Lab Manual For Zumdahl/zumdahl's Chemistry, 9th
9th Edition
ISBN: 9781285692357
Author: Steven S. Zumdahl, Susan A. Zumdahl
Publisher: Cengage Learning
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Chapter 22, Problem 139CWP
Name each of the following cyclic
a. 
b. 
c. 
d. 
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An organic chemistry Teaching Assistant (TA) suggested in your last discussion section that there is only one major organic product of the following reaction and
that this reaction builds a ring.
If the TA is right, draw the product in the drawing area below. If the TA is wrong, just check the box below the drawing area.
NaOH
?
A student suggests that the molecule on the right can be made from a single molecule that doesn't have a ring. If the student is correct, draw the starting
material below, otherwise, check the box under the drawing area.
Click and drag to start
drawing a structure.
: ☐
+
NaOH
टे
Rate = k [I]1.7303[S2O82-]0.8502,
Based on your rate, write down a mechanism consistent with your results and indicate which step is the rate determining step.
Chapter 22 Solutions
Lab Manual For Zumdahl/zumdahl's Chemistry, 9th
Ch. 22 - What is a hydrocarbon? What is the difference...Ch. 22 - Prob. 2RQCh. 22 - What are aromatic hydrocarbons? Benzene exhibits...Ch. 22 - Summarize the nomenclature rules for alkanes,...Ch. 22 - What functional group distinguishes each of the...Ch. 22 - Distinguish between isomerism and resonance....Ch. 22 - Prob. 7RQCh. 22 - Prob. 8RQCh. 22 - Prob. 9RQCh. 22 - Prob. 10RQ
Ch. 22 - Prob. 11RQCh. 22 - Describe the structural differences between DNA...Ch. 22 - Prob. 1QCh. 22 - Prob. 2QCh. 22 - Prob. 3QCh. 22 - Prob. 4QCh. 22 - Prob. 5QCh. 22 - Prob. 6QCh. 22 - Prob. 7QCh. 22 - Give an example reaction that would yield the...Ch. 22 - Prob. 9QCh. 22 - Prob. 10QCh. 22 - Prob. 11QCh. 22 - Prob. 12QCh. 22 - Prob. 13ECh. 22 - Prob. 14ECh. 22 - Draw all the structural isomers for C8H18 that...Ch. 22 - Draw all the structural isomers for C8H18 that...Ch. 22 - Prob. 17ECh. 22 - Prob. 18ECh. 22 - Draw the structural formula for each of the...Ch. 22 - Prob. 20ECh. 22 - Prob. 21ECh. 22 - Name each of the following cyclic alkanes, and...Ch. 22 - Prob. 23ECh. 22 - Draw the structures for two examples of...Ch. 22 - Name each of the following alkenes. a. CH2 = CH ...Ch. 22 - Name each of the following alkenes or alkynes. a....Ch. 22 - Prob. 27ECh. 22 - Give the structure for each of the following. a....Ch. 22 - Prob. 29ECh. 22 - Cumene is the starting material for the industrial...Ch. 22 - Name each of the following. a. b. CH3CH2CH2CCl3 c....Ch. 22 - Prob. 32ECh. 22 - There is only one compound that is named...Ch. 22 - Prob. 34ECh. 22 - Prob. 35ECh. 22 - Prob. 36ECh. 22 - Draw all the structural isomers of C5H10. Ignore...Ch. 22 - Prob. 38ECh. 22 - Draw all the structural and geometrical (cistrans)...Ch. 22 - Draw all the structural and geometrical (cistrans)...Ch. 22 - Draw all structural and geometrical (cistrans)...Ch. 22 - Prob. 42ECh. 22 - Prob. 43ECh. 22 - Prob. 44ECh. 22 - If one hydrogen in a hydrocarbon is replaced by a...Ch. 22 - There are three isomers of dichlorobenzene, one of...Ch. 22 - Identify each of the following compounds as a...Ch. 22 - Prob. 48ECh. 22 - Mimosine is a natural product found in large...Ch. 22 - Minoxidil (C9H15N5O) is a compound produced by...Ch. 22 - For each of the following alcohols, give the...Ch. 22 - Prob. 52ECh. 22 - Prob. 53ECh. 22 - Prob. 54ECh. 22 - Prob. 55ECh. 22 - Prob. 56ECh. 22 - Prob. 57ECh. 22 - Prob. 58ECh. 22 - Prob. 59ECh. 22 - Prob. 60ECh. 22 - Prob. 61ECh. 22 - Prob. 62ECh. 22 - Prob. 63ECh. 22 - Prob. 64ECh. 22 - Prob. 65ECh. 22 - Prob. 66ECh. 22 - Prob. 67ECh. 22 - Prob. 68ECh. 22 - Prob. 69ECh. 22 - Prob. 70ECh. 22 - Prob. 71ECh. 22 - Prob. 72ECh. 22 - Super glue contains methyl cyanoacrylate, which...Ch. 22 - Prob. 74ECh. 22 - Prob. 75ECh. 22 - Prob. 76ECh. 22 - Prob. 77ECh. 22 - Prob. 78ECh. 22 - Prob. 79ECh. 22 - Prob. 80ECh. 22 - Prob. 81ECh. 22 - Prob. 82ECh. 22 - Prob. 83ECh. 22 - Prob. 84ECh. 22 - Aspartame, the artificial sweetener marketed under...Ch. 22 - Prob. 86ECh. 22 - Prob. 87ECh. 22 - Draw the structures of the tripeptides glyalaser...Ch. 22 - Prob. 89ECh. 22 - Prob. 90ECh. 22 - Give an example of amino acids that could give...Ch. 22 - What types of interactions can occur between the...Ch. 22 - Prob. 93ECh. 22 - Prob. 94ECh. 22 - Prob. 95ECh. 22 - Prob. 96ECh. 22 - Prob. 97ECh. 22 - Prob. 98ECh. 22 - Prob. 99ECh. 22 - Prob. 100ECh. 22 - Prob. 101ECh. 22 - Prob. 102ECh. 22 - Prob. 103ECh. 22 - Prob. 104ECh. 22 - Prob. 105ECh. 22 - Prob. 106ECh. 22 - Prob. 107ECh. 22 - Prob. 108ECh. 22 - The base sequences in mRNA that code for certain...Ch. 22 - Prob. 110ECh. 22 - Prob. 111AECh. 22 - Prob. 112AECh. 22 - Prob. 113AECh. 22 - Prob. 114AECh. 22 - Prob. 115AECh. 22 - Prob. 116AECh. 22 - Explain why methyl alcohol is soluble in water in...Ch. 22 - Prob. 118AECh. 22 - Prob. 119AECh. 22 - Prob. 120AECh. 22 - Prob. 121AECh. 22 - Prob. 122AECh. 22 - Prob. 123AECh. 22 - Prob. 124AECh. 22 - Prob. 125AECh. 22 - Prob. 126AECh. 22 - Prob. 127AECh. 22 - Prob. 128AECh. 22 - Prob. 129AECh. 22 - a. Use bond energies (see Table 3-3) to estimate H...Ch. 22 - Prob. 131AECh. 22 - Prob. 132AECh. 22 - All amino acids have at least two functional...Ch. 22 - Prob. 134AECh. 22 - Prob. 135AECh. 22 - In glycine, the carboxylic acid group has Ka = 4.3...Ch. 22 - Name each of the following alkanes. a....Ch. 22 - Prob. 138CWPCh. 22 - Name each of the following cyclic alkanes. a. b....Ch. 22 - Name each of the following alkenes and alkynes. a....Ch. 22 - a. Name each of the following alcohols. b. Name...Ch. 22 - Prob. 142CWPCh. 22 - Prob. 143CWPCh. 22 - Prob. 144CWPCh. 22 - Prob. 145CPCh. 22 - Prob. 146CPCh. 22 - Prob. 147CPCh. 22 - Consider a sample of a hydrocarbon at 0.959 atm...Ch. 22 - Prob. 149CPCh. 22 - Prob. 150CPCh. 22 - Prob. 151CPCh. 22 - Prob. 152CPCh. 22 - Prob. 153CPCh. 22 - Prob. 154CPCh. 22 - Prob. 155CPCh. 22 - Alcohols are very useful starting materials for...Ch. 22 - A chemical breathalyzer test works because ethanol...Ch. 22 - Estradiol is a female hormone with the following...Ch. 22 - Prob. 159IPCh. 22 - Prob. 160IPCh. 22 - Prob. 161MPCh. 22 - Prob. 162MP
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- 36. Give the major product(s) of each of the following reactions. Aqueous work-up steps (when necessary) have been omitted. a. CH3CH=CHCH3 b. CH3CH2CH2CCH3 H,PO₂, H₂O, A (Hint: See Section 2-2.) 1. LIAIH. (CH,CH,),O 2. H', H₂O H NaBH, CH,CH₂OH d. Br LIAIH. (CH,CH,)₂O f. CH3 NaBH, CH,CH,OH (CH3)2CH H NaBH, CH,CH₂OH Harrow_forwardPredict the major products of this reaction: + H excess NaOH Δ ? Note that the second reactant is used in excess, that is, there is much more of the second reactant than the first. If there won't be any products, just check the box under the drawing area instead.arrow_forwardAn organic chemistry Teaching Assistant (TA) suggested in your last discussion section that there is only one major organic product of the following reaction and that this reaction builds a ring. If the TA is right, draw the product in the drawing area below. If the TA is wrong, just check the box below the drawing area. 1. NaOMe CH3O N. OCH3 ? 2. H3O+arrow_forward
- Complete the reaction in the drawing area below by adding the major products to the right-hand side. If there won't be any products, because nothing will happen under these reaction conditions, check the box under the drawing area instead. Note: if the products contain one or more pairs of enantiomers, don't worry about drawing each enantiomer with dash and wedge bonds. Just draw one molecule to represent each pair of enantiomers, using line bonds at the chiral center. + More... ☐ ☐ : ☐ + G 1. NaOMe Click and drag to start drawing a structure. 2. H +arrow_forward6. Ammonia reacts with nitrogen monoxide and oxygen to form nitrogen and water vapor. If the rate of consumption of NO is 4.5 mollitermin) (a) Find the rate of reaction (b) Find the rate of formations of N; and HO (c) Find the rate of consumption of NH, and O 4NH: 4NO 0:4: +60arrow_forward34. Give the expected major product of each of the following reactions. Conc. HI a. CH3CH2CH2OH b. (CH3)2CHCH2CH2OH Conc. HBr H Conc. HI C. OH Conc.HCI d. (CH3CH2)3COHarrow_forward
- 42. Which of the following halogenated compounds can be used successfully to prepare a Grignard reagent for alcohol synthesis by subsequent reaction with an aldehyde or ketone? Which ones cannot and why? H3C CH3 a. Br H OH b. Cl C. I H H d. Cl e. H OCH3 Br Harrow_forwardFor each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. ? Will the first MgBr product that forms in this reaction create a new CC bond? olo ? OH جمله O Yes Ⓒ No MgCl ? Will the first product that forms in this reaction create a new CC bond? Click and drag to start drawing a structure. Yes No X ☐ : ☐ टे PHarrow_forwardAssign all the protonsarrow_forward
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