Chemistry
Chemistry
4th Edition
ISBN: 9780078021527
Author: Julia Burdge
Publisher: McGraw-Hill Education
bartleby

Concept explainers

bartleby

Videos

Question
Book Icon
Chapter 22, Problem 24QP
Interpretation Introduction

Interpretation:

The structures of geometric and optical isomers of the given complexes are to be represented.

Concept introduction:

Stereoisomerism exists as two forms; geometric and optical. Geometric isomerism occurs due to breaking of chemical bonds, causing change in structural positioning of the ligands. When two ligands are placed adjacent to each other, they are called cis-isomers and when they are placed opposite to each other, they are called trans-isomers. It is more common in square planar and octahedral and less in tetrahedral complexes.

Optical isomerism is exhibited by complexes that can rotate the plane of polarized light into clockwise and anticlockwise directions. Optical isomers are non-superimposable mirror images of each other and are most common in octahedral compounds having six coordination number.

Blurred answer
Students have asked these similar questions
A solution containing 100.0 mL of 0.155 M EDTA buffered to pH 10.00 was titrated with 100.0 mL of 0.0152 M Hg(ClO4)2 in a cell: calomel electrode (saturated)//titration solution/Hg(l) Given the formation constant of Hg(EDTA)2-, logKf= 21.5, and alphaY4-=0.30, find out the cell voltage E. Hg2+(aq) + 2e- = Hg(l)  E0= 0.852 V E' (calomel electrode, saturated KCl) = 0.241 V
From the following reduction potentials I2 (s) + 2e- = 2I- (aq)   E0= 0.535 V I2 (aq) + 2e- = 2I- (aq)  E0= 0.620 V I3- (aq) + 2e- = 3I- (aq)  E0= 0.535 V a) Calculate the equilibrium constant for I2 (aq) + I- (aq) = I3- (aq). b) Calculate the equilibrium constant for I2 (s) + I- (aq) = I3- (aq). c) Calculate the solubility of I2 (s) in water.
2. (3 pts) Consider the unit cell for the spinel compound, CrFe204. How many total particles are in the unit cell? Also, show how the number of particles and their positions are consistent with the CrFe204 stoichiometry - this may or may not be reflected by the particle colors in the diagram. (HINT: In the diagram, the blue particle is in an interior position while each red particle is either in a corner or face position.)

Chapter 22 Solutions

Chemistry

Ch. 22.3 - Prob. 1PPACh. 22.3 - Prob. 1PPBCh. 22.3 - Prob. 1PPCCh. 22.3 - Prob. 1CPCh. 22.3 - Prob. 2CPCh. 22.4 - Prob. 1PPACh. 22.4 - Practice Problem BUILD Transition metal ions can...Ch. 22.4 - Prob. 1PPCCh. 22 - Prob. 1QPCh. 22 - Prob. 2QPCh. 22 - 22.3 Explain why atomic radii decrease very...Ch. 22 - Prob. 4QPCh. 22 - Write the electron configurations of the following...Ch. 22 - Prob. 6QPCh. 22 - Prob. 7QPCh. 22 - Prob. 8QPCh. 22 - Describe the interaction between a donor atom and...Ch. 22 - Prob. 10QPCh. 22 - Complete the following statements for the complex...Ch. 22 - Prob. 12QPCh. 22 - Prob. 13QPCh. 22 - Prob. 14QPCh. 22 - Prob. 15QPCh. 22 - Prob. 16QPCh. 22 - Prob. 17QPCh. 22 - Prob. 18QPCh. 22 - Prob. 19QPCh. 22 - Prob. 20QPCh. 22 - Prob. 21QPCh. 22 - The complex ion [Ni ( CN ) 2 Br 2 ] 2- has a...Ch. 22 - Prob. 23QPCh. 22 - Prob. 24QPCh. 22 - Prob. 25QPCh. 22 - Prob. 26QPCh. 22 - Prob. 27QPCh. 22 - Prob. 28QPCh. 22 - Prob. 29QPCh. 22 - Prob. 30QPCh. 22 - Prob. 31QPCh. 22 - Prob. 32QPCh. 22 - Prob. 33QPCh. 22 - Prob. 34QPCh. 22 - Prob. 35QPCh. 22 - Prob. 36QPCh. 22 - Prob. 37QPCh. 22 - Prob. 38QPCh. 22 - Prob. 39QPCh. 22 - Prob. 40QPCh. 22 - Prob. 41QPCh. 22 - A concentrated aqueous copper(II) chloride...Ch. 22 - Prob. 43QPCh. 22 - Prob. 44QPCh. 22 - Prob. 45APCh. 22 - Prob. 46APCh. 22 - Prob. 47APCh. 22 - Prob. 48APCh. 22 - Prob. 49APCh. 22 - Draw qualitative diagrams for the crystal held...Ch. 22 - Prob. 51APCh. 22 - Prob. 52APCh. 22 - Prob. 53APCh. 22 - Prob. 54APCh. 22 - Prob. 55APCh. 22 - Prob. 56APCh. 22 - Prob. 57APCh. 22 - Prob. 58APCh. 22 - 22.59 The -porphyrin complex is more stable than...Ch. 22 - Prob. 60APCh. 22 - Prob. 61APCh. 22 - Prob. 62APCh. 22 - Prob. 63APCh. 22 - Prob. 64APCh. 22 - Prob. 65APCh. 22 - Prob. 66APCh. 22 - Prob. 67APCh. 22 - Prob. 68APCh. 22 - Locate the transition metal atoms and ions in the...Ch. 22 - Prob. 70APCh. 22 - Prob. 71APCh. 22 - Copper is known to exist in the +3 oxidation...Ch. 22 - 22.73 Chemical analysis shows that hemoglobin...Ch. 22 - Prob. 74APCh. 22 - Prob. 75APCh. 22 - Prob. 76APCh. 22 - 22.77 Commercial silver-plating operations...Ch. 22 - Prob. 78APCh. 22 - 22.79 (a) The free Cu(I) ion is unstable in...Ch. 22 - Prob. 1SEPPCh. 22 - Prob. 2SEPPCh. 22 - Prob. 3SEPPCh. 22 - Prob. 4SEPP
Knowledge Booster
Background pattern image
Chemistry
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
SEE MORE QUESTIONS
Recommended textbooks for you
Text book image
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Text book image
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Text book image
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Text book image
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning
Text book image
Chemistry
Chemistry
ISBN:9781133611097
Author:Steven S. Zumdahl
Publisher:Cengage Learning
Text book image
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
The Bohr Model of the atom and Atomic Emission Spectra: Atomic Structure tutorial | Crash Chemistry; Author: Crash Chemistry Academy;https://www.youtube.com/watch?v=apuWi_Fbtys;License: Standard YouTube License, CC-BY