With the help of Robinson annulation the given compound is to be synthesized. Concept introduction: Condensation reaction takes place when methyl vinyl ketone or substituted methyl vinyl ketone derivative reacts with a ketone. The product formed is cyclohexanone ring. Robinson annulation occurs through Michael addition to methyl vinyl ketone followed by aldol condensation and dehydration.

Question

4. Draw and label all possible isomers for [M(py)3(DMSO)2(CI)] (py = pyridine, DMSO dimethylsulfoxide).

Answer 1

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 22, Problem 22.67SP

(a)

Interpretation Introduction

Interpretation:

With the help of Robinson annulation the given compound is to be synthesized.

Concept introduction:

Condensation reaction takes place when methyl vinyl ketone or substituted methyl vinyl ketone derivative reacts with a ketone. The product formed is cyclohexanone ring. Robinson annulation occurs through Michael addition to methyl vinyl ketone followed by aldol condensation and dehydration.

(b)

Interpretation Introduction

Interpretation:

With the help of Robinson annulation the given compound is to be synthesized.

Concept introduction:

Condensation reaction takes place when methyl vinyl ketone or substituted methyl vinyl ketone derivative reacts with a ketone. The product formed is cyclohexanone ring. Robinson annulation occurs through Michael addition to methyl vinyl ketone followed by aldol condensation and dehydration.

(c)

Interpretation Introduction

Interpretation:

With the help of Robinson annulation the given compound is to be synthesized.

Concept introduction:

Condensation reaction takes place when methyl vinyl ketone or substituted methyl vinyl ketone derivative reacts with a ketone. The product formed is cyclohexanone ring. Robinson annulation occurs through Michael addition to methyl vinyl ketone followed by aldol condensation and dehydration.

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4. Draw and label all possible isomers for [M(py)3(DMSO)2(CI)] (py = pyridine, DMSO dimethylsulfoxide).

The emission data in cps displayed in Table 1 is reported to two decimal places by the chemist. However, the instrument output is shown in Table 2. Table 2. Iron emission from ICP-AES Sample Blank Standard Emission, cps 579.503252562 9308340.13122 Unknown Sample 343.232365741 Did the chemist make the correct choice in how they choose to display the data up in Table 1? Choose the best explanation from the choices below. No. Since the instrument calculates 12 digits for all values, they should all be kept and not truncated. Doing so would eliminate significant information. No. Since the instrument calculates 5 decimal places for the standard, all of the values should be limited to the same number. The other decimal places are not significant for the blank and unknown sample. Yes. The way Saman made the standards was limited by the 250-mL volumetric flask. This glassware can report values to 2 decimal places, and this establishes our number of significant figures. Yes. Instrumental data…

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Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 22, Problem 22.67SP

(a)

Interpretation Introduction

Interpretation:

With the help of Robinson annulation the given compound is to be synthesized.

Concept introduction:

Condensation reaction takes place when methyl vinyl ketone or substituted methyl vinyl ketone derivative reacts with a ketone. The product formed is cyclohexanone ring. Robinson annulation occurs through Michael addition to methyl vinyl ketone followed by aldol condensation and dehydration.

(b)

Interpretation Introduction

Interpretation:

With the help of Robinson annulation the given compound is to be synthesized.

Concept introduction:

Condensation reaction takes place when methyl vinyl ketone or substituted methyl vinyl ketone derivative reacts with a ketone. The product formed is cyclohexanone ring. Robinson annulation occurs through Michael addition to methyl vinyl ketone followed by aldol condensation and dehydration.

(c)

Interpretation Introduction

Interpretation:

With the help of Robinson annulation the given compound is to be synthesized.

Concept introduction:

Condensation reaction takes place when methyl vinyl ketone or substituted methyl vinyl ketone derivative reacts with a ketone. The product formed is cyclohexanone ring. Robinson annulation occurs through Michael addition to methyl vinyl ketone followed by aldol condensation and dehydration.

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 22, Problem 22.67SP

(a)

Interpretation Introduction

Interpretation:

With the help of Robinson annulation the given compound is to be synthesized.

Concept introduction:

Condensation reaction takes place when methyl vinyl ketone or substituted methyl vinyl ketone derivative reacts with a ketone. The product formed is cyclohexanone ring. Robinson annulation occurs through Michael addition to methyl vinyl ketone followed by aldol condensation and dehydration.

(b)

Interpretation Introduction

Interpretation:

With the help of Robinson annulation the given compound is to be synthesized.

Concept introduction:

Condensation reaction takes place when methyl vinyl ketone or substituted methyl vinyl ketone derivative reacts with a ketone. The product formed is cyclohexanone ring. Robinson annulation occurs through Michael addition to methyl vinyl ketone followed by aldol condensation and dehydration.

(c)

Interpretation Introduction

Interpretation:

With the help of Robinson annulation the given compound is to be synthesized.

Concept introduction:

Condensation reaction takes place when methyl vinyl ketone or substituted methyl vinyl ketone derivative reacts with a ketone. The product formed is cyclohexanone ring. Robinson annulation occurs through Michael addition to methyl vinyl ketone followed by aldol condensation and dehydration.

Expert Solution & Answer

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 22, Problem 22.67SP

(a)

Interpretation Introduction