Organic Chemistry - Standalone book
10th Edition
ISBN: 9780073511214
Author: Francis A Carey Dr., Robert M. Giuliano
Publisher: McGraw-Hill Education
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Textbook Question
Chapter 2.14, Problem 8P
Refer to Table
Beeswax (Figure
formula for hentriacontane.
Octacosane has been found to be present in a certain fossil plant. Write a
condensed structural formula for octacosane.
What is the IUPAC name of the
the cockroach aggregation pheromone?
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1) Explain the similarities and differences between Lewis structures and line drawings. Provide a drawn example
different from the one shown in the video.
2) Provide a summary of the IUPAC rules. Do not copy them verbatim from the lecture video.
3) Draw and name an alkane or cycloalkane that has 3 different substituents. You can not have the same example as
someone else.
4) Draw and name an alkene that has an alkyne substituent. You can not have the same example as someone else.
5) Provide your own list of alkanes. They can not be the same structure but should all have the same number of
carbons. (see the problem solving video for an example) Rank them in order of increasing melting point. You can not
have the same example as someone else.
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Following are IUPAC names and structural formulas for compound Divide each name into a prefix, an infix, and a suffix and specify the information about the structural formula that is contained in each part of the name.
Indicate which of the following are true of pentane. For each false statement, describe the reason that it
is false.
It has a higher melting point than decane.
It can hydrogen bond with water.
It is a saturated hydrocarbon.
It has the following structural formula: CsH12. True
True
False
Faise
It can exist as 3 structural isomers.
True
It has weaker London dispersion forces between molecules than octane. False
It is a structural isomer of 2-methylpropane.
It can undergo combustion reaction.
False
True
Chapter 2 Solutions
Organic Chemistry - Standalone book
Ch. 2.4 - Prob. 1PCh. 2.7 - Prob. 2PCh. 2.8 - Identify the orbital overlaps of all of the bonds...Ch. 2.9 - The hydrocarbon shown, called vinylacetylene, is...Ch. 2.12 - Prob. 5PCh. 2.12 - Prob. 6PCh. 2.13 - Prob. 7PCh. 2.14 - Refer to Table 2.2 as needed to answer the...Ch. 2.15 - Prob. 9PCh. 2.15 - Prob. 10P
Ch. 2.16 - Prob. 11PCh. 2.17 - Prob. 12PCh. 2.18 - Prob. 13PCh. 2.20 - Prob. 14PCh. 2.21 - Match the boiling points with the appropriate...Ch. 2.22 - Write a balanced chemical equation for the...Ch. 2.22 - Using the data in Table 2.3, estimate the heat of...Ch. 2.22 - Prob. 18PCh. 2.22 - Prob. 19PCh. 2.23 - Prob. 20PCh. 2.23 - Which of the following reactions requires an...Ch. 2 - The general molecular formula for alkanes is...Ch. 2 - Prob. 23PCh. 2 - Prob. 24PCh. 2 - Prob. 25PCh. 2 - What is the hybridization of each carbon in...Ch. 2 - Prob. 27PCh. 2 - Does the overlap of two p orbitals in the fashion...Ch. 2 - Prob. 29PCh. 2 - Aphids secrete an alarm pheromone having the...Ch. 2 - All the parts of this problem refer to the alkane...Ch. 2 - Prob. 32PCh. 2 - Prob. 33PCh. 2 - Prob. 34PCh. 2 - From among the 18 constitutional isomers of C8H18,...Ch. 2 - Give the IUPAC name for each of the following...Ch. 2 - Using the method outlined in Section 2.16, give an...Ch. 2 - Prob. 38PCh. 2 - Write a balanced chemical equation for the...Ch. 2 - The heats of combustion of methane and butane are...Ch. 2 - In each of the following groups of compounds,...Ch. 2 - Given H for the reaction H2(g)+12O2(g)H2O(l)...Ch. 2 - Prob. 43PCh. 2 - Prob. 44PCh. 2 - Prob. 45PCh. 2 - Prob. 46PCh. 2 - Prob. 47PCh. 2 - Compound A undergoes the following reactions:...Ch. 2 - Prob. 49PCh. 2 - Some Biochemical Reactions of Alkanes Alkanes...Ch. 2 - Prob. 51DSPCh. 2 - Some Biochemical Reactions of Alkanes Alkanes...Ch. 2 - Prob. 53DSP
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- What are aromatic hydrocarbons? Benzene exhibits resonance. Explain. What are the bond angles in benzene? Give a detailed description of the bonding in benzene. The electrons in benzene are delocalized, while the electrons in simple alkenes and alkynes are localized. Explain the difference.arrow_forwardWhat is the difference in bonding and in general molecular formula between an alkene and a cycloalkane with the same number of carbon atoms?arrow_forwardAccording to Table 2.10, five constitutional isomers are possible for alkanes with six carbon atoms. Write structural and condensed formulas for these isomers.arrow_forward
- Distinguish between isomerism and resonance. Distinguish between structural and geometric isomerism. When writing the various structural isomers, the most difficult task is identifying which are different isomers and which are identical to a previously written structurethat is, which are compounds that differ only by the rotation of a carbon single bond. How do you distinguish between structural isomers and those that are identical? Alkenes and cycloalkanes are structural isomers of each other. Give an example of each using C4H8. Another common feature of alkenes and cycloalkanes is that both have restricted rotation about one or more bonds in the compound, so both can exhibit cis- trans isomerism. What is required for an alkene or cycloalkane to exhibit cis-trans isomerism? Explain the difference between cis and trans isomers. Alcohols and ethers are structural isomers of each other, as are aldehydes and ketones. Give an example of each to illustrate. Which functional group in Table 21-4 can be structural isomers of carboxylic acids? What is optical isomerism? What do you look for to determine whether an organic compound exhibits optical isomerism? 1-Bromo-1-chloroethane is optically active whereas 1-bromo-2-chloroethane is not optically active. Explain.arrow_forwardWhat is the systematic name for this alkane? (a) nonane (b) 2-ethyl-5-methylhexane (c) 2,5-dimethyl heptane (d) dimethyloctanearrow_forwardSummarize the nomenclature rules for alkanes, alkenes, alkynes, and aromatic compounds. Correct the following false statements regarding nomenclature of hydrocarbons. a. The root name for a hydrocarbon is based on the shortest continuous chain of carbon atoms. b. The suffix used to name all hydrocarbons is -ane. c. Substituent groups are numbered so as to give the largest numbers possible. d. No number is required to indicate the positions of double or triple bonds in alkenes and alkynes. e. Substituent groups get the lowest number possible in alkenes and alkynes. f. The ortho- term in aromatic hydrocarbons indicates the presence of two substituent groups bonded to carbon- 1 and carbon-3 in benzene.arrow_forward
- Is it possible for a motor fuel to have a negative octane rating? Explain.arrow_forwardKindly answer everything that is written on the photo. If you can't please let other people do it.arrow_forwardGive the structural formula (condensed or skeletal) of the given IUPAC names of saturated hydrocarbons. 1) 2-methyl-3-oxohept-4-enoic acid 2) 4-chloro-2-oxohexanoyl chloride 3) 4-nitro-4-propoxybut-1-ene 4) 1-hydroxyhex-5-yn-2-one 5) 1-methylpropyl 3-amino-3-(1-methylpropoxy)propanoate 6) 1-ethoxy-3-mercaptohexane-2-thionearrow_forward
- 5. Classify as saturated or unsaturated hydrocarbon, give the IUPAC name, and identify the organic family for each of the following substances. Organic family Saturated or unsaturated Formula Name CH3 Saturated CH-C-CHz-CH3 Alkane 2,2- dimethyl butane CH3 CH3 Unsaturated 3. CH3-CH-C = CH-CH3 Alkene 3,4- dimethyl I, pent- 2- ene CH3 C:Hs Unsaturated CH-CH-CH-C CH Alkyne 3,4- dimethyl - pent- 1- yoe CH3 Saturated Cyclic hydro carbong Çyclo propanearrow_forwardDraw expanded, condensed and line structural formulas. and list the properties of only ONE of the following compounds. Using a camera/cell phone or software/ App ('Explain Everything"), describe how you determine the structural formulas and the properties of your molecule. 1, 1,3,4-tetrachloro-2,3-dimethylbutan-2-olarrow_forwardEncircle and label the different functional groups aside from alkane present in the following organic structures found in common medicines.arrow_forward
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Chapter 4 Alkanes and Cycloalkanes Lesson 2; Author: Linda Hanson;https://www.youtube.com/watch?v=AL_CM_Btef4;License: Standard YouTube License, CC-BY
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