A plausible method for converting nitrobenzene into para-chloroaniline has to be found. Concept Introduction : Nitro group on reduction with Fe, Zn, Sn or SnCl 2 in the presence of HCl gives an amino group. Acetylation of an aromatic ring leads to the introduction of acetyl group in the functional group attached to the ring such as in amino group. This is achieved by using acetyl chloride. Chlorine is used for chlorination reaction. It leads the aromatic ring for the introduction of chloro group. Deacetylation means the removal of acetyl group which is done by aqueous acidic or basic conditions. To find: Convert nitrobenzene into para-chloroaniline by a plausible method Do the reduction for nitro group

Question

Want to see the full answer?

Answer 1

Question

Chapter 22.8, Problem 21CC

Interpretation Introduction

Interpretation: A plausible method for converting nitrobenzene into para-chloroaniline has to be found.

Concept Introduction:

Nitro group on reduction with Fe, Zn, Sn or SnCl₂ in the presence of HCl gives an amino group. Acetylation of an aromatic ring leads to the introduction of acetyl group in the functional group attached to the ring such as in amino group. This is achieved by using acetyl chloride. Chlorine is used for chlorination reaction. It leads the aromatic ring for the introduction of chloro group. Deacetylation means the removal of acetyl group which is done by aqueous acidic or basic conditions.

To find: Convert nitrobenzene into para-chloroaniline by a plausible method

Do the reduction for nitro group

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

Protecting Groups and Carbonyls 6) The synthesis generates allethrolone that exhibits high insect toxicity but low mammalian toxicity. They are used in pet shampoo, human lice shampoo, and industrial sprays for insects and mosquitos. Propose detailed mechanistic steps to generate the allethrolone label the different types of reagents (Grignard, acid/base protonation, acid/base deprotonation, reduction, oxidation, witting, aldol condensation, Robinson annulation, etc.) III + VI HS HS H+ CH,CH,Li III I II IV CI + P(Ph)3 V ༼ Hint: no strong base added VI S VII IX HO VIII -MgBr HgCl2,HgO HO. isomerization aqeuous solution H,SO, ༽༽༤༽༽ X MeOH Hint: enhances selectivity for reaction at the S X ☑

Draw the complete mechanism for the acid-catalyzed hydration of this alkene. esc 田 Explanation Check 1 888 Q A slock Add/Remove step Q F4 F5 F6 A བྲA F7 $ % 5 @ 4 2 3 & 6 87 Click and drag to start drawing a structure. © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Ce W E R T Y U S D LL G H IK DD 요 F8 F9 F10 F1 * ( 8 9 0 O P J K L Z X C V B N M H He command

Explanation Check F1 H₂O H₂ Pd 1) MCPBA 2) H3O+ 1) Hg(OAc)2, H₂O 2) NaBH4 OH CI OH OH OH hydration halohydrin formation addition halogenation hydrogenation inhalation hydrogenation hydration ☐ halohydrin formation addition halogenation formation chelation hydrogenation halohydrin formation substitution hydration halogenation addition Ohalohydrin formation subtraction halogenation addition hydrogenation hydration F2 80 F3 σ F4 F5 F6 1 ! 2 # 3 $ 4 % 05 Q W & Å © 2025 McGraw Hill LLC. All Rights Reserved. F7 F8 ( 6 7 8 9 LU E R T Y U A F9