(a) Interpretation: The name of each compound shown in the ball-and-stick model should be determined. Concept Introduction: In the ball-and-stick model, each atom has a specific color. Red − Oxygen atoms. White − H atoms. Black − Carbon atoms. Blue − N atoms.

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Answer 1

Question

Chapter 22, Problem 19P

Interpretation Introduction

(a)

Interpretation:

The name of each compound shown in the ball-and-stick model should be determined.

Concept Introduction:

In the ball-and-stick model, each atom has a specific color.

Red − Oxygen atoms.

White − H atoms.

Black − Carbon atoms.

Blue − N atoms.

Interpretation Introduction

(b)

Interpretation:

The compound needs to be classified as a base, nucleoside or nucleotide.

Concept Introduction:

In the nucleic acids, there are 5 common nitrogen-containing bases.

From the parent compound pyrimidine, there are three bases derived namely cytosine, uracil, and thymine.

There are two bases with two rings are derived from the parent compound purine which is adenine and guanine.

The anomeric carbon of monosaccharide joined with a nitrogen atom to form a nucleoside.

To make a nucleotide; a phosphate group is added to the 5'-OH of a nucleoside.

Nucleotides are named by adding the term 5'-monophosphate to the name of the nucleoside from whichthey are derived.

Ribonucleotides are derived from ribose. Deoxyribonucleotides arederived from 2-deoxyribose.

Interpretation Introduction

(c)

Interpretation:

Whether the compound is a component of RNA, DNA or both should be determined.

Concept Introduction:

There are two types of nucleotides. They are DNA and RNA. Nucleic acids are composed of monomers called nucleotides.

There are five common nitrogen-containing bases that are present in nucleic acids; cytosine, uracil, thymine, adenine, and guanine.

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(a 4 shows scanning electron microscope (SEM) images of extruded actions of packing bed for two capillary columns of different diameters, al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the same stationary phase, spherical particles with 1-um diameter. A) When the columns were prepared, the figure shows that the column with the larger diameter has more packing irregularities. Explain this observation. B) Predict what affect this should have on band broadening and discuss your prediction using the van Deemter terms. C) Does this figure support your explanations in application question 33? Explain why or why not and make any changes in your answers in light of this figure. Figure 4 SEM images of sections of packed columns for a) 750 and b) 30-um-i.d. capillary columns.³

fcrip = ↓ bandwidth Il temp 32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual components of the van Deemter equation and consequently, band broadening? Increase temperature Longer column Using a gas mobile phase instead of liquid Smaller particle stationary phase Multiple Paths Diffusion Mass Transfer

34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.). A) Predict whether decreasing the column inner diameters increase or decrease bandwidth. B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or decreasing bandwidth as a function of i.d. and justify your answer. Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles. 35 20 H(um) 큰 20 15 90 0+ 1500 100 75 550 01 02 594 05 μ(cm/sec) 30 15 10

Answer 2

Question

Chapter 22, Problem 19P

Interpretation Introduction

(a)

Interpretation:

The name of each compound shown in the ball-and-stick model should be determined.

Concept Introduction:

In the ball-and-stick model, each atom has a specific color.

Red − Oxygen atoms.

White − H atoms.

Black − Carbon atoms.

Blue − N atoms.

Interpretation Introduction

(b)

Interpretation:

The compound needs to be classified as a base, nucleoside or nucleotide.

Concept Introduction:

In the nucleic acids, there are 5 common nitrogen-containing bases.

From the parent compound pyrimidine, there are three bases derived namely cytosine, uracil, and thymine.

There are two bases with two rings are derived from the parent compound purine which is adenine and guanine.

The anomeric carbon of monosaccharide joined with a nitrogen atom to form a nucleoside.

To make a nucleotide; a phosphate group is added to the 5'-OH of a nucleoside.

Nucleotides are named by adding the term 5'-monophosphate to the name of the nucleoside from whichthey are derived.

Ribonucleotides are derived from ribose. Deoxyribonucleotides arederived from 2-deoxyribose.

Interpretation Introduction

(c)

Interpretation:

Whether the compound is a component of RNA, DNA or both should be determined.

Concept Introduction:

There are two types of nucleotides. They are DNA and RNA. Nucleic acids are composed of monomers called nucleotides.

There are five common nitrogen-containing bases that are present in nucleic acids; cytosine, uracil, thymine, adenine, and guanine.

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 22, Problem 19P

Interpretation Introduction

(a)

Interpretation:

The name of each compound shown in the ball-and-stick model should be determined.

Concept Introduction:

In the ball-and-stick model, each atom has a specific color.

Red − Oxygen atoms.

White − H atoms.

Black − Carbon atoms.

Blue − N atoms.

Interpretation Introduction

(b)

Interpretation:

The compound needs to be classified as a base, nucleoside or nucleotide.

Concept Introduction:

In the nucleic acids, there are 5 common nitrogen-containing bases.

From the parent compound pyrimidine, there are three bases derived namely cytosine, uracil, and thymine.

There are two bases with two rings are derived from the parent compound purine which is adenine and guanine.

The anomeric carbon of monosaccharide joined with a nitrogen atom to form a nucleoside.

To make a nucleotide; a phosphate group is added to the 5'-OH of a nucleoside.

Nucleotides are named by adding the term 5'-monophosphate to the name of the nucleoside from whichthey are derived.

Ribonucleotides are derived from ribose. Deoxyribonucleotides arederived from 2-deoxyribose.

Interpretation Introduction

(c)

Interpretation:

Whether the compound is a component of RNA, DNA or both should be determined.

Concept Introduction:

There are two types of nucleotides. They are DNA and RNA. Nucleic acids are composed of monomers called nucleotides.

There are five common nitrogen-containing bases that are present in nucleic acids; cytosine, uracil, thymine, adenine, and guanine.

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Answer 4

Question

Chapter 22, Problem 19P

Interpretation Introduction

(a)

Interpretation:

The name of each compound shown in the ball-and-stick model should be determined.

Concept Introduction:

In the ball-and-stick model, each atom has a specific color.

Red − Oxygen atoms.

White − H atoms.

Black − Carbon atoms.

Blue − N atoms.

Interpretation Introduction

(b)

Interpretation:

The compound needs to be classified as a base, nucleoside or nucleotide.

Concept Introduction:

In the nucleic acids, there are 5 common nitrogen-containing bases.

From the parent compound pyrimidine, there are three bases derived namely cytosine, uracil, and thymine.

There are two bases with two rings are derived from the parent compound purine which is adenine and guanine.

The anomeric carbon of monosaccharide joined with a nitrogen atom to form a nucleoside.

To make a nucleotide; a phosphate group is added to the 5'-OH of a nucleoside.

Nucleotides are named by adding the term 5'-monophosphate to the name of the nucleoside from whichthey are derived.

Ribonucleotides are derived from ribose. Deoxyribonucleotides arederived from 2-deoxyribose.

Interpretation Introduction

(c)

Interpretation:

Whether the compound is a component of RNA, DNA or both should be determined.

Concept Introduction:

There are two types of nucleotides. They are DNA and RNA. Nucleic acids are composed of monomers called nucleotides.

There are five common nitrogen-containing bases that are present in nucleic acids; cytosine, uracil, thymine, adenine, and guanine.

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 5

Chapter 22, Problem 19P

Interpretation Introduction

(a)

Interpretation:

The name of each compound shown in the ball-and-stick model should be determined.

Concept Introduction:

In the ball-and-stick model, each atom has a specific color.

Red − Oxygen atoms.

White − H atoms.

Black − Carbon atoms.

Blue − N atoms.

Interpretation Introduction

(b)

Interpretation:

The compound needs to be classified as a base, nucleoside or nucleotide.

Concept Introduction:

In the nucleic acids, there are 5 common nitrogen-containing bases.

From the parent compound pyrimidine, there are three bases derived namely cytosine, uracil, and thymine.

There are two bases with two rings are derived from the parent compound purine which is adenine and guanine.

The anomeric carbon of monosaccharide joined with a nitrogen atom to form a nucleoside.

To make a nucleotide; a phosphate group is added to the 5'-OH of a nucleoside.

Nucleotides are named by adding the term 5'-monophosphate to the name of the nucleoside from whichthey are derived.

Ribonucleotides are derived from ribose. Deoxyribonucleotides arederived from 2-deoxyribose.

Interpretation Introduction

(c)

Interpretation:

Whether the compound is a component of RNA, DNA or both should be determined.

Concept Introduction:

There are two types of nucleotides. They are DNA and RNA. Nucleic acids are composed of monomers called nucleotides.

There are five common nitrogen-containing bases that are present in nucleic acids; cytosine, uracil, thymine, adenine, and guanine.

Answer 6

Chapter 22, Problem 19P

Interpretation Introduction

(a)

Interpretation:

The name of each compound shown in the ball-and-stick model should be determined.

Concept Introduction:

In the ball-and-stick model, each atom has a specific color.

Red − Oxygen atoms.

White − H atoms.

Black − Carbon atoms.

Blue − N atoms.

Answer 7

Chapter 22, Problem 19P

Interpretation Introduction

(a)

Interpretation:

The name of each compound shown in the ball-and-stick model should be determined.

Concept Introduction:

In the ball-and-stick model, each atom has a specific color.

Red − Oxygen atoms.

White − H atoms.

Black − Carbon atoms.

Blue − N atoms.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The compound needs to be classified as a base, nucleoside or nucleotide.

Concept Introduction:

In the nucleic acids, there are 5 common nitrogen-containing bases.

From the parent compound pyrimidine, there are three bases derived namely cytosine, uracil, and thymine.

There are two bases with two rings are derived from the parent compound purine which is adenine and guanine.

The anomeric carbon of monosaccharide joined with a nitrogen atom to form a nucleoside.

To make a nucleotide; a phosphate group is added to the 5'-OH of a nucleoside.

Nucleotides are named by adding the term 5'-monophosphate to the name of the nucleoside from whichthey are derived.

Ribonucleotides are derived from ribose. Deoxyribonucleotides arederived from 2-deoxyribose.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The compound needs to be classified as a base, nucleoside or nucleotide.

Concept Introduction:

In the nucleic acids, there are 5 common nitrogen-containing bases.

From the parent compound pyrimidine, there are three bases derived namely cytosine, uracil, and thymine.

There are two bases with two rings are derived from the parent compound purine which is adenine and guanine.

The anomeric carbon of monosaccharide joined with a nitrogen atom to form a nucleoside.

To make a nucleotide; a phosphate group is added to the 5'-OH of a nucleoside.

Nucleotides are named by adding the term 5'-monophosphate to the name of the nucleoside from whichthey are derived.

Ribonucleotides are derived from ribose. Deoxyribonucleotides arederived from 2-deoxyribose.

Answer 10

Interpretation Introduction

(c)

Interpretation:

Whether the compound is a component of RNA, DNA or both should be determined.

Concept Introduction:

There are two types of nucleotides. They are DNA and RNA. Nucleic acids are composed of monomers called nucleotides.

There are five common nitrogen-containing bases that are present in nucleic acids; cytosine, uracil, thymine, adenine, and guanine.

Answer 11

Interpretation Introduction

(c)

Interpretation:

Whether the compound is a component of RNA, DNA or both should be determined.

Concept Introduction:

There are two types of nucleotides. They are DNA and RNA. Nucleic acids are composed of monomers called nucleotides.

There are five common nitrogen-containing bases that are present in nucleic acids; cytosine, uracil, thymine, adenine, and guanine.

Answer 12

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Answer 13

Expert Solution & Answer

Answer 14

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Answer 15

Ch. 22.1 - Prob. 22.1PP Ch. 22.1 - Prob. 22.1P Ch. 22.1 - -Fluorouracil is an anticancer drug that...Ch. 22.1 - Prob. 22.3P Ch. 22.1 - Prob. 22.4P Ch. 22.1 - Label each statement about the compound...Ch. 22.1 - Draw the structure of each nucleotide: (a) UMP;...Ch. 22.1 - Give the name that corresponds to each...Ch. 22.2 - Draw the structure of a dinucleotide formed by...Ch. 22.2 - Draw the structure of each polynucleotide: (a) CU;...

(a) Interpretation: The name of each compound shown in the ball-and-stick model should be determined. Concept Introduction: In the ball-and-stick model, each atom has a specific color. Red − Oxygen atoms. White − H atoms. Black − Carbon atoms. Blue − N atoms.

Solution Summary: The author explains that the name of each compound in the ball-and-stick model should be determined.

Concept explainers

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(a)

Interpretation:

The name of each compound shown in the ball-and-stick model should be determined.

Concept Introduction:

In the ball-and-stick model, each atom has a specific color.

Red − Oxygen atoms.

White − H atoms.

Black − Carbon atoms.

Blue − N atoms.

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Chapter 22 Solutions