(a) Interpretation: The reaction for the preparation of 2, 4-dinitroaniline from aniline is to be stated. Concept introduction: The replacement of hydrogen atom attached to a carbon atom of electron-rich benzene ring by an electrophile is known as electrophilic aromatic substitution reaction. The rate of electrophilic aromatic substitution reaction depends on the substituted group on the aromatic ring. The ring deactivating group retards the electrophilic aromatic substitution reaction and ring activating group enhances the electrophilic aromatic substitution reaction.

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Answer 1

Question

Chapter 23, Problem 23.28P

Interpretation Introduction

(a)

Interpretation:

The reaction for the preparation of 2, 4-dinitroaniline from aniline is to be stated.

Concept introduction:

The replacement of hydrogen atom attached to a carbon atom of electron-rich benzene ring by an electrophile is known as electrophilic aromatic substitution reaction. The rate of electrophilic aromatic substitution reaction depends on the substituted group on the aromatic ring. The ring deactivating group retards the electrophilic aromatic substitution reaction and ring activating group enhances the electrophilic aromatic substitution reaction.

Interpretation Introduction

(b)

Interpretation:

The reaction for the preparation of sulfathiazole from aniline is to be stated.

Concept introduction:

The replacement of hydrogen atom attached to a carbon atom of electron-rich benzene ring by an electrophile is known as electrophilic aromatic substitution reaction. The rate of electrophilic aromatic substitution reaction depends on the substituted group on the aromatic ring. The ring deactivating group retards the electrophilic aromatic substitution reaction and ring activating group enhances the electrophilic aromatic substitution reaction.

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Circle the letter next to the most appropriate response. 1) Which is likely to be the least soluble with water? a) hexane b) acetone c) trichloromethane d) trinitro-toluene 2) Which is likely to be the most soluble in 3,4-dimethyloctane? a) hexane b) acetone c) trichloromethane d) trinitro-toluene 3) When ammonium nitrate is dissolved in water, the solution: a) gets warmer. b) gets colder. c) stays the same temperature. d) is none of the above because potassium nitrate is insoluble.

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Answer 2

Question

Chapter 23, Problem 23.28P

Interpretation Introduction

(a)

Interpretation:

The reaction for the preparation of 2, 4-dinitroaniline from aniline is to be stated.

Concept introduction:

The replacement of hydrogen atom attached to a carbon atom of electron-rich benzene ring by an electrophile is known as electrophilic aromatic substitution reaction. The rate of electrophilic aromatic substitution reaction depends on the substituted group on the aromatic ring. The ring deactivating group retards the electrophilic aromatic substitution reaction and ring activating group enhances the electrophilic aromatic substitution reaction.

Interpretation Introduction

(b)

Interpretation:

The reaction for the preparation of sulfathiazole from aniline is to be stated.

Concept introduction:

The replacement of hydrogen atom attached to a carbon atom of electron-rich benzene ring by an electrophile is known as electrophilic aromatic substitution reaction. The rate of electrophilic aromatic substitution reaction depends on the substituted group on the aromatic ring. The ring deactivating group retards the electrophilic aromatic substitution reaction and ring activating group enhances the electrophilic aromatic substitution reaction.

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Answer 3

Question

Chapter 23, Problem 23.28P

Interpretation Introduction

(a)

Interpretation:

The reaction for the preparation of 2, 4-dinitroaniline from aniline is to be stated.

Concept introduction:

The replacement of hydrogen atom attached to a carbon atom of electron-rich benzene ring by an electrophile is known as electrophilic aromatic substitution reaction. The rate of electrophilic aromatic substitution reaction depends on the substituted group on the aromatic ring. The ring deactivating group retards the electrophilic aromatic substitution reaction and ring activating group enhances the electrophilic aromatic substitution reaction.

Interpretation Introduction

(b)

Interpretation:

The reaction for the preparation of sulfathiazole from aniline is to be stated.

Concept introduction:

The replacement of hydrogen atom attached to a carbon atom of electron-rich benzene ring by an electrophile is known as electrophilic aromatic substitution reaction. The rate of electrophilic aromatic substitution reaction depends on the substituted group on the aromatic ring. The ring deactivating group retards the electrophilic aromatic substitution reaction and ring activating group enhances the electrophilic aromatic substitution reaction.

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Answer 4

Question

Chapter 23, Problem 23.28P

Interpretation Introduction

(a)

Interpretation:

The reaction for the preparation of 2, 4-dinitroaniline from aniline is to be stated.

Concept introduction:

The replacement of hydrogen atom attached to a carbon atom of electron-rich benzene ring by an electrophile is known as electrophilic aromatic substitution reaction. The rate of electrophilic aromatic substitution reaction depends on the substituted group on the aromatic ring. The ring deactivating group retards the electrophilic aromatic substitution reaction and ring activating group enhances the electrophilic aromatic substitution reaction.

Interpretation Introduction

(b)

Interpretation:

The reaction for the preparation of sulfathiazole from aniline is to be stated.

Concept introduction:

The replacement of hydrogen atom attached to a carbon atom of electron-rich benzene ring by an electrophile is known as electrophilic aromatic substitution reaction. The rate of electrophilic aromatic substitution reaction depends on the substituted group on the aromatic ring. The ring deactivating group retards the electrophilic aromatic substitution reaction and ring activating group enhances the electrophilic aromatic substitution reaction.

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Answer 5

Chapter 23, Problem 23.28P

Interpretation Introduction

(a)

Interpretation:

The reaction for the preparation of 2, 4-dinitroaniline from aniline is to be stated.

Concept introduction:

The replacement of hydrogen atom attached to a carbon atom of electron-rich benzene ring by an electrophile is known as electrophilic aromatic substitution reaction. The rate of electrophilic aromatic substitution reaction depends on the substituted group on the aromatic ring. The ring deactivating group retards the electrophilic aromatic substitution reaction and ring activating group enhances the electrophilic aromatic substitution reaction.

Interpretation Introduction

(b)

Interpretation:

The reaction for the preparation of sulfathiazole from aniline is to be stated.

Concept introduction:

The replacement of hydrogen atom attached to a carbon atom of electron-rich benzene ring by an electrophile is known as electrophilic aromatic substitution reaction. The rate of electrophilic aromatic substitution reaction depends on the substituted group on the aromatic ring. The ring deactivating group retards the electrophilic aromatic substitution reaction and ring activating group enhances the electrophilic aromatic substitution reaction.

Answer 6

Chapter 23, Problem 23.28P

Interpretation Introduction

(a)

Interpretation:

The reaction for the preparation of 2, 4-dinitroaniline from aniline is to be stated.

Concept introduction:

The replacement of hydrogen atom attached to a carbon atom of electron-rich benzene ring by an electrophile is known as electrophilic aromatic substitution reaction. The rate of electrophilic aromatic substitution reaction depends on the substituted group on the aromatic ring. The ring deactivating group retards the electrophilic aromatic substitution reaction and ring activating group enhances the electrophilic aromatic substitution reaction.

Answer 7

Chapter 23, Problem 23.28P

Interpretation Introduction

(a)

Interpretation:

The reaction for the preparation of 2, 4-dinitroaniline from aniline is to be stated.

Concept introduction:

The replacement of hydrogen atom attached to a carbon atom of electron-rich benzene ring by an electrophile is known as electrophilic aromatic substitution reaction. The rate of electrophilic aromatic substitution reaction depends on the substituted group on the aromatic ring. The ring deactivating group retards the electrophilic aromatic substitution reaction and ring activating group enhances the electrophilic aromatic substitution reaction.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The reaction for the preparation of sulfathiazole from aniline is to be stated.

Concept introduction:

The replacement of hydrogen atom attached to a carbon atom of electron-rich benzene ring by an electrophile is known as electrophilic aromatic substitution reaction. The rate of electrophilic aromatic substitution reaction depends on the substituted group on the aromatic ring. The ring deactivating group retards the electrophilic aromatic substitution reaction and ring activating group enhances the electrophilic aromatic substitution reaction.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The reaction for the preparation of sulfathiazole from aniline is to be stated.

Concept introduction:

The replacement of hydrogen atom attached to a carbon atom of electron-rich benzene ring by an electrophile is known as electrophilic aromatic substitution reaction. The rate of electrophilic aromatic substitution reaction depends on the substituted group on the aromatic ring. The ring deactivating group retards the electrophilic aromatic substitution reaction and ring activating group enhances the electrophilic aromatic substitution reaction.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 23 - Prob. 23.1P Ch. 23 - Prob. 23.2P Ch. 23 - Prob. 23.3P Ch. 23 - Prob. 23.4P Ch. 23 - Prob. 23.5P Ch. 23 - Prob. 23.6P Ch. 23 - Prob. 23.7P Ch. 23 - Prob. 23.8P Ch. 23 - Prob. 23.9P Ch. 23 - Prob. 23.10P

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Chapter 23 Solutions