a) C 6 H 12 O 2 , 1735 cm -1 Interpretation: To draw the structures of the given compounds. Concept introduction: As ester is usually recognized if that are two strong bands using to C=O stereochemistry and C-O stereochemistry is an intra-red spectrum.

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Answer 1

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Chapter 21.10, Problem 26P

Interpretation Introduction

a) C₆H₁₂O₂, 1735 cm^-1

Interpretation:

To draw the structures of the given compounds.

Concept introduction:

As ester is usually recognized if that are two strong bands using to C=O stereochemistry and C-O stereochemistry is an intra-red spectrum.

Interpretation Introduction

b) C₄H₉NO, 1650 cm^-1

Interpretation:

To draw the structures of the given compounds.

Concept introduction:

As ester is usually recognized if that are two strong bands using to C=O stereochemistry and C-O stereochemistry is an intra-red spectrum.

Interpretation Introduction

c) C₄H₅ClO, 1780 cm^-1

Interpretation:

To draw the structures of the given compounds.

Concept introduction:

This conjunctive effect dominates over the carbon- chloride (-ce) electron withdraw â€“g effect and the net result is a decrease in the have number of the carbonyl absorption.

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(c) The following data have been obtained for the hydrolysis of sucrose, C12H22O11, to glucose, C6H12O6, and fructose C6H12O6, in acidic solution: C12H22O11 + H2O → C6H12O6 + C6H12O6 [sucrose]/mol dm³ t/min 0 0.316 14 0.300 39 0.274 60 0.256 80 0.238 110 0.211 (i) Graphically prove the order of the reaction and determine the rate constant of the reaction. (ii) Determine the half-life, t½ for the hydrolysis of sucrose.

(III) adsorbent (b) Adsorption of the hexacyanoferrate (III) ion, [Fe(CN)6] ³, on y-Al2O3 from aqueous solution was examined. The adsorption was modelled using a modified Langmuir isotherm, yielding the following values of Kat pH = 6.5: (ii) T/K 10-10 K 280 2.505 295 1.819 310 1.364 325 1.050 Determine the enthalpy of adsorption, AadsHⓇ. If the reported value of entropy of adsorption, Aads Se = 146 J K-1 mol-1 under the above conditions, determine Aads Gº.

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Answer 2

Question

Chapter 21.10, Problem 26P

Interpretation Introduction

a) C₆H₁₂O₂, 1735 cm^-1

Interpretation:

To draw the structures of the given compounds.

Concept introduction:

As ester is usually recognized if that are two strong bands using to C=O stereochemistry and C-O stereochemistry is an intra-red spectrum.

Interpretation Introduction

b) C₄H₉NO, 1650 cm^-1

Interpretation:

To draw the structures of the given compounds.

Concept introduction:

As ester is usually recognized if that are two strong bands using to C=O stereochemistry and C-O stereochemistry is an intra-red spectrum.

Interpretation Introduction

c) C₄H₅ClO, 1780 cm^-1

Interpretation:

To draw the structures of the given compounds.

Concept introduction:

This conjunctive effect dominates over the carbon- chloride (-ce) electron withdraw â€“g effect and the net result is a decrease in the have number of the carbonyl absorption.

Expert Solution & Answer

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Check out a sample textbook solution

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Answer 3

Question

Chapter 21.10, Problem 26P

Interpretation Introduction

a) C₆H₁₂O₂, 1735 cm^-1

Interpretation:

To draw the structures of the given compounds.

Concept introduction:

As ester is usually recognized if that are two strong bands using to C=O stereochemistry and C-O stereochemistry is an intra-red spectrum.

Interpretation Introduction

b) C₄H₉NO, 1650 cm^-1

Interpretation:

To draw the structures of the given compounds.

Concept introduction:

As ester is usually recognized if that are two strong bands using to C=O stereochemistry and C-O stereochemistry is an intra-red spectrum.

Interpretation Introduction

c) C₄H₅ClO, 1780 cm^-1

Interpretation:

To draw the structures of the given compounds.

Concept introduction:

This conjunctive effect dominates over the carbon- chloride (-ce) electron withdraw â€“g effect and the net result is a decrease in the have number of the carbonyl absorption.

Expert Solution & Answer

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Answer 4

Question

Chapter 21.10, Problem 26P

Interpretation Introduction

a) C₆H₁₂O₂, 1735 cm^-1

Interpretation:

To draw the structures of the given compounds.

Concept introduction:

As ester is usually recognized if that are two strong bands using to C=O stereochemistry and C-O stereochemistry is an intra-red spectrum.

Interpretation Introduction

b) C₄H₉NO, 1650 cm^-1

Interpretation:

To draw the structures of the given compounds.

Concept introduction:

As ester is usually recognized if that are two strong bands using to C=O stereochemistry and C-O stereochemistry is an intra-red spectrum.

Interpretation Introduction

c) C₄H₅ClO, 1780 cm^-1

Interpretation:

To draw the structures of the given compounds.

Concept introduction:

This conjunctive effect dominates over the carbon- chloride (-ce) electron withdraw â€“g effect and the net result is a decrease in the have number of the carbonyl absorption.

Expert Solution & Answer

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Check out a sample textbook solution

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Answer 5

Chapter 21.10, Problem 26P

Interpretation Introduction

a) C₆H₁₂O₂, 1735 cm^-1

Interpretation:

To draw the structures of the given compounds.

Concept introduction:

As ester is usually recognized if that are two strong bands using to C=O stereochemistry and C-O stereochemistry is an intra-red spectrum.

Interpretation Introduction

b) C₄H₉NO, 1650 cm^-1

Interpretation:

To draw the structures of the given compounds.

Concept introduction:

As ester is usually recognized if that are two strong bands using to C=O stereochemistry and C-O stereochemistry is an intra-red spectrum.

Interpretation Introduction

c) C₄H₅ClO, 1780 cm^-1

Interpretation:

To draw the structures of the given compounds.

Concept introduction:

This conjunctive effect dominates over the carbon- chloride (-ce) electron withdraw â€“g effect and the net result is a decrease in the have number of the carbonyl absorption.

Answer 6

Chapter 21.10, Problem 26P

Interpretation Introduction

a) C₆H₁₂O₂, 1735 cm^-1

Interpretation:

To draw the structures of the given compounds.

Concept introduction:

As ester is usually recognized if that are two strong bands using to C=O stereochemistry and C-O stereochemistry is an intra-red spectrum.

Answer 7

Chapter 21.10, Problem 26P

Interpretation Introduction

a) C₆H₁₂O₂, 1735 cm^-1

Interpretation:

To draw the structures of the given compounds.

Concept introduction:

As ester is usually recognized if that are two strong bands using to C=O stereochemistry and C-O stereochemistry is an intra-red spectrum.

Answer 8

Interpretation Introduction

b) C₄H₉NO, 1650 cm^-1

Interpretation:

To draw the structures of the given compounds.

Concept introduction:

As ester is usually recognized if that are two strong bands using to C=O stereochemistry and C-O stereochemistry is an intra-red spectrum.

Answer 9

Interpretation Introduction

b) C₄H₉NO, 1650 cm^-1

Interpretation:

To draw the structures of the given compounds.

Concept introduction:

As ester is usually recognized if that are two strong bands using to C=O stereochemistry and C-O stereochemistry is an intra-red spectrum.

Answer 10

Interpretation Introduction

c) C₄H₅ClO, 1780 cm^-1

Interpretation:

To draw the structures of the given compounds.

Concept introduction:

This conjunctive effect dominates over the carbon- chloride (-ce) electron withdraw â€“g effect and the net result is a decrease in the have number of the carbonyl absorption.

Answer 11

Interpretation Introduction

c) C₄H₅ClO, 1780 cm^-1

Interpretation:

To draw the structures of the given compounds.

Concept introduction:

This conjunctive effect dominates over the carbon- chloride (-ce) electron withdraw â€“g effect and the net result is a decrease in the have number of the carbonyl absorption.

Answer 12

Expert Solution & Answer

Answer 13

Expert Solution & Answer

Answer 14

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Answer 15

Ch. 21.1 - Give IUPAC names for the following substances:Ch. 21.1 - Draw structures corresponding to the following...Ch. 21.2 - Prob. 3P Ch. 21.2 - Rank the compounds in each of the following sets...Ch. 21.2 - Predict the products of the following nucleophilic...Ch. 21.2 - Prob. 6P Ch. 21.3 - Prob. 7P Ch. 21.3 - If the following molecule is treated with acid...Ch. 21.4 - How might you prepare the following esters using a...Ch. 21.4 - Prob. 10P

a) C 6 H 12 O 2 , 1735 cm -1 Interpretation: To draw the structures of the given compounds. Concept introduction: As ester is usually recognized if that are two strong bands using to C=O stereochemistry and C-O stereochemistry is an intra-red spectrum.