ORGANIC CHEMISTRY-WILEYPLUS ACCESS PKG.
ORGANIC CHEMISTRY-WILEYPLUS ACCESS PKG.
12th Edition
ISBN: 9781119766919
Author: Solomons
Publisher: WILEY
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Chapter 23, Problem 20P

α -Phellandrene and β -phellandrene are isomeric compounds that are minor constituents of spearmint oil; they have the molecular formula C 10 H 16 . Each compound has a UV absorption maximum in the 230–270 nm range. On catalytic hydrogenation, each compound yields 1-isopropyl-4-methylcyclohexane. On vigorous oxidation with potassium permanganate, α -phellandrene yields

Chapter 23, Problem 20P, 23.20	-Phellandrene and -phellandrene are isomeric compounds that are minor constituents of

Propose structures for α -and β -phellandrene.

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3. Titanium(III) chloride can be used to catalyze the polymerization of ethylene. It is prepared by hydrogen reduction of Titanium(IV) chloride. Reaction of hydrogen gas with titanium(IV) chloride gas produces solid titanium(III) chloride and hydrogen chloride gas. (a) Write a BALANCED chemical reaction for the preparation of titanium(III) chloride (b) A 250 L reaction vessel at 325°C is filled with hydrogen gas to a pressure of 1.3 atm. Titanium(IV) chloride is then added to bring the total pressure to 3.00 atm. How many grams of titanium(III) chloride will be produced after completion of the reaction? (c) What will be the pressure of the resulting hydrogen chloride gas that is also produced?
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