ORGANIC CHEMISTRY (LL)-W/SOLN.>CUSTOM<
ORGANIC CHEMISTRY (LL)-W/SOLN.>CUSTOM<
10th Edition
ISBN: 9781259972348
Author: Carey
Publisher: MCG CUSTOM
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Chapter 23, Problem 23P
Interpretation Introduction

Interpretation:

A reasonable synthesis of 3-pentadecyclcatechol from 2,3-dimethoxybenzaldehyde and any necessary organic or inorganic reagentsis to be shown.

Concept introduction:

Ethers react with hydrogen halides to form alcohols and alkyl halide.

Wilkinson catalyst is a coordination complex of rhodium. It is used to reduce double bonds.

In the Wittig reaction, an aldehyde or a ketone reacts with triphenyl phophonium ylide to generate an alkene and triphenylphosphine oxide.

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The following equations represent the formation of compound MX. What is the AH for the electron affinity of X (g)? X₂ (g) → 2X (g) M (s) → M (g) M (g) M (g) + e- AH = 60 kJ/mol AH = 22 kJ/mol X (g) + e-X (g) M* (g) +X (g) → MX (s) AH = 118 kJ/mol AH = ? AH = -190 kJ/mol AH = -100 kJ/mol a) -80 kJ b) -30 kJ c) -20 kJ d) 20 kJ e) 156 kJ
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