Organic Chemistry Plus Masteringchemistry With Pearson Etext, Global Edition
Organic Chemistry Plus Masteringchemistry With Pearson Etext, Global Edition
9th Edition
ISBN: 9781292151229
Author: Wade, LeRoy G.
Publisher: PEARSON
Question
Book Icon
Chapter 22.18, Problem 22.56P

(a)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

(b)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

(c)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

(d)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

(e)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

(f)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

Blurred answer
Students have asked these similar questions
For each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. ? NH2 MgBr Will the first product that forms in this reaction create a new CC bond? ○ Yes ○ No MgBr ? Will the first product that forms in this reaction create a new CC bond? O Yes O No Click and drag to start drawing a structure. :☐ G x c olo Ar HE
Predicting As the lead product manager at OrganometALEKS Industries, you are trying to decide if the following reaction will make a molecule with a new C - C bond as its major product: H₂N O H 1. ? 2. H3O+ If this reaction will work, draw the major organic product or products you would expect in the drawing area below. If there's more than one major product, you can draw them in any arrangement you like. Be sure you use wedge and dash bonds if necessary, for example to distinguish between major products with different stereochemistry. 0 If the major products of this reaction won't have a new CC bond, just check the box under the drawing area and leave it blank. فا Explanation Check Click and drag to start drawing a structure.
Highlight the chirality (or stereogenic) center(s) in the given compound. A compound may have one or more stereogenic centers. OH OH OH OH OH OH

Chapter 22 Solutions

Organic Chemistry Plus Masteringchemistry With Pearson Etext, Global Edition

Ch. 22.5C - Acid-catalyzed halogenation is synthetically...Ch. 22.6 - Show the products of the reactions of these...Ch. 22.7A - Prob. 22.18PCh. 22.7A - Prob. 22.19PCh. 22.7A - Prob. 22.20PCh. 22.7B - Prob. 22.21PCh. 22.8 - Prob. 22.22PCh. 22.8 - Prob. 22.24PCh. 22.9 - Prob. 22.25PCh. 22.9 - Prob. 22.26PCh. 22.9 - Prob. 22.27PCh. 22.9 - Prob. 22.28PCh. 22.9 - Prob. 22.29PCh. 22.10 - When cyclodecane-1,6-dione is treated with sodium...Ch. 22.11 - Prob. 22.32PCh. 22.11 - Prob. 22.33PCh. 22.12 - Prob. 22.34PCh. 22.12 - Prob. 22.35PCh. 22.12 - Prob. 22.36PCh. 22.12 - Prob. 22.37PCh. 22.12 - Show what esters would undergo Claisen...Ch. 22.13 - Prob. 22.39PCh. 22.13 - Prob. 22.40PCh. 22.14 - Prob. 22.41PCh. 22.14 - Prob. 22.42PCh. 22.14 - Show how crossed Claisen condensations could be...Ch. 22.14 - Prob. 22.44PCh. 22.14 - Prob. 22.45PCh. 22.15 - Prob. 22.46PCh. 22.16 - Prob. 22.47PCh. 22.16 - Prob. 22.48PCh. 22.17 - Prob. 22.49PCh. 22.17 - Prob. 22.50PCh. 22.17 - Prob. 22.51PCh. 22.18 - Prob. 22.52PCh. 22.18 - Prob. 22.53PCh. 22.18 - Prob. 22.54PCh. 22.18 - Prob. 22.55PCh. 22.18 - Prob. 22.56PCh. 22.19 - Prob. 22.57PCh. 22.19 - Prob. 22.58PCh. 22.19 - Prob. 22.59PCh. 22 - Prob. 22.60SPCh. 22 - 1. Rank the following compounds in order of...Ch. 22 - Prob. 22.62SPCh. 22 - Prob. 22.63SPCh. 22 - Prob. 22.64SPCh. 22 - Pentane-2,4-dione (acetylacetone) exists as a...Ch. 22 - a. Rank these compounds in order of increasing...Ch. 22 - Prob. 22.67SPCh. 22 - Prob. 22.68SPCh. 22 - 22-69 Predict the products of the following...Ch. 22 - Predict the products of these reaction sequences.Ch. 22 - Show how you would accomplish the following...Ch. 22 - Prob. 22.72SPCh. 22 - Prob. 22.73SPCh. 22 - Prob. 22.74SPCh. 22 - The Knoevenagel condensation is a special case of...Ch. 22 - Prob. 22.76SPCh. 22 - Propose mechanisms for the following reactions.Ch. 22 - Prob. 22.78SPCh. 22 - Show how you would accomplish the following...Ch. 22 - Prob. 22.80SPCh. 22 - Propose a mechanism for the following reaction....Ch. 22 - Prob. 22.83SPCh. 22 - Prob. 22.84SPCh. 22 - Prob. 22.85SP
Knowledge Booster
Background pattern image
Similar questions
SEE MORE QUESTIONS
Recommended textbooks for you
  • Text book image
    Organic Chemistry
    Chemistry
    ISBN:9781305080485
    Author:John E. McMurry
    Publisher:Cengage Learning
    Text book image
    Organic Chemistry
    Chemistry
    ISBN:9781305580350
    Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
    Publisher:Cengage Learning
Text book image
Organic Chemistry
Chemistry
ISBN:9781305080485
Author:John E. McMurry
Publisher:Cengage Learning
Text book image
Organic Chemistry
Chemistry
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:Cengage Learning