CHEMISTRY:ATOMS FIRST-2 YEAR CONNECT
2nd Edition
ISBN: 9781260592320
Author: Burdge
Publisher: MCG
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Chapter 22, Problem 22.43QP
Interpretation Introduction
Interpretation: The ligand exchange reaction occurred to be interpreted.
Concept Introduction:
Crystal field splitting: The energy gap between the splitting of d-orbitals of the metal ion in presence of ligands is known as the crystal field splitting
Reaction of coordination compounds: Complex ion undergoes ligand exchange (or substitution) reactions in solution. The
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Consider this step in a radical reaction:
Y
What type of step is this? Check all that apply.
Draw the products of the step on the right-hand side of the drawing area
below. If more than one set of products is possible, draw any set.
Also, draw the mechanism arrows on the left-hand side of the drawing
area to show how this happens.
ionization
propagation
initialization
passivation
none of the above
22.16 The following groups are ortho-para directors.
(a)
-C=CH₂
H
(d)
-Br
(b)
-NH2
(c)
-OCHS
Draw a contributing structure for the resonance-stabilized cation formed during elec-
trophilic aromatic substitution that shows the role of each group in stabilizing the
intermediate by further delocalizing its positive charge.
22.17 Predict the major product or products from treatment of each compound with
Cl₁/FeCl₂-
OH
(b)
NO2
CHO
22.18 How do you account for the fact that phenyl acetate is less reactive toward electro-
philic aromatic substitution than anisole?
Phenyl acetate
Anisole
CH
(d)
Chapter 22 Solutions
CHEMISTRY:ATOMS FIRST-2 YEAR CONNECT
Ch. 22.1 - Prob. 22.1WECh. 22.1 - Give oxidation numbers for the metals in (a)...Ch. 22.1 - Prob. 1PPBCh. 22.1 - Prob. 1PPCCh. 22.1 - Write the names of the following coordination...Ch. 22.1 - Give the correct name for (a) [Co(NH3)4Br2]Cl, (b)...Ch. 22.1 - Prob. 2PPBCh. 22.1 - Prob. 2PPCCh. 22.1 - Prob. 22.3WECh. 22.1 - Prob. 3PPA
Ch. 22.1 - Prob. 3PPBCh. 22.1 - Prob. 3PPCCh. 22.1 - Prob. 22.1.1SRCh. 22.1 - Prob. 22.1.2SRCh. 22.1 - Prob. 22.1.3SRCh. 22.1 - Prob. 22.1.4SRCh. 22.3 - Prob. 22.4WECh. 22.3 - Prob. 4PPACh. 22.3 - Prob. 4PPBCh. 22.3 - Prob. 4PPCCh. 22.3 - Prob. 22.3.1SRCh. 22.3 - Prob. 22.3.2SRCh. 22 - What distinguishes a transition metal from a main...Ch. 22 - Prob. 22.2QPCh. 22 - Prob. 22.3QPCh. 22 - Without referring to the text, write the...Ch. 22 - Write the electron configurations of the following...Ch. 22 - Prob. 22.6QPCh. 22 - Prob. 22.7QPCh. 22 - Prob. 22.8QPCh. 22 - Describe the interaction between a donor atom and...Ch. 22 - Prob. 22.10QPCh. 22 - Prob. 22.11QPCh. 22 - Prob. 22.12QPCh. 22 - Prob. 22.13QPCh. 22 - What are the systematic names for the following...Ch. 22 - Prob. 22.15QPCh. 22 - Write the formulas for each of the following ions...Ch. 22 - Prob. 22.17QPCh. 22 - Prob. 22.18QPCh. 22 - Prob. 22.19QPCh. 22 - Prob. 22.20QPCh. 22 - Prob. 22.21QPCh. 22 - Prob. 22.22QPCh. 22 - Prob. 22.23QPCh. 22 - Prob. 22.24QPCh. 22 - Prob. 22.25QPCh. 22 - Briefly describe crystal field theory.Ch. 22 - Prob. 22.27QPCh. 22 - What is the origin of color in a coordination...Ch. 22 - Prob. 22.29QPCh. 22 - Prob. 22.30QPCh. 22 - Prob. 22.31QPCh. 22 - Prob. 22.32QPCh. 22 - The absorption maximum for the complex ion...Ch. 22 - Prob. 22.34QPCh. 22 - Prob. 22.35QPCh. 22 - Prob. 22.36QPCh. 22 - Prob. 22.37QPCh. 22 - Prob. 22.38QPCh. 22 - Prob. 22.39QPCh. 22 - Prob. 22.40QPCh. 22 - The [Fe(CN)6]3 complex is more labile than the...Ch. 22 - Prob. 22.42QPCh. 22 - Prob. 22.43QPCh. 22 - Prob. 22.44QPCh. 22 - Prob. 22.45QPCh. 22 - Prob. 22.46QPCh. 22 - Prob. 22.47QPCh. 22 - Prob. 22.48QPCh. 22 - Prob. 22.49QPCh. 22 - Prob. 22.50QPCh. 22 - Prob. 22.51QPCh. 22 - Prob. 22.52QPCh. 22 - Prob. 22.53QPCh. 22 - Prob. 22.54QPCh. 22 - A student in 1895 prepared three coordination...Ch. 22 - Prob. 22.56QPCh. 22 - Prob. 22.57QPCh. 22 - Prob. 22.58QPCh. 22 - Prob. 22.59QPCh. 22 - Prob. 22.60QPCh. 22 - Prob. 22.61QPCh. 22 - Hydrated Mn2+ ions are practically colorless (see...Ch. 22 - Which of the following hydrated cations are...Ch. 22 - Prob. 22.64QPCh. 22 - Prob. 22.65QPCh. 22 - Prob. 22.66QPCh. 22 - Prob. 22.67QPCh. 22 - Prob. 22.68QPCh. 22 - Prob. 22.69QPCh. 22 - Prob. 22.70QPCh. 22 - Commercial silver-plating operations frequently...Ch. 22 - Prob. 22.72QPCh. 22 - Prob. 22.73QPCh. 22 - Prob. 22.74QPCh. 22 - Prob. 22.75QPCh. 22 - Prob. 22.76QPCh. 22 - Prob. 22.77QPCh. 22 - Prob. 22.78QPCh. 22 - Prob. 22.79QPCh. 22 - Prob. 22.80QP
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