Chemistry with Access Code, Hybrid Edition
9th Edition
ISBN: 9781285188492
Author: Steven S. Zumdahl
Publisher: CENGAGE L
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Question
Chapter 22, Problem 17E
(a)
Interpretation Introduction
Interpretation: The structures of the given compounds are to be drawn.
Concept introduction: Structure of any organic compound is drawn by following the sets of rules devised by IUPAC. Any structure denotes a particular compound. The root word determines the number of carbons while counting the longest carbon chain. Double of triple bond should be given lowest carbon number. Prefixes like di, tri, tetra, etc. signifies presence of more than one substituents.
(b)
Interpretation Introduction
Interpretation: The structures of the given compounds are to be drawn.
Concept introduction: Structure of any organic compound is drawn by following the sets of rules devised by IUPAC. Any structure denotes a particular compound. The root word determines the number of carbons while counting the longest carbon chain. Double of triple bond should be given lowest carbon number. Prefixes like di, tri, tetra, etc. signifies presence of more than one substituents.
(c)
Interpretation Introduction
Interpretation: The structures of the given compounds are to be drawn.
Concept introduction: Structure of any organic compound is drawn by following the sets of rules devised by IUPAC. Any structure denotes a particular compound. The root word determines the number of carbons while counting the longest carbon chain. Double of triple bond should be given lowest carbon number. Prefixes like di, tri, tetra, etc. signifies presence of more than one substituents.
(d)
Interpretation Introduction
Interpretation: The structures of the given compounds are to be drawn.
Concept introduction: Structure of any organic compound is drawn by following the sets of rules devised by IUPAC. Any structure denotes a particular compound. The root word determines the number of carbons while counting the longest carbon chain. Double of triple bond should be given lowest carbon number. Prefixes like di, tri, tetra, etc. signifies presence of more than one substituents.
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1. Consider the following molecular-level diagrams of a titration.
O-HA molecule
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a. Which diagram best illustrates the microscopic representation for the
EQUIVALENCE POINT in a titration of a weak acid (HA) with sodium.
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Answers to the remaining 6 questions will be hand-drawn on paper and submitted as a single
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Review of this week's reaction:
H₂NCN (cyanamide) + CH3NHCH2COOH (sarcosine) + NaCl, NH4OH, H₂O --->
H₂NC(=NH)N(CH3)CH2COOH (creatine)
Q7. Draw by hand the reaction of creatine synthesis listed above using line structures without showing
the Cs and some of the Hs, but include the lone pairs of electrons wherever they apply. (4 pts)
Q8. Considering the Zwitterion form of an amino acid, draw the Zwitterion form of Creatine. (2 pts)
Q9. Explain with drawing why the C-N bond shown in creatine structure below can or cannot rotate. (3
pts)
NH2(C=NH)-N(CH)CH2COOH
This bond
Q10. Draw two tautomers of creatine using line structures. (Note: this question is valid because problem
Q9 is valid). (4 pts)
Q11. Mechanism. After seeing and understanding the mechanism of creatine synthesis, students should
be ready to understand the first half of one of the Grignard reactions presented in a past…
Propose a synthesis pathway for the
following transformations. b) c) d)
Chapter 22 Solutions
Chemistry with Access Code, Hybrid Edition
Ch. 22 - What is a hydrocarbon? What is the difference...Ch. 22 - Prob. 2RQCh. 22 - What are aromatic hydrocarbons? Benzene exhibits...Ch. 22 - Summarize the nomenclature rules for alkanes,...Ch. 22 - What functional group distinguishes each of the...Ch. 22 - Distinguish between isomerism and resonance....Ch. 22 - Prob. 7RQCh. 22 - Prob. 8RQCh. 22 - Prob. 9RQCh. 22 - Prob. 10RQ
Ch. 22 - Prob. 11RQCh. 22 - Describe the structural differences between DNA...Ch. 22 - Prob. 1QCh. 22 - Prob. 2QCh. 22 - Prob. 3QCh. 22 - Prob. 4QCh. 22 - Prob. 5QCh. 22 - Prob. 6QCh. 22 - Prob. 7QCh. 22 - Give an example reaction that would yield the...Ch. 22 - Prob. 9QCh. 22 - Prob. 10QCh. 22 - Prob. 11QCh. 22 - Prob. 12QCh. 22 - Prob. 13ECh. 22 - Prob. 14ECh. 22 - Draw all the structural isomers for C8H18 that...Ch. 22 - Draw all the structural isomers for C8H18 that...Ch. 22 - Prob. 17ECh. 22 - Prob. 18ECh. 22 - Draw the structural formula for each of the...Ch. 22 - Prob. 20ECh. 22 - Prob. 21ECh. 22 - Name each of the following cyclic alkanes, and...Ch. 22 - Prob. 23ECh. 22 - Draw the structures for two examples of...Ch. 22 - Name each of the following alkenes. a. CH2 = CH ...Ch. 22 - Name each of the following alkenes or alkynes. a....Ch. 22 - Prob. 27ECh. 22 - Give the structure for each of the following. a....Ch. 22 - Prob. 29ECh. 22 - Cumene is the starting material for the industrial...Ch. 22 - Name each of the following. a. b. CH3CH2CH2CCl3 c....Ch. 22 - Prob. 32ECh. 22 - There is only one compound that is named...Ch. 22 - Prob. 34ECh. 22 - Prob. 35ECh. 22 - Prob. 36ECh. 22 - Draw all the structural isomers of C5H10. Ignore...Ch. 22 - Prob. 38ECh. 22 - Draw all the structural and geometrical (cistrans)...Ch. 22 - Draw all the structural and geometrical (cistrans)...Ch. 22 - Draw all structural and geometrical (cistrans)...Ch. 22 - Prob. 42ECh. 22 - Prob. 43ECh. 22 - Prob. 44ECh. 22 - If one hydrogen in a hydrocarbon is replaced by a...Ch. 22 - There are three isomers of dichlorobenzene, one of...Ch. 22 - Identify each of the following compounds as a...Ch. 22 - Prob. 48ECh. 22 - Mimosine is a natural product found in large...Ch. 22 - Minoxidil (C9H15N5O) is a compound produced by...Ch. 22 - For each of the following alcohols, give the...Ch. 22 - Prob. 52ECh. 22 - Prob. 53ECh. 22 - Prob. 54ECh. 22 - Prob. 55ECh. 22 - Prob. 56ECh. 22 - Prob. 57ECh. 22 - Prob. 58ECh. 22 - Prob. 59ECh. 22 - Prob. 60ECh. 22 - Prob. 61ECh. 22 - Prob. 62ECh. 22 - Prob. 63ECh. 22 - Prob. 64ECh. 22 - Prob. 65ECh. 22 - Prob. 66ECh. 22 - Prob. 67ECh. 22 - Prob. 68ECh. 22 - Prob. 69ECh. 22 - Prob. 70ECh. 22 - Prob. 71ECh. 22 - Prob. 72ECh. 22 - Super glue contains methyl cyanoacrylate, which...Ch. 22 - Prob. 74ECh. 22 - Prob. 75ECh. 22 - Prob. 76ECh. 22 - Prob. 77ECh. 22 - Prob. 78ECh. 22 - Prob. 79ECh. 22 - Prob. 80ECh. 22 - Prob. 81ECh. 22 - Prob. 82ECh. 22 - Prob. 83ECh. 22 - Prob. 84ECh. 22 - Aspartame, the artificial sweetener marketed under...Ch. 22 - Prob. 86ECh. 22 - Prob. 87ECh. 22 - Draw the structures of the tripeptides glyalaser...Ch. 22 - Prob. 89ECh. 22 - Prob. 90ECh. 22 - Give an example of amino acids that could give...Ch. 22 - What types of interactions can occur between the...Ch. 22 - Prob. 93ECh. 22 - Prob. 94ECh. 22 - Prob. 95ECh. 22 - Prob. 96ECh. 22 - Prob. 97ECh. 22 - Prob. 98ECh. 22 - Prob. 99ECh. 22 - Prob. 100ECh. 22 - Prob. 101ECh. 22 - Prob. 102ECh. 22 - Prob. 103ECh. 22 - Prob. 104ECh. 22 - Prob. 105ECh. 22 - Prob. 106ECh. 22 - Prob. 107ECh. 22 - Prob. 108ECh. 22 - The base sequences in mRNA that code for certain...Ch. 22 - Prob. 110ECh. 22 - Prob. 111AECh. 22 - Prob. 112AECh. 22 - Prob. 113AECh. 22 - Prob. 114AECh. 22 - Prob. 115AECh. 22 - Prob. 116AECh. 22 - Explain why methyl alcohol is soluble in water in...Ch. 22 - Prob. 118AECh. 22 - Prob. 119AECh. 22 - Prob. 120AECh. 22 - Prob. 121AECh. 22 - Prob. 122AECh. 22 - Prob. 123AECh. 22 - Prob. 124AECh. 22 - Prob. 125AECh. 22 - Prob. 126AECh. 22 - Prob. 127AECh. 22 - Prob. 128AECh. 22 - Prob. 129AECh. 22 - a. Use bond energies (see Table 3-3) to estimate H...Ch. 22 - Prob. 131AECh. 22 - Prob. 132AECh. 22 - All amino acids have at least two functional...Ch. 22 - Prob. 134AECh. 22 - Prob. 135AECh. 22 - In glycine, the carboxylic acid group has Ka = 4.3...Ch. 22 - Name each of the following alkanes. a....Ch. 22 - Prob. 138CWPCh. 22 - Name each of the following cyclic alkanes. a. b....Ch. 22 - Name each of the following alkenes and alkynes. a....Ch. 22 - a. Name each of the following alcohols. b. Name...Ch. 22 - Prob. 142CWPCh. 22 - Prob. 143CWPCh. 22 - Prob. 144CWPCh. 22 - Prob. 145CPCh. 22 - Prob. 146CPCh. 22 - Prob. 147CPCh. 22 - Consider a sample of a hydrocarbon at 0.959 atm...Ch. 22 - Prob. 149CPCh. 22 - Prob. 150CPCh. 22 - Prob. 151CPCh. 22 - Prob. 152CPCh. 22 - Prob. 153CPCh. 22 - Prob. 154CPCh. 22 - Prob. 155CPCh. 22 - Alcohols are very useful starting materials for...Ch. 22 - A chemical breathalyzer test works because ethanol...Ch. 22 - Estradiol is a female hormone with the following...Ch. 22 - Prob. 159IPCh. 22 - Prob. 160IPCh. 22 - Prob. 161MPCh. 22 - Prob. 162MP
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