(a) Interpretation: The stable isomer or decomposition product of the given structure is to be stated. Concept introduction: Tautomers are isomers which differ only in the position of the protons and electrons of the double bond of the electronegative atom in the compound. There is no change in the carbon skeleton of the compound. This phenomenon which involves simple proton transfer in an intramolecular fashion is known as tautomerism. The very common example of tautomerism is Keto-enol tautomerism. It can be acid or base-catalyzed.

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Answer 1

Question

Chapter 22, Problem 22.60AP

Interpretation Introduction

(a)

Interpretation:

The stable isomer or decomposition product of the given structure is to be stated.

Concept introduction:

Tautomers are isomers which differ only in the position of the protons and electrons of the double bond of the electronegative atom in the compound. There is no change in the carbon skeleton of the compound. This phenomenon which involves simple proton transfer in an intramolecular fashion is known as tautomerism. The very common example of tautomerism is Keto-enol tautomerism. It can be acid or base-catalyzed.

Interpretation Introduction

(b)

Interpretation:

The stable isomer or decomposition product of the given structure is to be stated.

Concept introduction:

The aromatic compounds are more stable as compared to the cyclic compounds. The delocalization of π electrons in aromatic rings makes them a stable compound. More the delocalization of π electrons takes place in the aromatic ring, more is the stability of the aromatic compound.

Interpretation Introduction

(c)

Interpretation:

The stable isomer or decomposition product of the given structure is to be stated.

Concept introduction:

Chemical decomposition is the breakdown of one molecule into two different or the same molecule to attain stability. It may be of three types, thermal, photochemical, and electrolytic decomposition reactions.

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An expression for the root mean square velocity, vrms, of a gas was derived. Using Maxwell’s velocity distribution, one can also calculate the mean velocity and the most probable velocity (mp) of a collection of molecules. The equations used for these two quantities are vmean=(8RT/πM)1/2 and vmp=(2RT/M)1/2 These values have a fixed relationship to each other.(a) Arrange these three quantities in order of increasing magnitude.(b) Show that the relative magnitudes are independent of the molar mass of the gas.(c) Use the smallest velocity as a reference for establishing the order of magnitude and determine the relationship between the larger and smaller values.

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Answer 2

Question

Chapter 22, Problem 22.60AP

Interpretation Introduction

(a)

Interpretation:

The stable isomer or decomposition product of the given structure is to be stated.

Concept introduction:

Tautomers are isomers which differ only in the position of the protons and electrons of the double bond of the electronegative atom in the compound. There is no change in the carbon skeleton of the compound. This phenomenon which involves simple proton transfer in an intramolecular fashion is known as tautomerism. The very common example of tautomerism is Keto-enol tautomerism. It can be acid or base-catalyzed.

Interpretation Introduction

(b)

Interpretation:

The stable isomer or decomposition product of the given structure is to be stated.

Concept introduction:

The aromatic compounds are more stable as compared to the cyclic compounds. The delocalization of π electrons in aromatic rings makes them a stable compound. More the delocalization of π electrons takes place in the aromatic ring, more is the stability of the aromatic compound.

Interpretation Introduction

(c)

Interpretation:

The stable isomer or decomposition product of the given structure is to be stated.

Concept introduction:

Chemical decomposition is the breakdown of one molecule into two different or the same molecule to attain stability. It may be of three types, thermal, photochemical, and electrolytic decomposition reactions.

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Answer 3

Question

Chapter 22, Problem 22.60AP

Interpretation Introduction

(a)

Interpretation:

The stable isomer or decomposition product of the given structure is to be stated.

Concept introduction:

Tautomers are isomers which differ only in the position of the protons and electrons of the double bond of the electronegative atom in the compound. There is no change in the carbon skeleton of the compound. This phenomenon which involves simple proton transfer in an intramolecular fashion is known as tautomerism. The very common example of tautomerism is Keto-enol tautomerism. It can be acid or base-catalyzed.

Interpretation Introduction

(b)

Interpretation:

The stable isomer or decomposition product of the given structure is to be stated.

Concept introduction:

The aromatic compounds are more stable as compared to the cyclic compounds. The delocalization of π electrons in aromatic rings makes them a stable compound. More the delocalization of π electrons takes place in the aromatic ring, more is the stability of the aromatic compound.

Interpretation Introduction

(c)

Interpretation:

The stable isomer or decomposition product of the given structure is to be stated.

Concept introduction:

Chemical decomposition is the breakdown of one molecule into two different or the same molecule to attain stability. It may be of three types, thermal, photochemical, and electrolytic decomposition reactions.

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Answer 4

Question

Chapter 22, Problem 22.60AP

Interpretation Introduction

(a)

Interpretation:

The stable isomer or decomposition product of the given structure is to be stated.

Concept introduction:

Tautomers are isomers which differ only in the position of the protons and electrons of the double bond of the electronegative atom in the compound. There is no change in the carbon skeleton of the compound. This phenomenon which involves simple proton transfer in an intramolecular fashion is known as tautomerism. The very common example of tautomerism is Keto-enol tautomerism. It can be acid or base-catalyzed.

Interpretation Introduction

(b)

Interpretation:

The stable isomer or decomposition product of the given structure is to be stated.

Concept introduction:

The aromatic compounds are more stable as compared to the cyclic compounds. The delocalization of π electrons in aromatic rings makes them a stable compound. More the delocalization of π electrons takes place in the aromatic ring, more is the stability of the aromatic compound.

Interpretation Introduction

(c)

Interpretation:

The stable isomer or decomposition product of the given structure is to be stated.

Concept introduction:

Chemical decomposition is the breakdown of one molecule into two different or the same molecule to attain stability. It may be of three types, thermal, photochemical, and electrolytic decomposition reactions.

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Answer 5

Chapter 22, Problem 22.60AP

Interpretation Introduction

(a)

Interpretation:

The stable isomer or decomposition product of the given structure is to be stated.

Concept introduction:

Tautomers are isomers which differ only in the position of the protons and electrons of the double bond of the electronegative atom in the compound. There is no change in the carbon skeleton of the compound. This phenomenon which involves simple proton transfer in an intramolecular fashion is known as tautomerism. The very common example of tautomerism is Keto-enol tautomerism. It can be acid or base-catalyzed.

Interpretation Introduction

(b)

Interpretation:

The stable isomer or decomposition product of the given structure is to be stated.

Concept introduction:

The aromatic compounds are more stable as compared to the cyclic compounds. The delocalization of π electrons in aromatic rings makes them a stable compound. More the delocalization of π electrons takes place in the aromatic ring, more is the stability of the aromatic compound.

Interpretation Introduction

(c)

Interpretation:

The stable isomer or decomposition product of the given structure is to be stated.

Concept introduction:

Chemical decomposition is the breakdown of one molecule into two different or the same molecule to attain stability. It may be of three types, thermal, photochemical, and electrolytic decomposition reactions.

Answer 6

Chapter 22, Problem 22.60AP

Interpretation Introduction

(a)

Interpretation:

The stable isomer or decomposition product of the given structure is to be stated.

Concept introduction:

Tautomers are isomers which differ only in the position of the protons and electrons of the double bond of the electronegative atom in the compound. There is no change in the carbon skeleton of the compound. This phenomenon which involves simple proton transfer in an intramolecular fashion is known as tautomerism. The very common example of tautomerism is Keto-enol tautomerism. It can be acid or base-catalyzed.

Answer 7

Chapter 22, Problem 22.60AP

Interpretation Introduction

(a)

Interpretation:

The stable isomer or decomposition product of the given structure is to be stated.

Concept introduction:

Tautomers are isomers which differ only in the position of the protons and electrons of the double bond of the electronegative atom in the compound. There is no change in the carbon skeleton of the compound. This phenomenon which involves simple proton transfer in an intramolecular fashion is known as tautomerism. The very common example of tautomerism is Keto-enol tautomerism. It can be acid or base-catalyzed.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The stable isomer or decomposition product of the given structure is to be stated.

Concept introduction:

The aromatic compounds are more stable as compared to the cyclic compounds. The delocalization of π electrons in aromatic rings makes them a stable compound. More the delocalization of π electrons takes place in the aromatic ring, more is the stability of the aromatic compound.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The stable isomer or decomposition product of the given structure is to be stated.

Concept introduction:

The aromatic compounds are more stable as compared to the cyclic compounds. The delocalization of π electrons in aromatic rings makes them a stable compound. More the delocalization of π electrons takes place in the aromatic ring, more is the stability of the aromatic compound.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The stable isomer or decomposition product of the given structure is to be stated.

Concept introduction:

Chemical decomposition is the breakdown of one molecule into two different or the same molecule to attain stability. It may be of three types, thermal, photochemical, and electrolytic decomposition reactions.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The stable isomer or decomposition product of the given structure is to be stated.

Concept introduction:

Chemical decomposition is the breakdown of one molecule into two different or the same molecule to attain stability. It may be of three types, thermal, photochemical, and electrolytic decomposition reactions.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 22 - Prob. 22.1P Ch. 22 - Prob. 22.2P Ch. 22 - Prob. 22.3P Ch. 22 - Prob. 22.4P Ch. 22 - Prob. 22.5P Ch. 22 - Prob. 22.6P Ch. 22 - Prob. 22.7P Ch. 22 - Prob. 22.8P Ch. 22 - Prob. 22.9P Ch. 22 - Prob. 22.10P

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Chapter 22 Solutions