9th Edition

ISBN: 9780534261641

Author: SIMEK

Publisher: Cengage Learning

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Textbook Question

Chapter 2.10, Problem 2.13P

Write equations for the following acid-base reactions Label the conjugate acids and bases and show any inductive stabilization Predict whether the equilibrium favors the reactants or products Try to do this without using a table of pK_a values, but if you need a hint, you can consult Appendix 4.

a. CH₃CH₂OH + CH₃NH⁻
b. F₃CCOONa + Br₃C—COOH
c. CH₃OH + H₂SO₄
d. NaOH + H₂S
e. CH₃NH₃⁺ + CH₃O⁺
f. BrCH₂CH₂OH + F₃C—CH₂O
g. NaOCH₂CH₃ + CI₂CHCH₂OH
h. H₂Se + NaNH₂
i. CH₃CHFCOOH + FCH₂CH₂COO⁻
j. CF₃CH₂O⁻ + FCH₂CH₂OH

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Chapter 2.8, Problem 2.12P

Chapter 2.10, Problem 2.14P

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Classify each of the following molecules as aromatic, antiaromatic, or nonaromatic. ZI NH Explanation Check O aromatic O antiaromatic O nonaromatic O aromatic O antiaromatic H O nonaromatic O aromatic O antiaromatic O nonaromatic ×

Part I. Draw the stepwise reaction mechanism of each product (a, b, c, d, e, f) HO HO OH НОН,С HO OH Sucrose HO CH₂OH H N N HO -H H -OH KMnO4, Heat H OH CH₂OH (d) Phenyl Osatriazole OH НОН,С HO HO + Glacial HOAC HO- HO CH₂OH OH HO Fructose (a) Glucose OH (b) H₂N HN‍ (c) CuSO4-5H2O, ethanol H N N N HO ·H H OH H OH N CH₂OH OH (f) Phenyl Osazone H (e) Carboxy phenyl osatriazole Figure 2.1. Reaction Scheme for the Total Synthesis of Fine Chemicals

Chapter 2 Solutions

ORGANIC CHEMISTRY II LAB MANUAL>CUSTOM<

Ch. 2.1A - Prob. 2.1P Ch. 2.1B - The NF bond is more polar than the NH bond: but...Ch. 2.1B - For each of the following compounds 1. Draw the...Ch. 2.1B - Two isomers of 1,2-dichloroethene are known One...Ch. 2.2C - Prob. 2.5P Ch. 2.2C - Prob. 2.6P Ch. 2.3 - Prob. 2.7P Ch. 2.4 - Calculate the pH of the following solutions a....Ch. 2.6A - Ammonia appears in Table 2-2 as both an acid and a...Ch. 2.7 - Write equations for the following acid-base...

Ch. 2.7 - Ethanol, methylamine. and acetic acid are all...Ch. 2.8 - Prob. 2.12P Ch. 2.10 - Write equations for the following acid-base...Ch. 2.10 - Rank the following acids in decreasing order of...Ch. 2.11 - Prob. 2.15P Ch. 2.11 - Prob. 2.16P Ch. 2.11 - Consider each pair of bases and explain which one...Ch. 2.12 - Which is a stronger base ethoxide ion or acetate...Ch. 2.12 - Prob. 2.19P Ch. 2.12 - Prob. 2.20P Ch. 2.12 - Prob. 2.21P Ch. 2.12 - Choose the more basic member of each pair of...Ch. 2.14 - Prob. 2.23P Ch. 2.15D - Classify the following hydrocarbons and draw a...Ch. 2.16D - Prob. 2.25P Ch. 2.17C - Draw a Lewis structure and classify each of the...Ch. 2.17C - Circle the functional groups in the following...Ch. 2 - The CN triple bond in acetonitrile has a dipole...Ch. 2 - Prob. 2.29SP Ch. 2 - Sulfur dioxide has a dipole moment of 1.60 D....Ch. 2 - Which of the following pure compounds can form...Ch. 2 - Predict which member of each pair is more soluble...Ch. 2 - Prob. 2.33SP Ch. 2 - Prob. 2.34SP Ch. 2 - Predict which compound in each pair has the higher...Ch. 2 - All of the following compounds can react as acids...Ch. 2 - Rank the following species in order of increasing...Ch. 2 - Rank the following species in order of increasing...Ch. 2 - The Ka of phenylacetic acid is 5 2 105, and the...Ch. 2 - The following compound can become protonated on...Ch. 2 - The following compounds are listed in increasing...Ch. 2 - Prob. 2.42SP Ch. 2 - Prob. 2.43SP Ch. 2 - Compare the relative acidity of 1-molar aqueous...Ch. 2 - The following compounds can all react as acids. a....Ch. 2 - The following compounds can all react as bases. a....Ch. 2 - The following compounds can all react as acids. a....Ch. 2 - Prob. 2.48SP Ch. 2 - Methyllithium (CH3Li) is often used as a base in...Ch. 2 - Label the reactants in these acid-base reactions...Ch. 2 - In each reaction, label the reactants as Lewis...Ch. 2 - Prob. 2.52SP Ch. 2 - Each of these compounds can react as a nucleophile...Ch. 2 - Prob. 2.54SP Ch. 2 - Give a definition and an example for each class of...Ch. 2 - Circle the functional groups in the following...Ch. 2 - Prob. 2.57SP

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