Quantitative Chemical Analysis
Quantitative Chemical Analysis
9th Edition
ISBN: 9781464135385
Author: Daniel C. Harris
Publisher: W. H. Freeman
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Chapter 23, Problem 23.18P
Interpretation Introduction

Interpretation:

The larger the partition coefficient, the longer it takes a solute to be eluted. Reason for this observation has to be given.

Concept introduction:

Partition coefficient:

Partition of a solute is depends on “like dissolves like” concept.  This means the solubility of solute is more in a solvent whose polarity is similar to that of the solute.

The partition coefficient of solute (S) is given by

Solute(inphase1)Solute(inphase2)

K=AS2AS1[S]2[S]1where,K-partitioncoefficientAS1-Activityofsoluteinphase1AS2-Activityofsoluteinphase2[S]1-Concentrationofsoluteinphase1[S]2-Concentrationofsoluteinphase2

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Determine if the following salt is neutral, acidic or basic. If acidic or basic, write the appropriate equilibrium equation for the acid or base that exists when the salt is dissolved in aqueous solution. If neutral, simply write only NR. Be sure to include the proper phases for all species within the reaction. N₂H₅ClO₄
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