(a) Interpretation: The curved arrow mechanism for the reaction (2) and the analogous reaction to this reaction is to be stated. Concept introduction: The enzyme dehydroquinate synthase is used to catalyze the reaction of 3 − deoxy − D − arabinoheptulosonate − 7 − phosphate to 3 − dehydroquinate and phosphate. Along with it it also uses NAD + as a coenzyme. This enzyme also involved in the synthesis of aromatic amino acids.

Question

Want to see the full answer?

Answer 1

Question

Chapter 22, Problem 22.97AP

Interpretation Introduction

(a)

Interpretation:

The curved arrow mechanism for the reaction (2) and the analogous reaction to this reaction is to be stated.

Concept introduction:

The enzyme dehydroquinate synthase is used to catalyze the reaction of 3− deoxy −D− arabinoheptulosonate −7− phosphate to 3− dehydroquinate and phosphate. Along with it it also uses NAD+ as a coenzyme. This enzyme also involved in the synthesis of aromatic amino acids.

Interpretation Introduction

(b)

Interpretation:

The chemical rationale involved in the reaction (1) and reaction (3) is to be stated.

Concept introduction:

The enzyme dehydroquinate synthase is used to catalyze the reaction of 3− deoxy −D− arabinoheptulosonate −7− phosphate to 3− dehydroquinate and phosphate. Along with it it also uses NAD+ as a coenzyme. This enzyme also involved in the synthesis of aromatic amino acids.

Interpretation Introduction

(c)

Interpretation:

The curved arrow mechanism for the reaction (4) and (5) and the analogous reaction to these reactions are to be stated.

Concept introduction:

The enzyme dehydroquinate synthase is used to catalyze the reaction of 3− deoxy −D− arabinoheptulosonate −7− phosphate to 3− dehydroquinate and phosphate. Along with it it also uses NAD+ as a coenzyme. This enzyme also involved in the synthesis of aromatic amino acids.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

None

Part II. two unbranched ketone have molecular formulla (C8H100). El-ms showed that both of them have a molecular ion peak at m/2 =128. However ketone (A) has a fragment peak at m/2 = 99 and 72 while ketone (B) snowed a fragment peak at m/2 = 113 and 58. 9) Propose the most plausible structures for both ketones b) Explain how you arrived at your conclusion by drawing the Structures of the distinguishing fragments for each ketone, including their fragmentation mechanisms.

Answer 2

Question

Chapter 22, Problem 22.97AP

Interpretation Introduction

(a)

Interpretation:

The curved arrow mechanism for the reaction (2) and the analogous reaction to this reaction is to be stated.

Concept introduction:

The enzyme dehydroquinate synthase is used to catalyze the reaction of 3− deoxy −D− arabinoheptulosonate −7− phosphate to 3− dehydroquinate and phosphate. Along with it it also uses NAD+ as a coenzyme. This enzyme also involved in the synthesis of aromatic amino acids.

Interpretation Introduction

(b)

Interpretation:

The chemical rationale involved in the reaction (1) and reaction (3) is to be stated.

Concept introduction:

The enzyme dehydroquinate synthase is used to catalyze the reaction of 3− deoxy −D− arabinoheptulosonate −7− phosphate to 3− dehydroquinate and phosphate. Along with it it also uses NAD+ as a coenzyme. This enzyme also involved in the synthesis of aromatic amino acids.

Interpretation Introduction

(c)

Interpretation:

The curved arrow mechanism for the reaction (4) and (5) and the analogous reaction to these reactions are to be stated.

Concept introduction:

The enzyme dehydroquinate synthase is used to catalyze the reaction of 3− deoxy −D− arabinoheptulosonate −7− phosphate to 3− dehydroquinate and phosphate. Along with it it also uses NAD+ as a coenzyme. This enzyme also involved in the synthesis of aromatic amino acids.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 22, Problem 22.97AP

Interpretation Introduction

(a)

Interpretation:

The curved arrow mechanism for the reaction (2) and the analogous reaction to this reaction is to be stated.

Concept introduction:

The enzyme dehydroquinate synthase is used to catalyze the reaction of 3− deoxy −D− arabinoheptulosonate −7− phosphate to 3− dehydroquinate and phosphate. Along with it it also uses NAD+ as a coenzyme. This enzyme also involved in the synthesis of aromatic amino acids.

Interpretation Introduction

(b)

Interpretation:

The chemical rationale involved in the reaction (1) and reaction (3) is to be stated.

Concept introduction:

The enzyme dehydroquinate synthase is used to catalyze the reaction of 3− deoxy −D− arabinoheptulosonate −7− phosphate to 3− dehydroquinate and phosphate. Along with it it also uses NAD+ as a coenzyme. This enzyme also involved in the synthesis of aromatic amino acids.

Interpretation Introduction

(c)

Interpretation:

The curved arrow mechanism for the reaction (4) and (5) and the analogous reaction to these reactions are to be stated.

Concept introduction:

The enzyme dehydroquinate synthase is used to catalyze the reaction of 3− deoxy −D− arabinoheptulosonate −7− phosphate to 3− dehydroquinate and phosphate. Along with it it also uses NAD+ as a coenzyme. This enzyme also involved in the synthesis of aromatic amino acids.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 22, Problem 22.97AP

Interpretation Introduction

(a)

Interpretation:

The curved arrow mechanism for the reaction (2) and the analogous reaction to this reaction is to be stated.

Concept introduction:

The enzyme dehydroquinate synthase is used to catalyze the reaction of 3− deoxy −D− arabinoheptulosonate −7− phosphate to 3− dehydroquinate and phosphate. Along with it it also uses NAD+ as a coenzyme. This enzyme also involved in the synthesis of aromatic amino acids.

Interpretation Introduction

(b)

Interpretation:

The chemical rationale involved in the reaction (1) and reaction (3) is to be stated.

Concept introduction:

The enzyme dehydroquinate synthase is used to catalyze the reaction of 3− deoxy −D− arabinoheptulosonate −7− phosphate to 3− dehydroquinate and phosphate. Along with it it also uses NAD+ as a coenzyme. This enzyme also involved in the synthesis of aromatic amino acids.

Interpretation Introduction

(c)

Interpretation:

The curved arrow mechanism for the reaction (4) and (5) and the analogous reaction to these reactions are to be stated.

Concept introduction:

The enzyme dehydroquinate synthase is used to catalyze the reaction of 3− deoxy −D− arabinoheptulosonate −7− phosphate to 3− dehydroquinate and phosphate. Along with it it also uses NAD+ as a coenzyme. This enzyme also involved in the synthesis of aromatic amino acids.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 22, Problem 22.97AP

Interpretation Introduction

(a)

Interpretation:

The curved arrow mechanism for the reaction (2) and the analogous reaction to this reaction is to be stated.

Concept introduction:

The enzyme dehydroquinate synthase is used to catalyze the reaction of 3− deoxy −D− arabinoheptulosonate −7− phosphate to 3− dehydroquinate and phosphate. Along with it it also uses NAD+ as a coenzyme. This enzyme also involved in the synthesis of aromatic amino acids.

Interpretation Introduction

(b)

Interpretation:

The chemical rationale involved in the reaction (1) and reaction (3) is to be stated.

Concept introduction:

The enzyme dehydroquinate synthase is used to catalyze the reaction of 3− deoxy −D− arabinoheptulosonate −7− phosphate to 3− dehydroquinate and phosphate. Along with it it also uses NAD+ as a coenzyme. This enzyme also involved in the synthesis of aromatic amino acids.

Interpretation Introduction

(c)

Interpretation:

The curved arrow mechanism for the reaction (4) and (5) and the analogous reaction to these reactions are to be stated.

Concept introduction:

The enzyme dehydroquinate synthase is used to catalyze the reaction of 3− deoxy −D− arabinoheptulosonate −7− phosphate to 3− dehydroquinate and phosphate. Along with it it also uses NAD+ as a coenzyme. This enzyme also involved in the synthesis of aromatic amino acids.

Answer 6

Chapter 22, Problem 22.97AP

Interpretation Introduction

(a)

Interpretation:

The curved arrow mechanism for the reaction (2) and the analogous reaction to this reaction is to be stated.

Concept introduction:

The enzyme dehydroquinate synthase is used to catalyze the reaction of 3− deoxy −D− arabinoheptulosonate −7− phosphate to 3− dehydroquinate and phosphate. Along with it it also uses NAD+ as a coenzyme. This enzyme also involved in the synthesis of aromatic amino acids.

Answer 7

Chapter 22, Problem 22.97AP

Interpretation Introduction

(a)

Interpretation:

The curved arrow mechanism for the reaction (2) and the analogous reaction to this reaction is to be stated.

Concept introduction:

The enzyme dehydroquinate synthase is used to catalyze the reaction of 3− deoxy −D− arabinoheptulosonate −7− phosphate to 3− dehydroquinate and phosphate. Along with it it also uses NAD+ as a coenzyme. This enzyme also involved in the synthesis of aromatic amino acids.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The chemical rationale involved in the reaction (1) and reaction (3) is to be stated.

Concept introduction:

The enzyme dehydroquinate synthase is used to catalyze the reaction of 3− deoxy −D− arabinoheptulosonate −7− phosphate to 3− dehydroquinate and phosphate. Along with it it also uses NAD+ as a coenzyme. This enzyme also involved in the synthesis of aromatic amino acids.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The chemical rationale involved in the reaction (1) and reaction (3) is to be stated.

Concept introduction:

The enzyme dehydroquinate synthase is used to catalyze the reaction of 3− deoxy −D− arabinoheptulosonate −7− phosphate to 3− dehydroquinate and phosphate. Along with it it also uses NAD+ as a coenzyme. This enzyme also involved in the synthesis of aromatic amino acids.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The curved arrow mechanism for the reaction (4) and (5) and the analogous reaction to these reactions are to be stated.

Concept introduction:

The enzyme dehydroquinate synthase is used to catalyze the reaction of 3− deoxy −D− arabinoheptulosonate −7− phosphate to 3− dehydroquinate and phosphate. Along with it it also uses NAD+ as a coenzyme. This enzyme also involved in the synthesis of aromatic amino acids.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The curved arrow mechanism for the reaction (4) and (5) and the analogous reaction to these reactions are to be stated.

Concept introduction:

The enzyme dehydroquinate synthase is used to catalyze the reaction of 3− deoxy −D− arabinoheptulosonate −7− phosphate to 3− dehydroquinate and phosphate. Along with it it also uses NAD+ as a coenzyme. This enzyme also involved in the synthesis of aromatic amino acids.

Answer 12

Expert Solution & Answer

Answer 13

Expert Solution & Answer

Answer 14

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 15

Ch. 22 - Prob. 22.1P Ch. 22 - Prob. 22.2P Ch. 22 - Prob. 22.3P Ch. 22 - Prob. 22.4P Ch. 22 - Prob. 22.5P Ch. 22 - Prob. 22.6P Ch. 22 - Prob. 22.7P Ch. 22 - Prob. 22.8P Ch. 22 - Prob. 22.9P Ch. 22 - Prob. 22.10P

Solution Summary: The author explains that the reaction (2) is analogous to reduction reaction since the mechanism proceeds with the elimination of a hydrogen atom.

Want to see the full answer?

Chapter 22 Solutions