The accomplishment of the given transformation by the use of nitrile as an intermediate is to be shown. Concept introduction: The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine .

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Answer 1

Question

Chapter 21.14, Problem 21.39P

(a)

Interpretation Introduction

Interpretation:

The accomplishment of the given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

(b)

Interpretation Introduction

Interpretation:

The accomplishment of given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

Grignard reagent is used to generate R− carbanion which attack on electron deficient centre. Carbonyl group that has good leaving group gives substituted product. This reagent is used to convert carbonyl group into alcohol.

(c)

Interpretation Introduction

Interpretation:

The accomplishment of given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

Grignard reagent is used to generate R− carbanion which attack on electron deficient centre. Carbonyl group that has good leaving group gives substituted product. This reagent is used to convert carbonyl group into alcohol.

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3. Consider the compounds below and determine if they are aromatic, antiaromatic, or non-aromatic. In case of aromatic or anti-aromatic, please indicate number of I electrons in the respective systems. (Hint: 1. Not all lone pair electrons were explicitly drawn and you should be able to tell that the bonding electrons and lone pair electrons should reside in which hybridized atomic orbital 2. You should consider ring strain- flexibility and steric repulsion that facilitates adoption of aromaticity or avoidance of anti- aromaticity) H H N N: NH2 N Aromaticity (Circle) Aromatic Aromatic Aromatic Aromatic Aromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic nonaromatic nonaromatic nonaromatic nonaromatic nonaromatic aromatic TT electrons Me H Me Aromaticity (Circle) Aromatic Aromatic Aromatic Aromatic Aromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic nonaromatic nonaromatic nonaromatic nonaromatic nonaromatic aromatic πT electrons H HH…

Answer 2

Question

Chapter 21.14, Problem 21.39P

(a)

Interpretation Introduction

Interpretation:

The accomplishment of the given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

(b)

Interpretation Introduction

Interpretation:

The accomplishment of given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

Grignard reagent is used to generate R− carbanion which attack on electron deficient centre. Carbonyl group that has good leaving group gives substituted product. This reagent is used to convert carbonyl group into alcohol.

(c)

Interpretation Introduction

Interpretation:

The accomplishment of given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

Grignard reagent is used to generate R− carbanion which attack on electron deficient centre. Carbonyl group that has good leaving group gives substituted product. This reagent is used to convert carbonyl group into alcohol.

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Answer 3

Question

Chapter 21.14, Problem 21.39P

(a)

Interpretation Introduction

Interpretation:

The accomplishment of the given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

(b)

Interpretation Introduction

Interpretation:

The accomplishment of given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

Grignard reagent is used to generate R− carbanion which attack on electron deficient centre. Carbonyl group that has good leaving group gives substituted product. This reagent is used to convert carbonyl group into alcohol.

(c)

Interpretation Introduction

Interpretation:

The accomplishment of given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

Grignard reagent is used to generate R− carbanion which attack on electron deficient centre. Carbonyl group that has good leaving group gives substituted product. This reagent is used to convert carbonyl group into alcohol.

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Answer 4

Question

Chapter 21.14, Problem 21.39P

(a)

Interpretation Introduction

Interpretation:

The accomplishment of the given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

(b)

Interpretation Introduction

Interpretation:

The accomplishment of given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

Grignard reagent is used to generate R− carbanion which attack on electron deficient centre. Carbonyl group that has good leaving group gives substituted product. This reagent is used to convert carbonyl group into alcohol.

(c)

Interpretation Introduction

Interpretation:

The accomplishment of given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

Grignard reagent is used to generate R− carbanion which attack on electron deficient centre. Carbonyl group that has good leaving group gives substituted product. This reagent is used to convert carbonyl group into alcohol.

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Answer 5

Chapter 21.14, Problem 21.39P

(a)

Interpretation Introduction

Interpretation:

The accomplishment of the given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

(b)

Interpretation Introduction

Interpretation:

The accomplishment of given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

Grignard reagent is used to generate R− carbanion which attack on electron deficient centre. Carbonyl group that has good leaving group gives substituted product. This reagent is used to convert carbonyl group into alcohol.

(c)

Interpretation Introduction

Interpretation:

The accomplishment of given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

Grignard reagent is used to generate R− carbanion which attack on electron deficient centre. Carbonyl group that has good leaving group gives substituted product. This reagent is used to convert carbonyl group into alcohol.

Answer 6

Chapter 21.14, Problem 21.39P

(a)

Interpretation Introduction

Interpretation:

The accomplishment of the given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

Answer 7

Chapter 21.14, Problem 21.39P

(a)

Interpretation Introduction

Interpretation:

The accomplishment of the given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The accomplishment of given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

Grignard reagent is used to generate R− carbanion which attack on electron deficient centre. Carbonyl group that has good leaving group gives substituted product. This reagent is used to convert carbonyl group into alcohol.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The accomplishment of given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

Grignard reagent is used to generate R− carbanion which attack on electron deficient centre. Carbonyl group that has good leaving group gives substituted product. This reagent is used to convert carbonyl group into alcohol.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The accomplishment of given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

Grignard reagent is used to generate R− carbanion which attack on electron deficient centre. Carbonyl group that has good leaving group gives substituted product. This reagent is used to convert carbonyl group into alcohol.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The accomplishment of given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

Grignard reagent is used to generate R− carbanion which attack on electron deficient centre. Carbonyl group that has good leaving group gives substituted product. This reagent is used to convert carbonyl group into alcohol.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 21.2F - Name the following carboxylic acid derivatives,...Ch. 21.4A - Prob. 21.2P Ch. 21.4A - Prob. 21.3P Ch. 21.4A - Prob. 21.4P Ch. 21.5C - Prob. 21.7P Ch. 21.6 - When ethyl 4-hydroxybutyrate is heated in the...Ch. 21.6 - Propose a mechanism for the following ring-opening...Ch. 21.6 - Prob. 21.15P Ch. 21.7B - Prob. 21.16P Ch. 21.7C - Prob. 21.19P

The accomplishment of the given transformation by the use of nitrile as an intermediate is to be shown. Concept introduction: The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine .

Solution Summary: The author illustrates the transformation of 1-hexanol by the use of nitrile as an intermediate. Grignard reagent is used to generate R- carbanion which

Concept explainers

Interpretation:

The accomplishment of the given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

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Chapter 21 Solutions

The accomplishment of the given transformation by the use of nitrile as an intermediate is to be shown. Concept introduction: The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine .

Solution Summary: The author illustrates the transformation of 1-hexanol by the use of nitrile as an intermediate. Grignard reagent is used to generate R- carbanion which

Concept explainers

Interpretation: The accomplishment of the given transformation by the use of nitrile as an intermediate is to be shown. Concept introduction: The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

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Chapter 21 Solutions

Interpretation:

The accomplishment of the given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.