Condensed structural formula for the given compounds has to be written. Concept Introduction: Condensed structural formula is representation of the organic compound. In this the lengthy carbon chain is shown only with the carbon atoms (along with the hydrogen) without any bonds. The additional branches are shown with explicit bonds.

Question

Draw the complete mechanism for the reaction below. Please include appropriate arrows, intermediates, and formal charges.

Answer 1

Question

Chapter 23, Problem 23.82QP

(a)

Interpretation Introduction

Interpretation:

Condensed structural formula for the given compounds has to be written.

Concept Introduction:

Condensed structural formula is representation of the organic compound. In this the lengthy carbon chain is shown only with the carbon atoms (along with the hydrogen) without any bonds. The additional branches are shown with explicit bonds.

(b)

Interpretation Introduction

Interpretation:

Condensed structural formula for the given compounds has to be written.

Concept Introduction:

Condensed structural formula is representation of the organic compound. In this the lengthy carbon chain is shown only with the carbon atoms (along with the hydrogen) without any bonds. The additional branches are shown with explicit bonds.

(c)

Interpretation Introduction

Interpretation:

Condensed structural formula for the given compounds has to be written.

Concept Introduction:

Condensed structural formula is representation of the organic compound. In this the lengthy carbon chain is shown only with the carbon atoms (along with the hydrogen) without any bonds. The additional branches are shown with explicit bonds.

(d)

Interpretation Introduction

Interpretation:

Condensed structural formula for the given compounds has to be written.

Concept Introduction:

Condensed structural formula is representation of the organic compound. In this the lengthy carbon chain is shown only with the carbon atoms (along with the hydrogen) without any bonds. The additional branches are shown with explicit bonds.

(e)

Interpretation Introduction

Interpretation:

Condensed structural formula for the given compounds has to be written.

Concept Introduction:

Condensed structural formula is representation of the organic compound. In this the lengthy carbon chain is shown only with the carbon atoms (along with the hydrogen) without any bonds. The additional branches are shown with explicit bonds.

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Draw the complete mechanism for the reaction below. Please include appropriate arrows, intermediates, and formal charges.

(c) The following data have been obtained for the hydrolysis of sucrose, C12H22O11, to glucose, C6H12O6, and fructose C6H12O6, in acidic solution: C12H22O11 + H2O → C6H12O6 + C6H12O6 [sucrose]/mol dm³ t/min 0 0.316 14 0.300 39 0.274 60 0.256 80 0.238 110 0.211 (i) Graphically prove the order of the reaction and determine the rate constant of the reaction. (ii) Determine the half-life, t½ for the hydrolysis of sucrose.

(III) adsorbent (b) Adsorption of the hexacyanoferrate (III) ion, [Fe(CN)6] ³, on y-Al2O3 from aqueous solution was examined. The adsorption was modelled using a modified Langmuir isotherm, yielding the following values of Kat pH = 6.5: (ii) T/K 10-10 K 280 2.505 295 1.819 310 1.364 325 1.050 Determine the enthalpy of adsorption, AadsHⓇ. If the reported value of entropy of adsorption, Aads Se = 146 J K-1 mol-1 under the above conditions, determine Aads Gº.

Answer 2

Question

Chapter 23, Problem 23.82QP

(a)

Interpretation Introduction

Interpretation:

Condensed structural formula for the given compounds has to be written.

Concept Introduction:

Condensed structural formula is representation of the organic compound. In this the lengthy carbon chain is shown only with the carbon atoms (along with the hydrogen) without any bonds. The additional branches are shown with explicit bonds.

(b)

Interpretation Introduction

Interpretation:

Condensed structural formula for the given compounds has to be written.

Concept Introduction:

Condensed structural formula is representation of the organic compound. In this the lengthy carbon chain is shown only with the carbon atoms (along with the hydrogen) without any bonds. The additional branches are shown with explicit bonds.

(c)

Interpretation Introduction

Interpretation:

Condensed structural formula for the given compounds has to be written.

Concept Introduction:

Condensed structural formula is representation of the organic compound. In this the lengthy carbon chain is shown only with the carbon atoms (along with the hydrogen) without any bonds. The additional branches are shown with explicit bonds.

(d)

Interpretation Introduction

Interpretation:

Condensed structural formula for the given compounds has to be written.

Concept Introduction:

Condensed structural formula is representation of the organic compound. In this the lengthy carbon chain is shown only with the carbon atoms (along with the hydrogen) without any bonds. The additional branches are shown with explicit bonds.

(e)

Interpretation Introduction

Interpretation:

Condensed structural formula for the given compounds has to be written.

Concept Introduction:

Condensed structural formula is representation of the organic compound. In this the lengthy carbon chain is shown only with the carbon atoms (along with the hydrogen) without any bonds. The additional branches are shown with explicit bonds.

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Answer 3

Question

Chapter 23, Problem 23.82QP

(a)

Interpretation Introduction

Interpretation:

Condensed structural formula for the given compounds has to be written.

Concept Introduction:

Condensed structural formula is representation of the organic compound. In this the lengthy carbon chain is shown only with the carbon atoms (along with the hydrogen) without any bonds. The additional branches are shown with explicit bonds.

(b)

Interpretation Introduction

Interpretation:

Condensed structural formula for the given compounds has to be written.

Concept Introduction:

Condensed structural formula is representation of the organic compound. In this the lengthy carbon chain is shown only with the carbon atoms (along with the hydrogen) without any bonds. The additional branches are shown with explicit bonds.

(c)

Interpretation Introduction

Interpretation:

Condensed structural formula for the given compounds has to be written.

Concept Introduction:

Condensed structural formula is representation of the organic compound. In this the lengthy carbon chain is shown only with the carbon atoms (along with the hydrogen) without any bonds. The additional branches are shown with explicit bonds.

(d)

Interpretation Introduction

Interpretation:

Condensed structural formula for the given compounds has to be written.

Concept Introduction:

Condensed structural formula is representation of the organic compound. In this the lengthy carbon chain is shown only with the carbon atoms (along with the hydrogen) without any bonds. The additional branches are shown with explicit bonds.

(e)

Interpretation Introduction

Interpretation:

Condensed structural formula for the given compounds has to be written.

Concept Introduction:

Condensed structural formula is representation of the organic compound. In this the lengthy carbon chain is shown only with the carbon atoms (along with the hydrogen) without any bonds. The additional branches are shown with explicit bonds.

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Answer 4

Question

Chapter 23, Problem 23.82QP

(a)

Interpretation Introduction

Interpretation:

Condensed structural formula for the given compounds has to be written.

Concept Introduction:

Condensed structural formula is representation of the organic compound. In this the lengthy carbon chain is shown only with the carbon atoms (along with the hydrogen) without any bonds. The additional branches are shown with explicit bonds.

(b)

Interpretation Introduction

Interpretation:

Condensed structural formula for the given compounds has to be written.

Concept Introduction:

Condensed structural formula is representation of the organic compound. In this the lengthy carbon chain is shown only with the carbon atoms (along with the hydrogen) without any bonds. The additional branches are shown with explicit bonds.

(c)

Interpretation Introduction

Interpretation:

Condensed structural formula for the given compounds has to be written.

Concept Introduction:

Condensed structural formula is representation of the organic compound. In this the lengthy carbon chain is shown only with the carbon atoms (along with the hydrogen) without any bonds. The additional branches are shown with explicit bonds.

(d)

Interpretation Introduction

Interpretation:

Condensed structural formula for the given compounds has to be written.

Concept Introduction:

Condensed structural formula is representation of the organic compound. In this the lengthy carbon chain is shown only with the carbon atoms (along with the hydrogen) without any bonds. The additional branches are shown with explicit bonds.

(e)

Interpretation Introduction

Interpretation:

Condensed structural formula for the given compounds has to be written.

Concept Introduction:

Condensed structural formula is representation of the organic compound. In this the lengthy carbon chain is shown only with the carbon atoms (along with the hydrogen) without any bonds. The additional branches are shown with explicit bonds.

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Answer 5

Chapter 23, Problem 23.82QP

(a)

Interpretation Introduction

Interpretation:

Condensed structural formula for the given compounds has to be written.

Concept Introduction:

Condensed structural formula is representation of the organic compound. In this the lengthy carbon chain is shown only with the carbon atoms (along with the hydrogen) without any bonds. The additional branches are shown with explicit bonds.

(b)

Interpretation Introduction

Interpretation:

Condensed structural formula for the given compounds has to be written.

Concept Introduction:

Condensed structural formula is representation of the organic compound. In this the lengthy carbon chain is shown only with the carbon atoms (along with the hydrogen) without any bonds. The additional branches are shown with explicit bonds.

(c)

Interpretation Introduction

Interpretation:

Condensed structural formula for the given compounds has to be written.

Concept Introduction:

Condensed structural formula is representation of the organic compound. In this the lengthy carbon chain is shown only with the carbon atoms (along with the hydrogen) without any bonds. The additional branches are shown with explicit bonds.

(d)

Interpretation Introduction

Interpretation:

Condensed structural formula for the given compounds has to be written.

Concept Introduction:

Condensed structural formula is representation of the organic compound. In this the lengthy carbon chain is shown only with the carbon atoms (along with the hydrogen) without any bonds. The additional branches are shown with explicit bonds.

(e)

Interpretation Introduction

Interpretation:

Condensed structural formula for the given compounds has to be written.

Concept Introduction:

Condensed structural formula is representation of the organic compound. In this the lengthy carbon chain is shown only with the carbon atoms (along with the hydrogen) without any bonds. The additional branches are shown with explicit bonds.

Answer 6

Chapter 23, Problem 23.82QP

(a)

Interpretation Introduction

Interpretation:

Condensed structural formula for the given compounds has to be written.

Concept Introduction:

Condensed structural formula is representation of the organic compound. In this the lengthy carbon chain is shown only with the carbon atoms (along with the hydrogen) without any bonds. The additional branches are shown with explicit bonds.

Answer 7

Chapter 23, Problem 23.82QP

(a)

Interpretation Introduction

Interpretation:

Condensed structural formula for the given compounds has to be written.

Concept Introduction:

Condensed structural formula is representation of the organic compound. In this the lengthy carbon chain is shown only with the carbon atoms (along with the hydrogen) without any bonds. The additional branches are shown with explicit bonds.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Condensed structural formula for the given compounds has to be written.

Concept Introduction:

Condensed structural formula is representation of the organic compound. In this the lengthy carbon chain is shown only with the carbon atoms (along with the hydrogen) without any bonds. The additional branches are shown with explicit bonds.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Condensed structural formula for the given compounds has to be written.

Concept Introduction:

Condensed structural formula is representation of the organic compound. In this the lengthy carbon chain is shown only with the carbon atoms (along with the hydrogen) without any bonds. The additional branches are shown with explicit bonds.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Condensed structural formula for the given compounds has to be written.

Concept Introduction:

Condensed structural formula is representation of the organic compound. In this the lengthy carbon chain is shown only with the carbon atoms (along with the hydrogen) without any bonds. The additional branches are shown with explicit bonds.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Condensed structural formula for the given compounds has to be written.

Concept Introduction:

Condensed structural formula is representation of the organic compound. In this the lengthy carbon chain is shown only with the carbon atoms (along with the hydrogen) without any bonds. The additional branches are shown with explicit bonds.

Answer 12

(d)

Interpretation Introduction

Interpretation:

Condensed structural formula for the given compounds has to be written.

Concept Introduction:

Condensed structural formula is representation of the organic compound. In this the lengthy carbon chain is shown only with the carbon atoms (along with the hydrogen) without any bonds. The additional branches are shown with explicit bonds.

Answer 13

(d)

Interpretation Introduction

Interpretation:

Condensed structural formula for the given compounds has to be written.

Concept Introduction:

Condensed structural formula is representation of the organic compound. In this the lengthy carbon chain is shown only with the carbon atoms (along with the hydrogen) without any bonds. The additional branches are shown with explicit bonds.

Answer 14

(e)

Interpretation Introduction

Interpretation:

Condensed structural formula for the given compounds has to be written.

Concept Introduction:

Condensed structural formula is representation of the organic compound. In this the lengthy carbon chain is shown only with the carbon atoms (along with the hydrogen) without any bonds. The additional branches are shown with explicit bonds.

Answer 15

(e)

Interpretation Introduction

Interpretation:

Condensed structural formula for the given compounds has to be written.

Concept Introduction:

Condensed structural formula is representation of the organic compound. In this the lengthy carbon chain is shown only with the carbon atoms (along with the hydrogen) without any bonds. The additional branches are shown with explicit bonds.

Answer 16

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Answer 21

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Answer 22

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Answer 23

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Answer 27

Ch. 23.2 - Prob. 23.1E Ch. 23.2 - In the model shown here, C atoms are black and H...Ch. 23.2 - Prob. 23.2CC Ch. 23.3 - Prob. 23.2E Ch. 23.3 - Prob. 23.3E Ch. 23.5 - Prob. 23.4E Ch. 23.5 - Prob. 23.5E Ch. 23.5 - Prob. 23.6E Ch. 23.5 - Prob. 23.7E Ch. 23.5 - Prob. 23.8E

Solution Summary: The author explains that condensed structural formula can be drawn considering the carbon skeleton in the given compound.

Concept explainers

Chapter 23 Solutions