(a) Interpretation: The set of chemical tests that would distinguish N - methylhexanamide, 1 - octanamine and N , N -dimethyl-1-hexanamine is to be stated. Concept introduction: Amines are the organic compounds that are formed by replacement of hydrogen from ammonia. Amides are the organic compounds that are formed by combination of carboxylic acids and amine. Amides are hydrolyzed either in acidic or basic media to yield carboxylic acids and amine or ammonium ion and carboxylate anions.

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Answer 1

Question

Chapter 23, Problem 23.48AP

Interpretation Introduction

(a)

Interpretation:

The set of chemical tests that would distinguish N- methylhexanamide, 1- octanamine and N,N-dimethyl-1-hexanamine is to be stated.

Concept introduction:

Amines are the organic compounds that are formed by replacement of hydrogen from ammonia. Amides are the organic compounds that are formed by combination of carboxylic acids and amine. Amides are hydrolyzed either in acidic or basic media to yield carboxylic acids and amine or ammonium ion and carboxylate anions.

Interpretation Introduction

(b)

Interpretation:

The set of chemical tests that would distinguish p- methylaniline, benzylamine, p- cresol, and anisole is to be stated.

Concept introduction:

Amines are the organic compounds that are formed by replacement of hydrogen from ammonia. Amines are basic in nature because the nitrogen can donate its lone pairs and also the ability of the nitrogen to accept the proton in water. The phenols are aromatic alcohols. Phenol is acidic in nature because it forms stable phenoxide ion by loss of a proton.

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There are 48 pairs of students in the following table. Each pair has quantitatively determined the mass of taurine in a 250 mL can of the popular energy drink marketed as “Munster” using High Performance Liquid Chromatography (HPLC). The class results are presented below: QUESTION: Summarise and report these results including an indication of measurement uncertainty. In both calculation samples calculate if an outlier is present, max value, number of samples, mean, standard deviation, g (suspect), g (critical) and t (critical). Mass of Taurine (mg) Mass of Taurine (mg) (Table continued) 152.01 152.23 151.87 151.45 154.11 152.64 152.98 153.24 152.88 151.45 153.49 152.48 150.68 152.33 151.52 153.63 152.48 151.68 153.17 153.40 153.77 153.67 152.34 153.16 152.57 153.02 152.86 151.50 151.23 152.57 152.72 151.54 146.47 152.38 152.44 152.54 152.53 152.54 151.32…

Indicate the rate expressions for reactions that have order 0, 1, and 2.

Answer 2

Question

Chapter 23, Problem 23.48AP

Interpretation Introduction

(a)

Interpretation:

The set of chemical tests that would distinguish N- methylhexanamide, 1- octanamine and N,N-dimethyl-1-hexanamine is to be stated.

Concept introduction:

Amines are the organic compounds that are formed by replacement of hydrogen from ammonia. Amides are the organic compounds that are formed by combination of carboxylic acids and amine. Amides are hydrolyzed either in acidic or basic media to yield carboxylic acids and amine or ammonium ion and carboxylate anions.

Interpretation Introduction

(b)

Interpretation:

The set of chemical tests that would distinguish p- methylaniline, benzylamine, p- cresol, and anisole is to be stated.

Concept introduction:

Amines are the organic compounds that are formed by replacement of hydrogen from ammonia. Amines are basic in nature because the nitrogen can donate its lone pairs and also the ability of the nitrogen to accept the proton in water. The phenols are aromatic alcohols. Phenol is acidic in nature because it forms stable phenoxide ion by loss of a proton.

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Answer 3

Question

Chapter 23, Problem 23.48AP

Interpretation Introduction

(a)

Interpretation:

The set of chemical tests that would distinguish N- methylhexanamide, 1- octanamine and N,N-dimethyl-1-hexanamine is to be stated.

Concept introduction:

Amines are the organic compounds that are formed by replacement of hydrogen from ammonia. Amides are the organic compounds that are formed by combination of carboxylic acids and amine. Amides are hydrolyzed either in acidic or basic media to yield carboxylic acids and amine or ammonium ion and carboxylate anions.

Interpretation Introduction

(b)

Interpretation:

The set of chemical tests that would distinguish p- methylaniline, benzylamine, p- cresol, and anisole is to be stated.

Concept introduction:

Amines are the organic compounds that are formed by replacement of hydrogen from ammonia. Amines are basic in nature because the nitrogen can donate its lone pairs and also the ability of the nitrogen to accept the proton in water. The phenols are aromatic alcohols. Phenol is acidic in nature because it forms stable phenoxide ion by loss of a proton.

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Answer 4

Question

Chapter 23, Problem 23.48AP

Interpretation Introduction

(a)

Interpretation:

The set of chemical tests that would distinguish N- methylhexanamide, 1- octanamine and N,N-dimethyl-1-hexanamine is to be stated.

Concept introduction:

Amines are the organic compounds that are formed by replacement of hydrogen from ammonia. Amides are the organic compounds that are formed by combination of carboxylic acids and amine. Amides are hydrolyzed either in acidic or basic media to yield carboxylic acids and amine or ammonium ion and carboxylate anions.

Interpretation Introduction

(b)

Interpretation:

The set of chemical tests that would distinguish p- methylaniline, benzylamine, p- cresol, and anisole is to be stated.

Concept introduction:

Amines are the organic compounds that are formed by replacement of hydrogen from ammonia. Amines are basic in nature because the nitrogen can donate its lone pairs and also the ability of the nitrogen to accept the proton in water. The phenols are aromatic alcohols. Phenol is acidic in nature because it forms stable phenoxide ion by loss of a proton.

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Answer 5

Chapter 23, Problem 23.48AP

Interpretation Introduction

(a)

Interpretation:

The set of chemical tests that would distinguish N- methylhexanamide, 1- octanamine and N,N-dimethyl-1-hexanamine is to be stated.

Concept introduction:

Amines are the organic compounds that are formed by replacement of hydrogen from ammonia. Amides are the organic compounds that are formed by combination of carboxylic acids and amine. Amides are hydrolyzed either in acidic or basic media to yield carboxylic acids and amine or ammonium ion and carboxylate anions.

Interpretation Introduction

(b)

Interpretation:

The set of chemical tests that would distinguish p- methylaniline, benzylamine, p- cresol, and anisole is to be stated.

Concept introduction:

Amines are the organic compounds that are formed by replacement of hydrogen from ammonia. Amines are basic in nature because the nitrogen can donate its lone pairs and also the ability of the nitrogen to accept the proton in water. The phenols are aromatic alcohols. Phenol is acidic in nature because it forms stable phenoxide ion by loss of a proton.

Answer 6

Chapter 23, Problem 23.48AP

Interpretation Introduction

(a)

Interpretation:

The set of chemical tests that would distinguish N- methylhexanamide, 1- octanamine and N,N-dimethyl-1-hexanamine is to be stated.

Concept introduction:

Amines are the organic compounds that are formed by replacement of hydrogen from ammonia. Amides are the organic compounds that are formed by combination of carboxylic acids and amine. Amides are hydrolyzed either in acidic or basic media to yield carboxylic acids and amine or ammonium ion and carboxylate anions.

Answer 7

Chapter 23, Problem 23.48AP

Interpretation Introduction

(a)

Interpretation:

The set of chemical tests that would distinguish N- methylhexanamide, 1- octanamine and N,N-dimethyl-1-hexanamine is to be stated.

Concept introduction:

Amines are the organic compounds that are formed by replacement of hydrogen from ammonia. Amides are the organic compounds that are formed by combination of carboxylic acids and amine. Amides are hydrolyzed either in acidic or basic media to yield carboxylic acids and amine or ammonium ion and carboxylate anions.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The set of chemical tests that would distinguish p- methylaniline, benzylamine, p- cresol, and anisole is to be stated.

Concept introduction:

Amines are the organic compounds that are formed by replacement of hydrogen from ammonia. Amines are basic in nature because the nitrogen can donate its lone pairs and also the ability of the nitrogen to accept the proton in water. The phenols are aromatic alcohols. Phenol is acidic in nature because it forms stable phenoxide ion by loss of a proton.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The set of chemical tests that would distinguish p- methylaniline, benzylamine, p- cresol, and anisole is to be stated.

Concept introduction:

Amines are the organic compounds that are formed by replacement of hydrogen from ammonia. Amines are basic in nature because the nitrogen can donate its lone pairs and also the ability of the nitrogen to accept the proton in water. The phenols are aromatic alcohols. Phenol is acidic in nature because it forms stable phenoxide ion by loss of a proton.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 23 - Prob. 23.1P Ch. 23 - Prob. 23.2P Ch. 23 - Prob. 23.3P Ch. 23 - Prob. 23.4P Ch. 23 - Prob. 23.5P Ch. 23 - Prob. 23.6P Ch. 23 - Prob. 23.7P Ch. 23 - Prob. 23.8P Ch. 23 - Prob. 23.9P Ch. 23 - Prob. 23.10P

Solution Summary: The author explains the set of chemical tests that would distinguish N- methylhexanamide, 1

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Chapter 23 Solutions