CHEMISTRY:ATOMS FIRST-2 YEAR CONNECT
2nd Edition
ISBN: 9781260592320
Author: Burdge
Publisher: MCG
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Question
Chapter 22, Problem 22.22QP
Interpretation Introduction
Interpretation: Draw the structures of geometric isomers for the given complex ion.
Concept Introduction:
Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.
Stereoisomer: The same molecular formula but different with the arrangements of atoms around the metal ion. The Ligands are arranged differently in coordination compounds.
Geometric isomers: stereoisomers that cannot be interconverted without breaking the
Optical isomers: Optical isomers are non-superimposable mirror images.
Plane-polarized light: Light that oscillates in a single plane.
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Rank each of the following substituted benzene molecules in order of which will react fastest (1) to slowest (4) by electrophilic
aromatic substitution.
Explanation
Check
CF3
(Choose one)
OH
(Choose one)
H
(Choose one)
(Choose one)
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Identifying electron-donating and electron-withdrawing effects
For each of the substituted benzene molecules below, determine the inductive and resonance effects the substituent will have on the
benzene ring, as well as the overall electron-density of the ring compared to unsubstituted benzene.
Molecule
Inductive Effects
Resonance Effects
Overall Electron-Density
CF3
O donating
O donating
O electron-rich
O withdrawing
withdrawing
O no inductive effects
O no resonance effects
O electron-deficient
O similar to benzene
OCH3
Explanation
Check
O donating
O donating
○ withdrawing
withdrawing
O no inductive effects
no resonance effects
electron-rich
electron-deficient
O similar to benzene
Х
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The acid-base chemistry of both EDTA and EBT are important to ensuring that the reactions proceed as desired, thus the pH is controlled using a buffer. What percent of the EBT indicator will be in the desired HIn2- state at pH = 10.5. pKa1 = 6.2 and pKa2 = 11.6 of EBT
Chapter 22 Solutions
CHEMISTRY:ATOMS FIRST-2 YEAR CONNECT
Ch. 22.1 - Prob. 22.1WECh. 22.1 - Give oxidation numbers for the metals in (a)...Ch. 22.1 - Prob. 1PPBCh. 22.1 - Prob. 1PPCCh. 22.1 - Write the names of the following coordination...Ch. 22.1 - Give the correct name for (a) [Co(NH3)4Br2]Cl, (b)...Ch. 22.1 - Prob. 2PPBCh. 22.1 - Prob. 2PPCCh. 22.1 - Prob. 22.3WECh. 22.1 - Prob. 3PPA
Ch. 22.1 - Prob. 3PPBCh. 22.1 - Prob. 3PPCCh. 22.1 - Prob. 22.1.1SRCh. 22.1 - Prob. 22.1.2SRCh. 22.1 - Prob. 22.1.3SRCh. 22.1 - Prob. 22.1.4SRCh. 22.3 - Prob. 22.4WECh. 22.3 - Prob. 4PPACh. 22.3 - Prob. 4PPBCh. 22.3 - Prob. 4PPCCh. 22.3 - Prob. 22.3.1SRCh. 22.3 - Prob. 22.3.2SRCh. 22 - What distinguishes a transition metal from a main...Ch. 22 - Prob. 22.2QPCh. 22 - Prob. 22.3QPCh. 22 - Without referring to the text, write the...Ch. 22 - Write the electron configurations of the following...Ch. 22 - Prob. 22.6QPCh. 22 - Prob. 22.7QPCh. 22 - Prob. 22.8QPCh. 22 - Describe the interaction between a donor atom and...Ch. 22 - Prob. 22.10QPCh. 22 - Prob. 22.11QPCh. 22 - Prob. 22.12QPCh. 22 - Prob. 22.13QPCh. 22 - What are the systematic names for the following...Ch. 22 - Prob. 22.15QPCh. 22 - Write the formulas for each of the following ions...Ch. 22 - Prob. 22.17QPCh. 22 - Prob. 22.18QPCh. 22 - Prob. 22.19QPCh. 22 - Prob. 22.20QPCh. 22 - Prob. 22.21QPCh. 22 - Prob. 22.22QPCh. 22 - Prob. 22.23QPCh. 22 - Prob. 22.24QPCh. 22 - Prob. 22.25QPCh. 22 - Briefly describe crystal field theory.Ch. 22 - Prob. 22.27QPCh. 22 - What is the origin of color in a coordination...Ch. 22 - Prob. 22.29QPCh. 22 - Prob. 22.30QPCh. 22 - Prob. 22.31QPCh. 22 - Prob. 22.32QPCh. 22 - The absorption maximum for the complex ion...Ch. 22 - Prob. 22.34QPCh. 22 - Prob. 22.35QPCh. 22 - Prob. 22.36QPCh. 22 - Prob. 22.37QPCh. 22 - Prob. 22.38QPCh. 22 - Prob. 22.39QPCh. 22 - Prob. 22.40QPCh. 22 - The [Fe(CN)6]3 complex is more labile than the...Ch. 22 - Prob. 22.42QPCh. 22 - Prob. 22.43QPCh. 22 - Prob. 22.44QPCh. 22 - Prob. 22.45QPCh. 22 - Prob. 22.46QPCh. 22 - Prob. 22.47QPCh. 22 - Prob. 22.48QPCh. 22 - Prob. 22.49QPCh. 22 - Prob. 22.50QPCh. 22 - Prob. 22.51QPCh. 22 - Prob. 22.52QPCh. 22 - Prob. 22.53QPCh. 22 - Prob. 22.54QPCh. 22 - A student in 1895 prepared three coordination...Ch. 22 - Prob. 22.56QPCh. 22 - Prob. 22.57QPCh. 22 - Prob. 22.58QPCh. 22 - Prob. 22.59QPCh. 22 - Prob. 22.60QPCh. 22 - Prob. 22.61QPCh. 22 - Hydrated Mn2+ ions are practically colorless (see...Ch. 22 - Which of the following hydrated cations are...Ch. 22 - Prob. 22.64QPCh. 22 - Prob. 22.65QPCh. 22 - Prob. 22.66QPCh. 22 - Prob. 22.67QPCh. 22 - Prob. 22.68QPCh. 22 - Prob. 22.69QPCh. 22 - Prob. 22.70QPCh. 22 - Commercial silver-plating operations frequently...Ch. 22 - Prob. 22.72QPCh. 22 - Prob. 22.73QPCh. 22 - Prob. 22.74QPCh. 22 - Prob. 22.75QPCh. 22 - Prob. 22.76QPCh. 22 - Prob. 22.77QPCh. 22 - Prob. 22.78QPCh. 22 - Prob. 22.79QPCh. 22 - Prob. 22.80QP
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