EBK GET READY FOR ORGANIC CHEMISTRY
EBK GET READY FOR ORGANIC CHEMISTRY
2nd Edition
ISBN: 9780321830555
Author: KARTY
Publisher: VST
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Chapter 22, Problem 22.50P
Interpretation Introduction

Interpretation:

The rate of substitution in a deiodination reaction is Ar-F <Ar-Cl < Ar-Br < Ar-I is to be explained.

Concept introduction:

In a deiodination reaction, a positive charge appears on the iodine atom attached to the benzene ring in the intermediate species. The halogen, which is less electronegative and larger in size, best stabilizes the positive charge. Iodine is larger in size and less electronegative. As the size of halogen decreases and electronegativity increases, stability of positive charge decreases. The order of stability in increasing order is F < Cl < Br < I.

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Chapter 22 Solutions

EBK GET READY FOR ORGANIC CHEMISTRY

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