Prob. 81APCh. 23 - Prob. 82APCh. 23 - Prob. 1SEPPCh. 23 - Prob. 2SEPPCh. 23 - Prob. 3SEPPCh. 23 - Prob. 4SEPP
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- Germanium (Ge) is a semiconductor with a bandgap of 2.2 eV. How could you dope Ge to make it a p-type semiconductor with a larger bandgap? Group of answer choices It is impossible to dope Ge and have this result in a larger bandgap. Dope the Ge with silicon (Si) Dope the Ge with gallium (Ga) Dope the Ge with phosphorus (P)arrow_forwardWhich of the following semiconductors would you choose to have photons with the longest possible wavelengths be able to promote electrons to the semiconductor's conduction band? Group of answer choices Si Ge InSb CdSarrow_forwardWhich of the following metals is the only one with all of its bands completely full? Group of answer choices K Na Ca Alarrow_forward
- 2. Specify the solvent and reagent(s) required to carry out each of the following FGI. If two reagent sets must be used for the FGI, specify the solvent and reagent(s) for each reagent set. If a reaction cannot be carried out with reagents (sets) class, write NP (not possible) in the solvent box for reagent set #1. Use the letter abbreviation for each solvent; use a number abbreviation for reagent(s). Solvents: CH2Cl2 (A); Reagents: H₂O (B); CH3CO₂H (D) NaHCO3 (4); Hg(OAc)2 (5); HBr (1); R₂BH (6); H2SO4 (2); CH3OH (C); Br₂ (3); H₂O₂ / HO- (7); NaBH4 (8) Reagent Set #1 Reagent Set #2 FGI OH - α-α Br + enant Solvent Reagent(s) Solvent Reagent(s)arrow_forwardBased on concepts from Lecture 3-5, which of the following ionic compounds should be most soluble in water? Group of answer choices MgO BeO CaO BaOarrow_forwardFrom an energy standpoint, which two process - in the correct order - are involved in the dissolving of an ionic compound crystal? Group of answer choices Water coordination to the ions followed by sublimation into the gas phase Sublimation of the crystal into gas-phase ions followed by water coordination to the ions Ion dissociation from the crystal followed by water coordination to the ions Water coordination to the ions followed by ion dissociation from the crystalarrow_forward
- For which Group 2 metal (M), is this process the most exothermic? M2+(g) + O2−(g) + CO2(g) → MO(s) + CO2(g) Group of answer choices M = Sr M = Mg M = Ca M = Baarrow_forward2. Specify the solvent and reagent(s) required to carry out each of the following FGI. If two reagent sets must be used for the FGI, specify the solvent and reagent(s) for each reagent set. If a reaction cannot be carried out with reagents (sets) class, write NP (not possible) in the solvent box for reagent set #1. Use the letter abbreviation for each solvent; use a number abbreviation for reagent(s). Solvents: CH2Cl2 (A); H₂O (B); Reagents: HBr (1); H2SO4 (2); CH3OH (C); Br₂ (3); CH3CO₂H (D) NaHCO3 (4); Hg(OAc)2 (5); R₂BH (6); H₂O₂ / HO- (7); NaBH4 (8) Reagent Set #1 Reagent Set #2 FGI Solvent Reagent(s) Solvent Reagent(s) HO OHarrow_forwardFor which of the following ionic compounds would you expect the smallest difference between its theoretical and experimental lattice enthalpies? (You may assume these all have the same unit cell structure.) Electronegativities: Ca (1.0), Fe (1.8), Mg (1.2), O (3.5), S (2.5), Zn (1.6) Group of answer choices ZnO MgS CaO FeSarrow_forward
- In the Born-Haber cycle for KCl crystal formation, what enthalpy component must be divided by two? Group of answer choices KCl(s) enthalpy of formation Ionization energy for K(g) K(s) sublimation enthalpy Cl2 bond dissociation enthalpyarrow_forward2. Specify the solvent and reagent(s) required to carry out each of the following FGI. If two reagent sets must be used for the FGI, specify the solvent and reagent(s) for each reagent set. If a reaction cannot be carried out with reagents (sets) class, write NP (not possible) in the solvent box for reagent set #1. Use the letter abbreviation for each solvent; use a number abbreviation for reagent(s). Solvents: CH2Cl2 (A); H₂O (B); Reagents: HBr (1); R₂BH (6); H2SO4 (2); CH3OH (C); Br₂ (3); CH3CO₂H (D) NaHCO3 (4); Hg(OAc)2 (5); H₂O₂ / HO (7); NaBH4 (8) Reagent Set #1 Reagent Set #2 FGI хот Br Solvent Reagent(s) Solvent Reagent(s)arrow_forwardWhat is the correct chemical equation for the lattice formation reaction for CaBr2? Group of answer choices Ca2+(g) + 2 Br−(g) → CaBr2(s) ½ Ca2+(g) + Br−(g) → ½ CaBr2(s) Ca(s) + Br2(l) → CaBr2(s) Ca(s) + 2 Br−(g) → CaBr2(s)arrow_forward
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