The use of Friedel-Crafts acylation to synthesize the given compound is to be shown. Concept introduction: Friedel Crafts acylation is the electrophilic aromatic substitution reaction that allows the reaction between arenes and acyl chlorides. It is a very effective way of attaching hydrocarbon-based groups on to a benzene ring and the product formed is a ketone .

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Answer 1

Question

Chapter 21.10, Problem 21.30P

(a)

Interpretation Introduction

Interpretation:

The use of Friedel-Crafts acylation to synthesize the given compound is to be shown.

Concept introduction:

Friedel Crafts acylation is the electrophilic aromatic substitution reaction that allows the reaction between arenes and acyl chlorides. It is a very effective way of attaching hydrocarbon-based groups on to a benzene ring and the product formed is a ketone.

(b)

Interpretation Introduction

Interpretation:

The use of Friedel-Crafts acylation to synthesize the given compound is to be shown.

Concept introduction:

Friedel Crafts acylation is the electrophilic aromatic substitution reaction that allows the reaction between arenes and acyl chlorides. It is a very effective way of attaching hydrocarbon-based groups on to a benzene ring and the product formed is a ketone.

(c)

Interpretation Introduction

Interpretation:

The use of Friedel-Crafts acylation to synthesize the given compound is to be shown.

Concept introduction:

Friedel Crafts acylation is the electrophilic aromatic substitution reaction that allows the reaction between arenes and acyl chlorides. It is a very effective way of attaching hydrocarbon-based groups on to a benzene ring and the product formed is a ketone.

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1. Consider these three reactions as the elementary steps in the mechanism for a chemical reaction. 2600 2400 2200 2000 1800 1600 1400 1200 1000 800 Potential Energy (kJ) 600 400 200 0 -200- -400 -600- -800 (i) Cl₂ (g) + Pt(s) → 2Cl (g) + Pt(s) (ii) Cl (g)+ CO (g) + Pt (s) → CICO (g) + Pt (s) Ea = 1550 kJ Ea = 2240 kJ (iii) Cl (g) + CICO (g) → Cl₂CO (g) Ea = 2350 kJ AH=-950 kJ ΔΗ = 575 ΚΙ AH=-825 kJ a. Draw the potential energy diagram for the reaction. Label the data points for clarity. The potential energy of the reactants is 600 kJ Reaction Progress b. What is the overall chemical equation? c. What is the overall change in enthalpy for the above chemical reaction? d. What is the overall amount of activation energy for the above chemical reaction? e. Which reaction intermediate would be considered a catalyst (if any) and why? f. If you were to add 2700kJ of energy to the reaction (e.g. 2700 kl of heat or electricity), would you be able to make the reaction reverse itself (i.e. have…

Answer 2

Question

Chapter 21.10, Problem 21.30P

(a)

Interpretation Introduction

Interpretation:

The use of Friedel-Crafts acylation to synthesize the given compound is to be shown.

Concept introduction:

Friedel Crafts acylation is the electrophilic aromatic substitution reaction that allows the reaction between arenes and acyl chlorides. It is a very effective way of attaching hydrocarbon-based groups on to a benzene ring and the product formed is a ketone.

(b)

Interpretation Introduction

Interpretation:

The use of Friedel-Crafts acylation to synthesize the given compound is to be shown.

Concept introduction:

Friedel Crafts acylation is the electrophilic aromatic substitution reaction that allows the reaction between arenes and acyl chlorides. It is a very effective way of attaching hydrocarbon-based groups on to a benzene ring and the product formed is a ketone.

(c)

Interpretation Introduction

Interpretation:

The use of Friedel-Crafts acylation to synthesize the given compound is to be shown.

Concept introduction:

Friedel Crafts acylation is the electrophilic aromatic substitution reaction that allows the reaction between arenes and acyl chlorides. It is a very effective way of attaching hydrocarbon-based groups on to a benzene ring and the product formed is a ketone.

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Answer 3

Question

Chapter 21.10, Problem 21.30P

(a)

Interpretation Introduction

Interpretation:

The use of Friedel-Crafts acylation to synthesize the given compound is to be shown.

Concept introduction:

Friedel Crafts acylation is the electrophilic aromatic substitution reaction that allows the reaction between arenes and acyl chlorides. It is a very effective way of attaching hydrocarbon-based groups on to a benzene ring and the product formed is a ketone.

(b)

Interpretation Introduction

Interpretation:

The use of Friedel-Crafts acylation to synthesize the given compound is to be shown.

Concept introduction:

Friedel Crafts acylation is the electrophilic aromatic substitution reaction that allows the reaction between arenes and acyl chlorides. It is a very effective way of attaching hydrocarbon-based groups on to a benzene ring and the product formed is a ketone.

(c)

Interpretation Introduction

Interpretation:

The use of Friedel-Crafts acylation to synthesize the given compound is to be shown.

Concept introduction:

Friedel Crafts acylation is the electrophilic aromatic substitution reaction that allows the reaction between arenes and acyl chlorides. It is a very effective way of attaching hydrocarbon-based groups on to a benzene ring and the product formed is a ketone.

Expert Solution & Answer

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Answer 4

Question

Chapter 21.10, Problem 21.30P

(a)

Interpretation Introduction

Interpretation:

The use of Friedel-Crafts acylation to synthesize the given compound is to be shown.

Concept introduction:

Friedel Crafts acylation is the electrophilic aromatic substitution reaction that allows the reaction between arenes and acyl chlorides. It is a very effective way of attaching hydrocarbon-based groups on to a benzene ring and the product formed is a ketone.

(b)

Interpretation Introduction

Interpretation:

The use of Friedel-Crafts acylation to synthesize the given compound is to be shown.

Concept introduction:

Friedel Crafts acylation is the electrophilic aromatic substitution reaction that allows the reaction between arenes and acyl chlorides. It is a very effective way of attaching hydrocarbon-based groups on to a benzene ring and the product formed is a ketone.

(c)

Interpretation Introduction

Interpretation:

The use of Friedel-Crafts acylation to synthesize the given compound is to be shown.

Concept introduction:

Friedel Crafts acylation is the electrophilic aromatic substitution reaction that allows the reaction between arenes and acyl chlorides. It is a very effective way of attaching hydrocarbon-based groups on to a benzene ring and the product formed is a ketone.

Expert Solution & Answer

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Answer 5

Chapter 21.10, Problem 21.30P

(a)

Interpretation Introduction

Interpretation:

The use of Friedel-Crafts acylation to synthesize the given compound is to be shown.

Concept introduction:

Friedel Crafts acylation is the electrophilic aromatic substitution reaction that allows the reaction between arenes and acyl chlorides. It is a very effective way of attaching hydrocarbon-based groups on to a benzene ring and the product formed is a ketone.

(b)

Interpretation Introduction

Interpretation:

The use of Friedel-Crafts acylation to synthesize the given compound is to be shown.

Concept introduction:

Friedel Crafts acylation is the electrophilic aromatic substitution reaction that allows the reaction between arenes and acyl chlorides. It is a very effective way of attaching hydrocarbon-based groups on to a benzene ring and the product formed is a ketone.

(c)

Interpretation Introduction

Interpretation:

The use of Friedel-Crafts acylation to synthesize the given compound is to be shown.

Concept introduction:

Friedel Crafts acylation is the electrophilic aromatic substitution reaction that allows the reaction between arenes and acyl chlorides. It is a very effective way of attaching hydrocarbon-based groups on to a benzene ring and the product formed is a ketone.

Answer 6

Chapter 21.10, Problem 21.30P

(a)

Interpretation Introduction

Interpretation:

The use of Friedel-Crafts acylation to synthesize the given compound is to be shown.

Concept introduction:

Friedel Crafts acylation is the electrophilic aromatic substitution reaction that allows the reaction between arenes and acyl chlorides. It is a very effective way of attaching hydrocarbon-based groups on to a benzene ring and the product formed is a ketone.

Answer 7

Chapter 21.10, Problem 21.30P

(a)

Interpretation Introduction

Interpretation:

The use of Friedel-Crafts acylation to synthesize the given compound is to be shown.

Concept introduction:

Friedel Crafts acylation is the electrophilic aromatic substitution reaction that allows the reaction between arenes and acyl chlorides. It is a very effective way of attaching hydrocarbon-based groups on to a benzene ring and the product formed is a ketone.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The use of Friedel-Crafts acylation to synthesize the given compound is to be shown.

Concept introduction:

Friedel Crafts acylation is the electrophilic aromatic substitution reaction that allows the reaction between arenes and acyl chlorides. It is a very effective way of attaching hydrocarbon-based groups on to a benzene ring and the product formed is a ketone.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The use of Friedel-Crafts acylation to synthesize the given compound is to be shown.

Concept introduction:

Friedel Crafts acylation is the electrophilic aromatic substitution reaction that allows the reaction between arenes and acyl chlorides. It is a very effective way of attaching hydrocarbon-based groups on to a benzene ring and the product formed is a ketone.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The use of Friedel-Crafts acylation to synthesize the given compound is to be shown.

Concept introduction:

Friedel Crafts acylation is the electrophilic aromatic substitution reaction that allows the reaction between arenes and acyl chlorides. It is a very effective way of attaching hydrocarbon-based groups on to a benzene ring and the product formed is a ketone.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The use of Friedel-Crafts acylation to synthesize the given compound is to be shown.

Concept introduction:

Friedel Crafts acylation is the electrophilic aromatic substitution reaction that allows the reaction between arenes and acyl chlorides. It is a very effective way of attaching hydrocarbon-based groups on to a benzene ring and the product formed is a ketone.

Answer 12

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Answer 14

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Answer 15

Ch. 21.2F - Name the following carboxylic acid derivatives,...Ch. 21.4A - Prob. 21.2P Ch. 21.4A - Prob. 21.3P Ch. 21.4A - Prob. 21.4P Ch. 21.5C - Prob. 21.7P Ch. 21.6 - When ethyl 4-hydroxybutyrate is heated in the...Ch. 21.6 - Propose a mechanism for the following ring-opening...Ch. 21.6 - Prob. 21.15P Ch. 21.7B - Prob. 21.16P Ch. 21.7C - Prob. 21.19P

Solution Summary: The author describes Friedel-Crafts acylation as the electrophilic aromatic substitution reaction that allows the reaction between arenes and acetyl chlorides.

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Chapter 21 Solutions