A mechanism corresponding to the basic hydrolysis of benzonitrile to the benzoate ion and ammonia is to be stated. Concept introduction: The basic hydrolysis of benzonitrile to the benzoate ion and ammonia comprises three steps. The first step is the addition of hydroxide ion to the carbon of cyano group. The second step is formation of enol tautomer of amide. The third step is the tautomerism (removal and displacement of a proton).

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Answer 1

Question

Chapter 21.7D, Problem 21.22P

Interpretation Introduction

Interpretation:

A mechanism corresponding to the basic hydrolysis of benzonitrile to the benzoate ion and ammonia is to be stated.

Concept introduction:

The basic hydrolysis of benzonitrile to the benzoate ion and ammonia comprises three steps. The first step is the addition of hydroxide ion to the carbon of cyano group. The second step is formation of enol tautomer of amide. The third step is the tautomerism (removal and displacement of a proton).

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Draw the two products of the reaction. H₂C. CH₂ H :0: CH3 CH₂ +1

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Answer 2

Question

Chapter 21.7D, Problem 21.22P

Interpretation Introduction

Interpretation:

A mechanism corresponding to the basic hydrolysis of benzonitrile to the benzoate ion and ammonia is to be stated.

Concept introduction:

The basic hydrolysis of benzonitrile to the benzoate ion and ammonia comprises three steps. The first step is the addition of hydroxide ion to the carbon of cyano group. The second step is formation of enol tautomer of amide. The third step is the tautomerism (removal and displacement of a proton).

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Answer 3

Question

Chapter 21.7D, Problem 21.22P

Interpretation Introduction

Interpretation:

A mechanism corresponding to the basic hydrolysis of benzonitrile to the benzoate ion and ammonia is to be stated.

Concept introduction:

The basic hydrolysis of benzonitrile to the benzoate ion and ammonia comprises three steps. The first step is the addition of hydroxide ion to the carbon of cyano group. The second step is formation of enol tautomer of amide. The third step is the tautomerism (removal and displacement of a proton).

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Answer 4

Question

Chapter 21.7D, Problem 21.22P

Interpretation Introduction

Interpretation:

A mechanism corresponding to the basic hydrolysis of benzonitrile to the benzoate ion and ammonia is to be stated.

Concept introduction:

The basic hydrolysis of benzonitrile to the benzoate ion and ammonia comprises three steps. The first step is the addition of hydroxide ion to the carbon of cyano group. The second step is formation of enol tautomer of amide. The third step is the tautomerism (removal and displacement of a proton).

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Answer 5

Chapter 21.7D, Problem 21.22P

Interpretation Introduction

Interpretation:

A mechanism corresponding to the basic hydrolysis of benzonitrile to the benzoate ion and ammonia is to be stated.

Concept introduction:

The basic hydrolysis of benzonitrile to the benzoate ion and ammonia comprises three steps. The first step is the addition of hydroxide ion to the carbon of cyano group. The second step is formation of enol tautomer of amide. The third step is the tautomerism (removal and displacement of a proton).

Answer 6

Chapter 21.7D, Problem 21.22P

Interpretation Introduction

Interpretation:

A mechanism corresponding to the basic hydrolysis of benzonitrile to the benzoate ion and ammonia is to be stated.

Concept introduction:

The basic hydrolysis of benzonitrile to the benzoate ion and ammonia comprises three steps. The first step is the addition of hydroxide ion to the carbon of cyano group. The second step is formation of enol tautomer of amide. The third step is the tautomerism (removal and displacement of a proton).

Answer 7

Chapter 21.7D, Problem 21.22P

Interpretation Introduction

Interpretation:

A mechanism corresponding to the basic hydrolysis of benzonitrile to the benzoate ion and ammonia is to be stated.

Concept introduction:

The basic hydrolysis of benzonitrile to the benzoate ion and ammonia comprises three steps. The first step is the addition of hydroxide ion to the carbon of cyano group. The second step is formation of enol tautomer of amide. The third step is the tautomerism (removal and displacement of a proton).

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 21.2F - Name the following carboxylic acid derivatives,...Ch. 21.4A - Prob. 21.2P Ch. 21.4A - Prob. 21.3P Ch. 21.4A - Prob. 21.4P Ch. 21.5C - Prob. 21.7P Ch. 21.6 - When ethyl 4-hydroxybutyrate is heated in the...Ch. 21.6 - Propose a mechanism for the following ring-opening...Ch. 21.6 - Prob. 21.15P Ch. 21.7B - Prob. 21.16P Ch. 21.7C - Prob. 21.19P

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