(a) Interpretation: Whether the given reaction proceeds as indicated is to be determined. Concept introduction: The amine groups attached to benzene are Lewis bases; the lone pair on nitrogen coordinates with Lewis acid on reaction with Friedel Craft acylation, and nitrogen carries a positive charge and thus becomes a highly deactivating group.

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Answer 1

Question

Chapter 23, Problem 23.9YT

Interpretation Introduction

(a)

Interpretation:

Whether the given reaction proceeds as indicated is to be determined.

Concept introduction:

The amine groups attached to benzene are Lewis bases; the lone pair on nitrogen coordinates with Lewis acid on reaction with Friedel Craft acylation, and nitrogen carries a positive charge and thus becomes a highly deactivating group.

Interpretation Introduction

(b)

Interpretation:

Whether the given reaction proceeds as indicated is to be determined.

Concept introduction:

The electron donating groups increase the electron density around the ring and activate the ring. The activating groups are ortho/para directing, thus giving ortho/para substituted product on Friedel Craft acylation.

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Answer 2

Question

Chapter 23, Problem 23.9YT

Interpretation Introduction

(a)

Interpretation:

Whether the given reaction proceeds as indicated is to be determined.

Concept introduction:

The amine groups attached to benzene are Lewis bases; the lone pair on nitrogen coordinates with Lewis acid on reaction with Friedel Craft acylation, and nitrogen carries a positive charge and thus becomes a highly deactivating group.

Interpretation Introduction

(b)

Interpretation:

Whether the given reaction proceeds as indicated is to be determined.

Concept introduction:

The electron donating groups increase the electron density around the ring and activate the ring. The activating groups are ortho/para directing, thus giving ortho/para substituted product on Friedel Craft acylation.

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Answer 3

Question

Chapter 23, Problem 23.9YT

Interpretation Introduction

(a)

Interpretation:

Whether the given reaction proceeds as indicated is to be determined.

Concept introduction:

The amine groups attached to benzene are Lewis bases; the lone pair on nitrogen coordinates with Lewis acid on reaction with Friedel Craft acylation, and nitrogen carries a positive charge and thus becomes a highly deactivating group.

Interpretation Introduction

(b)

Interpretation:

Whether the given reaction proceeds as indicated is to be determined.

Concept introduction:

The electron donating groups increase the electron density around the ring and activate the ring. The activating groups are ortho/para directing, thus giving ortho/para substituted product on Friedel Craft acylation.

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See solution

Answer 4

Question

Chapter 23, Problem 23.9YT

Interpretation Introduction

(a)

Interpretation:

Whether the given reaction proceeds as indicated is to be determined.

Concept introduction:

The amine groups attached to benzene are Lewis bases; the lone pair on nitrogen coordinates with Lewis acid on reaction with Friedel Craft acylation, and nitrogen carries a positive charge and thus becomes a highly deactivating group.

Interpretation Introduction

(b)

Interpretation:

Whether the given reaction proceeds as indicated is to be determined.

Concept introduction:

The electron donating groups increase the electron density around the ring and activate the ring. The activating groups are ortho/para directing, thus giving ortho/para substituted product on Friedel Craft acylation.

Expert Solution & Answer

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Answer 5

Chapter 23, Problem 23.9YT

Interpretation Introduction

(a)

Interpretation:

Whether the given reaction proceeds as indicated is to be determined.

Concept introduction:

The amine groups attached to benzene are Lewis bases; the lone pair on nitrogen coordinates with Lewis acid on reaction with Friedel Craft acylation, and nitrogen carries a positive charge and thus becomes a highly deactivating group.

Interpretation Introduction

(b)

Interpretation:

Whether the given reaction proceeds as indicated is to be determined.

Concept introduction:

The electron donating groups increase the electron density around the ring and activate the ring. The activating groups are ortho/para directing, thus giving ortho/para substituted product on Friedel Craft acylation.

Answer 6

Chapter 23, Problem 23.9YT

Interpretation Introduction

(a)

Interpretation:

Whether the given reaction proceeds as indicated is to be determined.

Concept introduction:

The amine groups attached to benzene are Lewis bases; the lone pair on nitrogen coordinates with Lewis acid on reaction with Friedel Craft acylation, and nitrogen carries a positive charge and thus becomes a highly deactivating group.

Answer 7

Chapter 23, Problem 23.9YT

Interpretation Introduction

(a)

Interpretation:

Whether the given reaction proceeds as indicated is to be determined.

Concept introduction:

The amine groups attached to benzene are Lewis bases; the lone pair on nitrogen coordinates with Lewis acid on reaction with Friedel Craft acylation, and nitrogen carries a positive charge and thus becomes a highly deactivating group.

Answer 8

Interpretation Introduction

(b)

Interpretation:

Whether the given reaction proceeds as indicated is to be determined.

Concept introduction:

The electron donating groups increase the electron density around the ring and activate the ring. The activating groups are ortho/para directing, thus giving ortho/para substituted product on Friedel Craft acylation.

Answer 9

Interpretation Introduction

(b)

Interpretation:

Whether the given reaction proceeds as indicated is to be determined.

Concept introduction:

The electron donating groups increase the electron density around the ring and activate the ring. The activating groups are ortho/para directing, thus giving ortho/para substituted product on Friedel Craft acylation.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 23 - Prob. 23.1P Ch. 23 - Prob. 23.2P Ch. 23 - Prob. 23.3P Ch. 23 - Prob. 23.4P Ch. 23 - Prob. 23.5P Ch. 23 - Prob. 23.6P Ch. 23 - Prob. 23.7P Ch. 23 - Prob. 23.8P Ch. 23 - Prob. 23.9P Ch. 23 - Prob. 23.10P

Solution Summary: The author explains how the amine groups attached to benzene are Lewis bases. The lone pair on nitrogen coordinates with Lewis acid on reaction with Friedel Craft acylation.

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