The formula of the given compoundis to be determined: Concept introduction: Coordination compounds are the compounds formed by the reaction of metal ions with polar molecules, or with a group of anions. They contain coordinate covalent bonds. Oxidation state is also known as oxidation number. It is used to describe the oxidation, that is, theloss of electrons, in any compound. The ligands are named first in alphabetical order and metal ion last in a complex ion. The name of anionic ligand ends with letter ‘o”. The neutral ligands are called by the name of the molecule except CO (carbonyl), NH 3 (ammine), and H 2 O (aqua). Prefixes di, tri, tetra, penta, and hexa are used, to specify the number of ligands when two or more of same ligands are present. The oxidation number of the metal is written after the name of the metal in roman numerals. If the complex is an anion, its name ends with ‘-ate’.

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Answer 1

Question

Chapter 22, Problem 16QP

Interpretation Introduction

Interpretation:

The formula of the given compoundis to be determined:

Concept introduction:

Coordination compounds are the compounds formed by the reaction of metal ions with polar molecules, or with a group of anions. They contain coordinate covalent bonds.

Oxidation state is also known as oxidation number. It is used to describe the oxidation, that is, theloss of electrons, in any compound.

The ligands are named first in alphabetical order and metal ion last in a complex ion.

The name of anionic ligand ends with letter ‘o”.

The neutral ligands are called by the name of the molecule except CO (carbonyl), NH3 (ammine), and H2O (aqua).

Prefixes di, tri, tetra, penta, and hexa are used, to specify the number of ligands when two or more of same ligands are present.

The oxidation number of the metal is written after the name of the metal in roman numerals.

If the complex is an anion, its name ends with ‘-ate’.

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4. Provide a clear arrow-pushing mechanism for each of the following reactions. Do not skip proton transfers, do not combine steps, and make sure your arrows are clear enough to be interpreted without ambiguity. a. 2. 1. LDA 3. H3O+ HO

b. H3C CH3 H3O+ ✓ H OH

2. Provide reagents/conditions to accomplish the following syntheses. More than one step is required in some cases. a. CH3

Answer 2

Question

Chapter 22, Problem 16QP

Interpretation Introduction

Interpretation:

The formula of the given compoundis to be determined:

Concept introduction:

Coordination compounds are the compounds formed by the reaction of metal ions with polar molecules, or with a group of anions. They contain coordinate covalent bonds.

Oxidation state is also known as oxidation number. It is used to describe the oxidation, that is, theloss of electrons, in any compound.

The ligands are named first in alphabetical order and metal ion last in a complex ion.

The name of anionic ligand ends with letter ‘o”.

The neutral ligands are called by the name of the molecule except CO (carbonyl), NH3 (ammine), and H2O (aqua).

Prefixes di, tri, tetra, penta, and hexa are used, to specify the number of ligands when two or more of same ligands are present.

The oxidation number of the metal is written after the name of the metal in roman numerals.

If the complex is an anion, its name ends with ‘-ate’.

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Answer 3

Question

Chapter 22, Problem 16QP

Interpretation Introduction

Interpretation:

The formula of the given compoundis to be determined:

Concept introduction:

Coordination compounds are the compounds formed by the reaction of metal ions with polar molecules, or with a group of anions. They contain coordinate covalent bonds.

Oxidation state is also known as oxidation number. It is used to describe the oxidation, that is, theloss of electrons, in any compound.

The ligands are named first in alphabetical order and metal ion last in a complex ion.

The name of anionic ligand ends with letter ‘o”.

The neutral ligands are called by the name of the molecule except CO (carbonyl), NH3 (ammine), and H2O (aqua).

Prefixes di, tri, tetra, penta, and hexa are used, to specify the number of ligands when two or more of same ligands are present.

The oxidation number of the metal is written after the name of the metal in roman numerals.

If the complex is an anion, its name ends with ‘-ate’.

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Answer 4

Question

Chapter 22, Problem 16QP

Interpretation Introduction

Interpretation:

The formula of the given compoundis to be determined:

Concept introduction:

Coordination compounds are the compounds formed by the reaction of metal ions with polar molecules, or with a group of anions. They contain coordinate covalent bonds.

Oxidation state is also known as oxidation number. It is used to describe the oxidation, that is, theloss of electrons, in any compound.

The ligands are named first in alphabetical order and metal ion last in a complex ion.

The name of anionic ligand ends with letter ‘o”.

The neutral ligands are called by the name of the molecule except CO (carbonyl), NH3 (ammine), and H2O (aqua).

Prefixes di, tri, tetra, penta, and hexa are used, to specify the number of ligands when two or more of same ligands are present.

The oxidation number of the metal is written after the name of the metal in roman numerals.

If the complex is an anion, its name ends with ‘-ate’.

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Answer 5

Chapter 22, Problem 16QP

Interpretation Introduction

Interpretation:

The formula of the given compoundis to be determined:

Concept introduction:

Coordination compounds are the compounds formed by the reaction of metal ions with polar molecules, or with a group of anions. They contain coordinate covalent bonds.

Oxidation state is also known as oxidation number. It is used to describe the oxidation, that is, theloss of electrons, in any compound.

The ligands are named first in alphabetical order and metal ion last in a complex ion.

The name of anionic ligand ends with letter ‘o”.

The neutral ligands are called by the name of the molecule except CO (carbonyl), NH3 (ammine), and H2O (aqua).

Prefixes di, tri, tetra, penta, and hexa are used, to specify the number of ligands when two or more of same ligands are present.

The oxidation number of the metal is written after the name of the metal in roman numerals.

If the complex is an anion, its name ends with ‘-ate’.

Answer 6

Chapter 22, Problem 16QP

Interpretation Introduction

Interpretation:

The formula of the given compoundis to be determined:

Concept introduction:

Coordination compounds are the compounds formed by the reaction of metal ions with polar molecules, or with a group of anions. They contain coordinate covalent bonds.

Oxidation state is also known as oxidation number. It is used to describe the oxidation, that is, theloss of electrons, in any compound.

The ligands are named first in alphabetical order and metal ion last in a complex ion.

The name of anionic ligand ends with letter ‘o”.

The neutral ligands are called by the name of the molecule except CO (carbonyl), NH3 (ammine), and H2O (aqua).

Prefixes di, tri, tetra, penta, and hexa are used, to specify the number of ligands when two or more of same ligands are present.

The oxidation number of the metal is written after the name of the metal in roman numerals.

If the complex is an anion, its name ends with ‘-ate’.

Answer 7

Chapter 22, Problem 16QP

Interpretation Introduction

Interpretation:

The formula of the given compoundis to be determined:

Concept introduction:

Coordination compounds are the compounds formed by the reaction of metal ions with polar molecules, or with a group of anions. They contain coordinate covalent bonds.

Oxidation state is also known as oxidation number. It is used to describe the oxidation, that is, theloss of electrons, in any compound.

The ligands are named first in alphabetical order and metal ion last in a complex ion.

The name of anionic ligand ends with letter ‘o”.

The neutral ligands are called by the name of the molecule except CO (carbonyl), NH3 (ammine), and H2O (aqua).

Prefixes di, tri, tetra, penta, and hexa are used, to specify the number of ligands when two or more of same ligands are present.

The oxidation number of the metal is written after the name of the metal in roman numerals.

If the complex is an anion, its name ends with ‘-ate’.

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 22.1 - Prob. 1PPA Ch. 22.1 - Prob. 1PPB Ch. 22.1 - Prob. 1PPC Ch. 22.1 - Prob. 1CP Ch. 22.1 - Prob. 2CP Ch. 22.1 - Prob. 3CP Ch. 22.1 - Prob. 4CP Ch. 22.2 - Prob. 1PPA Ch. 22.2 - Prob. 1PPB Ch. 22.2 - Prob. 1PPC

Solution Summary: The author explains that coordination compounds are formed by the reaction of metal ions with polar molecules.

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Chapter 22 Solutions