a) CH 3 CH 2 CONHCH 3 Interpretation: To prepare the given amides by using an acid chloride and an amine or ammonia. Concept introduction: Evidently, in deciding the starting materials (reagents) for the synthesis, we observe that there are two distinct parts of the amide viz the acyl part which should come from the respective acyl chloride viz propanoyl chloride; and the amine part , which should come from the oppropriate amine methylamine.

Question

You are trying to decide if there is a single reagent you can add that will make the following synthesis possible without any other major side products: xi 1. ☑ 2. H₂O хе i Draw the missing reagent X you think will make this synthesis work in the drawing area below. If there is no reagent that will make your desired product in good yield or without complications, just check the box under the drawing area and leave it blank. Click and drag to start drawing a structure. There is no reagent that will make this synthesis work without complications. : ☐ S ☐

Answer 1

Question

Chapter 21.4, Problem 12P

Interpretation Introduction

a) CH₃CH₂CONHCH₃

Interpretation:

To prepare the given amides by using an acid chloride and an amine or ammonia.

Concept introduction:

Evidently, in deciding the starting materials (reagents) for the synthesis, we observe that there are two distinct parts of the amide viz the acyl part which should come from the respective acyl chloride viz propanoyl chloride; and the amine part , which should come from the oppropriate amine methylamine.

Interpretation Introduction

b) N,N-Diethylbenzamide

Interpretation:

To prepare the given amides by using an acid chloride and an amine or ammonia.

Concept introduction:

Evidently, introspection of the target molecule viz the amide, shows that it has two distinct parts, viz the acyl part, Phco should come from the acid chloride, viz benzoyl chloride, and the amine part should come from the appropriate amine, in this case it is N,N-diethyl amine.

Interpretation Introduction

c) Propanamide

Interpretation:

To prepare the given amides by using an acid chloride and an amine or ammonia.

Concept introduction:

Introspection of the target amide shows that there are two distinct parts viz, the acyl part and the amine part the acyl part should come from the appropriate acid chloride in this case, it is propanoyl chloride while the amine part should be provided from ammonia.

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You are trying to decide if there is a single reagent you can add that will make the following synthesis possible without any other major side products: xi 1. ☑ 2. H₂O хе i Draw the missing reagent X you think will make this synthesis work in the drawing area below. If there is no reagent that will make your desired product in good yield or without complications, just check the box under the drawing area and leave it blank. Click and drag to start drawing a structure. There is no reagent that will make this synthesis work without complications. : ☐ S ☐

Predict the major products of this organic reaction: H OH 1. LiAlH4 2. H₂O ? Note: be sure you use dash and wedge bonds when necessary, for example to distinguish between major products with different stereochemistry. Click and drag to start drawing a structure. G C टे

For each reaction below, decide if the first stable organic product that forms in solution will create a new C-C bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. NH2 CI MgCl ? Will the first product that forms in this reaction create a new CC bond? Yes No MgBr ? Will the first product that forms in this reaction create a new CC bond? Yes No G टे

Answer 2

Question

Chapter 21.4, Problem 12P

Interpretation Introduction

a) CH₃CH₂CONHCH₃

Interpretation:

To prepare the given amides by using an acid chloride and an amine or ammonia.

Concept introduction:

Evidently, in deciding the starting materials (reagents) for the synthesis, we observe that there are two distinct parts of the amide viz the acyl part which should come from the respective acyl chloride viz propanoyl chloride; and the amine part , which should come from the oppropriate amine methylamine.

Interpretation Introduction

b) N,N-Diethylbenzamide

Interpretation:

To prepare the given amides by using an acid chloride and an amine or ammonia.

Concept introduction:

Evidently, introspection of the target molecule viz the amide, shows that it has two distinct parts, viz the acyl part, Phco should come from the acid chloride, viz benzoyl chloride, and the amine part should come from the appropriate amine, in this case it is N,N-diethyl amine.

Interpretation Introduction

c) Propanamide

Interpretation:

To prepare the given amides by using an acid chloride and an amine or ammonia.

Concept introduction:

Introspection of the target amide shows that there are two distinct parts viz, the acyl part and the amine part the acyl part should come from the appropriate acid chloride in this case, it is propanoyl chloride while the amine part should be provided from ammonia.

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Answer 3

Question

Chapter 21.4, Problem 12P

Interpretation Introduction

a) CH₃CH₂CONHCH₃

Interpretation:

To prepare the given amides by using an acid chloride and an amine or ammonia.

Concept introduction:

Evidently, in deciding the starting materials (reagents) for the synthesis, we observe that there are two distinct parts of the amide viz the acyl part which should come from the respective acyl chloride viz propanoyl chloride; and the amine part , which should come from the oppropriate amine methylamine.

Interpretation Introduction

b) N,N-Diethylbenzamide

Interpretation:

To prepare the given amides by using an acid chloride and an amine or ammonia.

Concept introduction:

Evidently, introspection of the target molecule viz the amide, shows that it has two distinct parts, viz the acyl part, Phco should come from the acid chloride, viz benzoyl chloride, and the amine part should come from the appropriate amine, in this case it is N,N-diethyl amine.

Interpretation Introduction

c) Propanamide

Interpretation:

To prepare the given amides by using an acid chloride and an amine or ammonia.

Concept introduction:

Introspection of the target amide shows that there are two distinct parts viz, the acyl part and the amine part the acyl part should come from the appropriate acid chloride in this case, it is propanoyl chloride while the amine part should be provided from ammonia.

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Answer 4

Question

Chapter 21.4, Problem 12P

Interpretation Introduction

a) CH₃CH₂CONHCH₃

Interpretation:

To prepare the given amides by using an acid chloride and an amine or ammonia.

Concept introduction:

Evidently, in deciding the starting materials (reagents) for the synthesis, we observe that there are two distinct parts of the amide viz the acyl part which should come from the respective acyl chloride viz propanoyl chloride; and the amine part , which should come from the oppropriate amine methylamine.

Interpretation Introduction

b) N,N-Diethylbenzamide

Interpretation:

To prepare the given amides by using an acid chloride and an amine or ammonia.

Concept introduction:

Evidently, introspection of the target molecule viz the amide, shows that it has two distinct parts, viz the acyl part, Phco should come from the acid chloride, viz benzoyl chloride, and the amine part should come from the appropriate amine, in this case it is N,N-diethyl amine.

Interpretation Introduction

c) Propanamide

Interpretation:

To prepare the given amides by using an acid chloride and an amine or ammonia.

Concept introduction:

Introspection of the target amide shows that there are two distinct parts viz, the acyl part and the amine part the acyl part should come from the appropriate acid chloride in this case, it is propanoyl chloride while the amine part should be provided from ammonia.

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Answer 5

Chapter 21.4, Problem 12P

Interpretation Introduction

a) CH₃CH₂CONHCH₃

Interpretation:

To prepare the given amides by using an acid chloride and an amine or ammonia.

Concept introduction:

Evidently, in deciding the starting materials (reagents) for the synthesis, we observe that there are two distinct parts of the amide viz the acyl part which should come from the respective acyl chloride viz propanoyl chloride; and the amine part , which should come from the oppropriate amine methylamine.

Interpretation Introduction

b) N,N-Diethylbenzamide

Interpretation:

To prepare the given amides by using an acid chloride and an amine or ammonia.

Concept introduction:

Evidently, introspection of the target molecule viz the amide, shows that it has two distinct parts, viz the acyl part, Phco should come from the acid chloride, viz benzoyl chloride, and the amine part should come from the appropriate amine, in this case it is N,N-diethyl amine.

Interpretation Introduction

c) Propanamide

Interpretation:

To prepare the given amides by using an acid chloride and an amine or ammonia.

Concept introduction:

Introspection of the target amide shows that there are two distinct parts viz, the acyl part and the amine part the acyl part should come from the appropriate acid chloride in this case, it is propanoyl chloride while the amine part should be provided from ammonia.

Answer 6

Chapter 21.4, Problem 12P

Interpretation Introduction

a) CH₃CH₂CONHCH₃

Interpretation:

To prepare the given amides by using an acid chloride and an amine or ammonia.

Concept introduction:

Evidently, in deciding the starting materials (reagents) for the synthesis, we observe that there are two distinct parts of the amide viz the acyl part which should come from the respective acyl chloride viz propanoyl chloride; and the amine part , which should come from the oppropriate amine methylamine.

Answer 7

Chapter 21.4, Problem 12P

Interpretation Introduction

a) CH₃CH₂CONHCH₃

Interpretation:

To prepare the given amides by using an acid chloride and an amine or ammonia.

Concept introduction:

Evidently, in deciding the starting materials (reagents) for the synthesis, we observe that there are two distinct parts of the amide viz the acyl part which should come from the respective acyl chloride viz propanoyl chloride; and the amine part , which should come from the oppropriate amine methylamine.

Answer 8

Interpretation Introduction

b) N,N-Diethylbenzamide

Interpretation:

To prepare the given amides by using an acid chloride and an amine or ammonia.

Concept introduction:

Evidently, introspection of the target molecule viz the amide, shows that it has two distinct parts, viz the acyl part, Phco should come from the acid chloride, viz benzoyl chloride, and the amine part should come from the appropriate amine, in this case it is N,N-diethyl amine.

Answer 9

Interpretation Introduction

b) N,N-Diethylbenzamide

Interpretation:

To prepare the given amides by using an acid chloride and an amine or ammonia.

Concept introduction:

Evidently, introspection of the target molecule viz the amide, shows that it has two distinct parts, viz the acyl part, Phco should come from the acid chloride, viz benzoyl chloride, and the amine part should come from the appropriate amine, in this case it is N,N-diethyl amine.

Answer 10

Interpretation Introduction

c) Propanamide

Interpretation:

To prepare the given amides by using an acid chloride and an amine or ammonia.

Concept introduction:

Introspection of the target amide shows that there are two distinct parts viz, the acyl part and the amine part the acyl part should come from the appropriate acid chloride in this case, it is propanoyl chloride while the amine part should be provided from ammonia.

Answer 11

Interpretation Introduction

c) Propanamide

Interpretation:

To prepare the given amides by using an acid chloride and an amine or ammonia.

Concept introduction:

Introspection of the target amide shows that there are two distinct parts viz, the acyl part and the amine part the acyl part should come from the appropriate acid chloride in this case, it is propanoyl chloride while the amine part should be provided from ammonia.

Answer 12

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Answer 23

Ch. 21.1 - Give IUPAC names for the following substances:Ch. 21.1 - Draw structures corresponding to the following...Ch. 21.2 - Prob. 3P Ch. 21.2 - Rank the compounds in each of the following sets...Ch. 21.2 - Predict the products of the following nucleophilic...Ch. 21.2 - Prob. 6P Ch. 21.3 - Prob. 7P Ch. 21.3 - If the following molecule is treated with acid...Ch. 21.4 - How might you prepare the following esters using a...Ch. 21.4 - Prob. 10P

Solution Summary: The author explains the mechanism of the nucleophilic acyl substitution reaction.

Chapter 21 Solutions