(a) Interpretation: The source of junction potential in a glass-reference electrode system should be predicted. Concept introduction: Glass electrode consists of a glass bulb that contains a solution of hydrochloric acid with fixed concentration. It is a type of ion selective electrode. It measures the pH of the solution.

Question

Two reactants X and Z are required to convert the compound CH3-CH2-CH2Br to the compound CH3-CH2-CH=P(C6H5)3. State reactants X and Z.

Answer 1

Question

Chapter 23, Problem 23.7QAP

Interpretation Introduction

(a)

Interpretation:

The source of junction potential in a glass-reference electrode system should be predicted.

Concept introduction:

Glass electrode consists of a glass bulb that contains a solution of hydrochloric acid with fixed concentration. It is a type of ion selective electrode. It measures the pH of the solution.

Interpretation Introduction

(b)

Interpretation:

The source of boundary potential in a membrane electrode should be predicted.

Concept introduction:

Membrane electrodes consists a thin glass membrane and are used to measure the pH of the solution.

Interpretation Introduction

(c)

Interpretation:

The source of asymmetric potential in a glass-membrane electrode should be predicted.

Concept introduction:

Membrane electrodes consists a thin glass membrane and are used to measure the pH of the solution.

Interpretation Introduction

(d)

Interpretation:

The source of the potential of a crystalline membrane electrode that is used to determine the concentration of F− should be predicted.

Concept introduction:

Membrane electrodes consists a thin glass membrane and are used to measure the pH of the solution. Crystalline membrane are manufactured by the ionic compounds or a homogeneous mixture of ionic compounds.

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Two reactants X and Z are required to convert the compound CH3-CH2-CH2Br to the compound CH3-CH2-CH=P(C6H5)3. State reactants X and Z.

2. Write a reasonable mechanism that converts the reactants into the products. Avoid issues A-U from the previous page. You can use any number of steps (it does not have to be a one-step mechanism). Do not use any other chemicals (solvents, acids, bases, etc.) in your mechanism. 2 2 H ΗΘ

For the following reaction, the partial pressures were determined for the reaction components as shownbelow. Is the reaction at equilibrium? If not, in which direction will it proceed?I2 (g) + Cl2 (g) ⇋ 2 ICl (g) Kp = 81.9 partial pressures: I2 = 0.114 atm; Cl2 = 0.102 atm; ICl = 0.355 atm

Answer 2

Question

Chapter 23, Problem 23.7QAP

Interpretation Introduction

(a)

Interpretation:

The source of junction potential in a glass-reference electrode system should be predicted.

Concept introduction:

Glass electrode consists of a glass bulb that contains a solution of hydrochloric acid with fixed concentration. It is a type of ion selective electrode. It measures the pH of the solution.

Interpretation Introduction

(b)

Interpretation:

The source of boundary potential in a membrane electrode should be predicted.

Concept introduction:

Membrane electrodes consists a thin glass membrane and are used to measure the pH of the solution.

Interpretation Introduction

(c)

Interpretation:

The source of asymmetric potential in a glass-membrane electrode should be predicted.

Concept introduction:

Membrane electrodes consists a thin glass membrane and are used to measure the pH of the solution.

Interpretation Introduction

(d)

Interpretation:

The source of the potential of a crystalline membrane electrode that is used to determine the concentration of F− should be predicted.

Concept introduction:

Membrane electrodes consists a thin glass membrane and are used to measure the pH of the solution. Crystalline membrane are manufactured by the ionic compounds or a homogeneous mixture of ionic compounds.

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Answer 3

Question

Chapter 23, Problem 23.7QAP

Interpretation Introduction

(a)

Interpretation:

The source of junction potential in a glass-reference electrode system should be predicted.

Concept introduction:

Glass electrode consists of a glass bulb that contains a solution of hydrochloric acid with fixed concentration. It is a type of ion selective electrode. It measures the pH of the solution.

Interpretation Introduction

(b)

Interpretation:

The source of boundary potential in a membrane electrode should be predicted.

Concept introduction:

Membrane electrodes consists a thin glass membrane and are used to measure the pH of the solution.

Interpretation Introduction

(c)

Interpretation:

The source of asymmetric potential in a glass-membrane electrode should be predicted.

Concept introduction:

Membrane electrodes consists a thin glass membrane and are used to measure the pH of the solution.

Interpretation Introduction

(d)

Interpretation:

The source of the potential of a crystalline membrane electrode that is used to determine the concentration of F− should be predicted.

Concept introduction:

Membrane electrodes consists a thin glass membrane and are used to measure the pH of the solution. Crystalline membrane are manufactured by the ionic compounds or a homogeneous mixture of ionic compounds.

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Answer 4

Question

Chapter 23, Problem 23.7QAP

Interpretation Introduction

(a)

Interpretation:

The source of junction potential in a glass-reference electrode system should be predicted.

Concept introduction:

Glass electrode consists of a glass bulb that contains a solution of hydrochloric acid with fixed concentration. It is a type of ion selective electrode. It measures the pH of the solution.

Interpretation Introduction

(b)

Interpretation:

The source of boundary potential in a membrane electrode should be predicted.

Concept introduction:

Membrane electrodes consists a thin glass membrane and are used to measure the pH of the solution.

Interpretation Introduction

(c)

Interpretation:

The source of asymmetric potential in a glass-membrane electrode should be predicted.

Concept introduction:

Membrane electrodes consists a thin glass membrane and are used to measure the pH of the solution.

Interpretation Introduction

(d)

Interpretation:

The source of the potential of a crystalline membrane electrode that is used to determine the concentration of F− should be predicted.

Concept introduction:

Membrane electrodes consists a thin glass membrane and are used to measure the pH of the solution. Crystalline membrane are manufactured by the ionic compounds or a homogeneous mixture of ionic compounds.

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Answer 5

Chapter 23, Problem 23.7QAP

Interpretation Introduction

(a)

Interpretation:

The source of junction potential in a glass-reference electrode system should be predicted.

Concept introduction:

Glass electrode consists of a glass bulb that contains a solution of hydrochloric acid with fixed concentration. It is a type of ion selective electrode. It measures the pH of the solution.

Interpretation Introduction

(b)

Interpretation:

The source of boundary potential in a membrane electrode should be predicted.

Concept introduction:

Membrane electrodes consists a thin glass membrane and are used to measure the pH of the solution.

Interpretation Introduction

(c)

Interpretation:

The source of asymmetric potential in a glass-membrane electrode should be predicted.

Concept introduction:

Membrane electrodes consists a thin glass membrane and are used to measure the pH of the solution.

Interpretation Introduction

(d)

Interpretation:

The source of the potential of a crystalline membrane electrode that is used to determine the concentration of F− should be predicted.

Concept introduction:

Membrane electrodes consists a thin glass membrane and are used to measure the pH of the solution. Crystalline membrane are manufactured by the ionic compounds or a homogeneous mixture of ionic compounds.

Answer 6

Chapter 23, Problem 23.7QAP

Interpretation Introduction

(a)

Interpretation:

The source of junction potential in a glass-reference electrode system should be predicted.

Concept introduction:

Glass electrode consists of a glass bulb that contains a solution of hydrochloric acid with fixed concentration. It is a type of ion selective electrode. It measures the pH of the solution.

Answer 7

Chapter 23, Problem 23.7QAP

Interpretation Introduction

(a)

Interpretation:

The source of junction potential in a glass-reference electrode system should be predicted.

Concept introduction:

Glass electrode consists of a glass bulb that contains a solution of hydrochloric acid with fixed concentration. It is a type of ion selective electrode. It measures the pH of the solution.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The source of boundary potential in a membrane electrode should be predicted.

Concept introduction:

Membrane electrodes consists a thin glass membrane and are used to measure the pH of the solution.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The source of boundary potential in a membrane electrode should be predicted.

Concept introduction:

Membrane electrodes consists a thin glass membrane and are used to measure the pH of the solution.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The source of asymmetric potential in a glass-membrane electrode should be predicted.

Concept introduction:

Membrane electrodes consists a thin glass membrane and are used to measure the pH of the solution.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The source of asymmetric potential in a glass-membrane electrode should be predicted.

Concept introduction:

Membrane electrodes consists a thin glass membrane and are used to measure the pH of the solution.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The source of the potential of a crystalline membrane electrode that is used to determine the concentration of F− should be predicted.

Concept introduction:

Membrane electrodes consists a thin glass membrane and are used to measure the pH of the solution. Crystalline membrane are manufactured by the ionic compounds or a homogeneous mixture of ionic compounds.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The source of the potential of a crystalline membrane electrode that is used to determine the concentration of F− should be predicted.

Concept introduction:

Membrane electrodes consists a thin glass membrane and are used to measure the pH of the solution. Crystalline membrane are manufactured by the ionic compounds or a homogeneous mixture of ionic compounds.

Answer 14

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Answer 25

Ch. 23 - Prob. 23.1QAP Ch. 23 - Prob. 23.2QAP Ch. 23 - Prob. 23.3QAP Ch. 23 - Prob. 23.4QAP Ch. 23 - Prob. 23.5QAP Ch. 23 - Prob. 23.6QAP Ch. 23 - Prob. 23.7QAP Ch. 23 - Prob. 23.8QAP Ch. 23 - Prob. 23.9QAP Ch. 23 - List the advantages and disadvantages of a...

Concept explainers

(b)

Interpretation:

The source of boundary potential in a membrane electrode should be predicted.

Concept introduction:

Membrane electrodes consists a thin glass membrane and are used to measure the pH of the solution.

(c)

Interpretation:

The source of asymmetric potential in a glass-membrane electrode should be predicted.

Concept introduction:

Membrane electrodes consists a thin glass membrane and are used to measure the pH of the solution.

Chapter 23 Solutions

Concept explainers

(b) Interpretation: The source of boundary potential in a membrane electrode should be predicted. Concept introduction: Membrane electrodes consists a thin glass membrane and are used to measure the pH of the solution.

(c) Interpretation: The source of asymmetric potential in a glass-membrane electrode should be predicted. Concept introduction: Membrane electrodes consists a thin glass membrane and are used to measure the pH of the solution.

Chapter 23 Solutions

(b)

Interpretation:

The source of boundary potential in a membrane electrode should be predicted.

Concept introduction:

Membrane electrodes consists a thin glass membrane and are used to measure the pH of the solution.

(c)

Interpretation:

The source of asymmetric potential in a glass-membrane electrode should be predicted.

Concept introduction:

Membrane electrodes consists a thin glass membrane and are used to measure the pH of the solution.