
Concept explainers
(a)
Interpretation:
The orbital overlap picture of Tryptophan is to be drawn.
Concept introduction:
In chemistry, overlapping of orbital takes place to form bonds between the atoms. At least two orbitals must overlap with each other to form a bond. The examples of orbitals are s, p, d, f orbitals. Sigma bond involves the head to head overlapping of two orbitals; on the other hand, π-bond involves the side to side or lateral overlapping of two orbitals.
(b)
Interpretation:
The aromaticity of tryptophan is to be discussed using orbital overlap diagram.
Concept introduction:
The aromaticity is the phenomena in which compound has odor. The word aromaticity is derived from the word aroma, means odor.

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Chapter 23 Solutions
CHEMISTRY-W/MASTERING CHEMISTRY ACCESS
- Soap is made by the previous reaction *see image. The main difference between one soap and another soap isthe length (number of carbons) of the carboxylic acid. However, if a soap irritates your skin, they mostlikely used too much lye.Detergents have the same chemical structure as soaps except for the functional group. Detergentshave sulfate (R-SO4H) and phosphate (R-PO4H2) functional groups. Draw the above carboxylic acidcarbon chain but as the two variants of detergents. *see imagearrow_forwardWhat are the reactions or reagents used? *see imagearrow_forwardWhat are the reactions or reagents used? *see imagearrow_forward
- Provide the mechanism for this transformation: *see imagearrow_forwardAssign all the signals individually (please assign the red, green and blue)arrow_forwardThe two pKa values of oxalic acid are 1.25 and 3.81. Why are they not the same value? Show the protontransfer as part of your explanation. *see imagearrow_forward
- .. Give the major organic product(s) for each of the following reactions or sequences of reactions. Show ll relevant stereochemistry [3 ONLY]. A H Br 1. NaCN 2 NaOH, H₂O, heat 3. H3O+ B. CH₂COOH 19000 1. LiAlH4 THF, heat 2 H₂O* C. CH Br 1. NaCN, acetone 2 H3O+, heat D. Br 1. Mg. ether 3. H₂O+ 2 CO₂ E. CN 1. (CH) CHMgBr, ether 2 H₂O+arrow_forwardAssign this COSY spectrumarrow_forwardCan I please get help with this?arrow_forward
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