ORGANIC CHEMISTRY-WILEYPLUS ACCESS PKG.
ORGANIC CHEMISTRY-WILEYPLUS ACCESS PKG.
12th Edition
ISBN: 9781119766919
Author: Solomons
Publisher: WILEY
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Chapter 23, Problem 16P
Interpretation Introduction

Interpretation:

Using palmitoleic acid as an example, each of the given reaction of the double bond is to be illustrated.

Concept introduction:

Palmitoleic acid is a solid fat that is formed of a combination of 66% saturated fat (palmitic acid) and 34% unsaturated fat (oleic acid). The structural formula of palmitoleic acid can be given as follows:

ORGANIC CHEMISTRY-WILEYPLUS ACCESS PKG., Chapter 23, Problem 16P

Solid fats are the triacylglycerols and are solid at room temperature. Oil or liquid fat from plant source undergoes catalytic hydrogenation in order to get converted into solid fat. It needs extensive application to convert vegetable oil into solid commercial cooking fat for the longer shelf life of the fat/oil.

All fatty acids undergo reactions typical of carboxylic acids, such as with alcohols, mineral acids and bromine and phosphorus.

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3. Titanium(III) chloride can be used to catalyze the polymerization of ethylene. It is prepared by hydrogen reduction of Titanium(IV) chloride. Reaction of hydrogen gas with titanium(IV) chloride gas produces solid titanium(III) chloride and hydrogen chloride gas. (a) Write a BALANCED chemical reaction for the preparation of titanium(III) chloride (b) A 250 L reaction vessel at 325°C is filled with hydrogen gas to a pressure of 1.3 atm. Titanium(IV) chloride is then added to bring the total pressure to 3.00 atm. How many grams of titanium(III) chloride will be produced after completion of the reaction? (c) What will be the pressure of the resulting hydrogen chloride gas that is also produced?
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