Organic Chemistry
Organic Chemistry
8th Edition
ISBN: 9781337516402
Author: Brown
Publisher: Cengage
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Chapter 22, Problem 22.19P

(a)

Interpretation Introduction

Interpretation:

Given compounds has to be arranged in their decreasing order of reactivity towards electrophilic aromatic substitution.

(a)

Expert Solution
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Explanation of Solution

Given compounds,

Organic Chemistry, Chapter 22, Problem 22.19P , additional homework tip  1

General trend of compounds reactivity in electrophilic aromatic substitution for a set of compounds having similar structure is given by,

Presenceofelectrondonatingsubstituents>Nosubstituents>Electronwithdrawingsubstituents

So, electron donating substituents will increases the reactivity, while electron withdrawing substituents will decreases the reactivity.

Therefore, the decreasing order of reactivity towards electrophilic aromatic substitution of the given compounds are given below,

B>A>C

(b)

Interpretation Introduction

Interpretation:

Given compounds has to be arranged in their decreasing order of reactivity towards electrophilic aromatic substitution.

(b)

Expert Solution
Check Mark

Explanation of Solution

Given compounds,

Organic Chemistry, Chapter 22, Problem 22.19P , additional homework tip  2

General trend of compounds reactivity in electrophilic aromatic substitution for a set of compounds having similar structure is given by,

Presenceofelectrondonatingsubstituents>Nosubstituents>Electronwithdrawingsubstituents

So, electron donating substituents will increases the reactivity, while electron withdrawing substituents will decreases the reactivity.

Therefore, the decreasing order of reactivity towards electrophilic aromatic substitution of the given compounds are given below,

C>B>A

(c)

Interpretation Introduction

Interpretation:

Given compounds has to be arranged in their decreasing order of reactivity towards electrophilic aromatic substitution.

(c)

Expert Solution
Check Mark

Explanation of Solution

Given compounds,

Organic Chemistry, Chapter 22, Problem 22.19P , additional homework tip  3

General trend of compounds reactivity in electrophilic aromatic substitution for a set of compounds having similar structure is given by,

Presenceofelectrondonatingsubstituents>Nosubstituents>Electronwithdrawingsubstituents

So, electron donating substituents will increases the reactivity, while electron withdrawing substituents will decreases the reactivity.

Therefore, the decreasing order of reactivity towards electrophilic aromatic substitution of the given compounds are given below,

A>B>C

(d)

Interpretation Introduction

Interpretation:

Given compounds has to be arranged in their decreasing order of reactivity towards electrophilic aromatic substitution.

(d)

Expert Solution
Check Mark

Explanation of Solution

Given compounds,

Organic Chemistry, Chapter 22, Problem 22.19P , additional homework tip  4

General trend of compounds reactivity in electrophilic aromatic substitution for a set of compounds having similar structure is given by,

Presenceofelectrondonatingsubstituents>Nosubstituents>Electronwithdrawingsubstituents

So, electron donating substituents will increases the reactivity, while electron withdrawing substituents will decreases the reactivity.

Therefore, the decreasing order of reactivity towards electrophilic aromatic substitution of the given compounds are given below,

C>A>B

(e)

Interpretation Introduction

Interpretation:

Given compounds has to be arranged in their decreasing order of reactivity towards electrophilic aromatic substitution.

(e)

Expert Solution
Check Mark

Explanation of Solution

Given compounds,

Organic Chemistry, Chapter 22, Problem 22.19P , additional homework tip  5

General trend of compounds reactivity in electrophilic aromatic substitution for a set of compounds having similar structure is given by,

Presenceofelectrondonatingsubstituents>Nosubstituents>Electronwithdrawingsubstituents

So, electron donating substituents will increases the reactivity, while electron withdrawing substituents will decreases the reactivity.

Therefore, the decreasing order of reactivity towards electrophilic aromatic substitution of the given compounds are given below,

A>B>C

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Chapter 22 Solutions

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