(a)
Interpretation:
A reaction free-energy diagram for acid-catalyzed enol formation using the mechanism in Eq.22.17b is to be sketched.
Concept Introduction:
Conversion of
(b)
Interpretation:
A reaction free-energy diagram for the acid catalyzed halogenation of
Concept Introduction:
Halogenation reaction of aldehyde or ketone is done either in acidic or in basic aqueous medium. The halogenation takes place at the

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Chapter 22 Solutions
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- Aldehydes and Ketones: Show the reaction conditions, and molecules, that connect the reactant to the product. A protecting group will be needed. *see imagearrow_forwardAldehydes and Ketones: Show the reaction conditions, and molecules, that connect the reactant to the product. *see imagearrow_forwardProvide the missing information for each of the four reactions: *see imagearrow_forward
- 6. Chlorine dioxide (CIO) is used as a disinfectant in municipal water-treatment plants. It decomposes in a first-order reaction with a rate constant of 14 s. How long would it take for an initial concentration of 0.06 M to decrease to 0.02 M? [6 pts]arrow_forwardIf possible, replace an H atom on the a carbon of the molecule in the drawing area with a methyl group substituent, and replace an H atom on the ẞ carbon with a hydroxyl group substituent. If one of the substituents can't be added for any reason, just don't add it. If neither substituent can be added, check the box under the drawing area. en HO OHarrow_forwardCurved arrows are used to illustrate the flow of electrons. Use the reaction conditions provided and follow the curved arrows to draw the intermediate and product of this hydrohalogenation reaction. Include all lone pairs and charges as appropriate. Br Select to Draw 51°F Sunny esc F1 HBr Select to Draw 1,2-hydride shift Br Select to Draw Q Search F2 F3 F4 1 2 # # 3 DII L F5 F6 F tA $ % Λarrow_forward
- please help i cant find the article to even startarrow_forwardWhat are the missing reagents for the spots labeled 1 and 3? Please give a detailed explanation and include the drawings and show how the synthesis proceeds with the reagents.arrow_forwardhelp with the rf values i am so confusedarrow_forward
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