BURDGE CHEMISTRY VALUE ED (LL)
4th Edition
ISBN: 9781259995958
Author: VALUE EDITION
Publisher: MCG CUSTOM
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Question
Chapter 22, Problem 20QP
Interpretation Introduction
Interpretation:
The factor that determines the chirality of a molecule and the measurement of chirality by using a polarimeter are to be explained.
Concept introduction:
Optical isomers that are non-superimposable over each other are said to be chiral molecules or isomers. Chiral molecules are optically active isomers as they can rotate the plane of polarized light that passes through the polarimeter.
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Students have asked these similar questions
1.
For an unknown compound with a molecular formula of C8H100:
a.
What is the DU? (show your work)
b.
Solve the structure and assign each of the following spectra.
8
6
2
ō (ppm)
4
2
0
200
150
100
50
ō (ppm)
LOD
D
4000
3000
2000
1500
1000
500
HAVENUMBERI -11
16. The proton NMR spectral information shown in this problem is for a compound with formula
CioH,N. Expansions are shown for the region from 8.7 to 7.0 ppm. The normal carbon-13 spec-
tral results, including DEPT-135 and DEPT-90 results, are tabulated:
7
J
Normal Carbon
DEPT-135
DEPT-90
19 ppm
Positive
No peak
122
Positive
Positive
cus
и
124
Positive
Positive
126
Positive
Positive
128
No peak
No peak
4°
129
Positive
Positive
130
Positive
Positive
(144
No peak
No peak
148
No peak
No peak
150
Positive
Positive
してし
3. Propose a synthesis for the following transformation. Do not draw an arrow-pushing
mechanism below, but make sure to draw the product of each proposed step (3 points).
+ En
CN
CN
Chapter 22 Solutions
BURDGE CHEMISTRY VALUE ED (LL)
Ch. 22.1 - Prob. 1PPACh. 22.1 - Prob. 1PPBCh. 22.1 - Prob. 1PPCCh. 22.1 - Prob. 1CPCh. 22.1 - Prob. 2CPCh. 22.1 - Prob. 3CPCh. 22.1 - Prob. 4CPCh. 22.2 - Prob. 1PPACh. 22.2 - Prob. 1PPBCh. 22.2 - Prob. 1PPC
Ch. 22.3 - Prob. 1PPACh. 22.3 - Prob. 1PPBCh. 22.3 - Prob. 1PPCCh. 22.3 - Prob. 1CPCh. 22.3 - Prob. 2CPCh. 22.4 - Prob. 1PPACh. 22.4 - Practice Problem BUILD
Transition metal ions can...Ch. 22.4 - Prob. 1PPCCh. 22 - Prob. 1QPCh. 22 - Prob. 2QPCh. 22 - 22.3 Explain why atomic radii decrease very...Ch. 22 - Prob. 4QPCh. 22 - Write the electron configurations of the following...Ch. 22 - Prob. 6QPCh. 22 - Prob. 7QPCh. 22 - Prob. 8QPCh. 22 - Describe the interaction between a donor atom and...Ch. 22 - Prob. 10QPCh. 22 - Complete the following statements for the complex...Ch. 22 - Prob. 12QPCh. 22 - Prob. 13QPCh. 22 - Prob. 14QPCh. 22 - Prob. 15QPCh. 22 - Prob. 16QPCh. 22 - Prob. 17QPCh. 22 - Prob. 18QPCh. 22 - Prob. 19QPCh. 22 - Prob. 20QPCh. 22 - Prob. 21QPCh. 22 - The complex ion [Ni ( CN ) 2 Br 2 ] 2- has a...Ch. 22 - Prob. 23QPCh. 22 - Prob. 24QPCh. 22 - Prob. 25QPCh. 22 - Prob. 26QPCh. 22 - Prob. 27QPCh. 22 - Prob. 28QPCh. 22 - Prob. 29QPCh. 22 - Prob. 30QPCh. 22 - Prob. 31QPCh. 22 - Prob. 32QPCh. 22 - Prob. 33QPCh. 22 - Prob. 34QPCh. 22 - Prob. 35QPCh. 22 - Prob. 36QPCh. 22 - Prob. 37QPCh. 22 - Prob. 38QPCh. 22 - Prob. 39QPCh. 22 - Prob. 40QPCh. 22 - Prob. 41QPCh. 22 - A concentrated aqueous copper(II) chloride...Ch. 22 - Prob. 43QPCh. 22 - Prob. 44QPCh. 22 - Prob. 45APCh. 22 - Prob. 46APCh. 22 - Prob. 47APCh. 22 - Prob. 48APCh. 22 - Prob. 49APCh. 22 - Draw qualitative diagrams for the crystal held...Ch. 22 - Prob. 51APCh. 22 - Prob. 52APCh. 22 - Prob. 53APCh. 22 - Prob. 54APCh. 22 - Prob. 55APCh. 22 - Prob. 56APCh. 22 - Prob. 57APCh. 22 - Prob. 58APCh. 22 - 22.59 The -porphyrin complex is more stable than...Ch. 22 - Prob. 60APCh. 22 - Prob. 61APCh. 22 - Prob. 62APCh. 22 - Prob. 63APCh. 22 - Prob. 64APCh. 22 - Prob. 65APCh. 22 - Prob. 66APCh. 22 - Prob. 67APCh. 22 - Prob. 68APCh. 22 - Locate the transition metal atoms and ions in the...Ch. 22 - Prob. 70APCh. 22 - Prob. 71APCh. 22 - Copper is known to exist in the +3 oxidation...Ch. 22 - 22.73 Chemical analysis shows that hemoglobin...Ch. 22 - Prob. 74APCh. 22 - Prob. 75APCh. 22 - Prob. 76APCh. 22 - 22.77 Commercial silver-plating operations...Ch. 22 - Prob. 78APCh. 22 - 22.79 (a) The free Cu(I) ion is unstable in...Ch. 22 - Prob. 1SEPPCh. 22 - Prob. 2SEPPCh. 22 - Prob. 3SEPPCh. 22 - Prob. 4SEPP
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- Label the spectrum with spectroscopyarrow_forwardLabel the spectrum with spectroscopyarrow_forwardQ1: Draw the most stable and the least stable Newman projections about the C2-C3 bond for each of the following isomers (A-C). Are the barriers to rotation identical for enantiomers A and B? How about the diastereomers (A versus C or B versus C)? enantiomers H Br H Br (S) CH3 H3C (S) (R) CH3 H3C H Br A Br H C H Br H3C (R) B (R)CH3 H Br H Br H3C (R) (S) CH3 Br H D identicalarrow_forward
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