Chemistry by OpenStax (2015-05-04)
1st Edition
ISBN: 9781938168390
Author: Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher: OpenStax
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Textbook Question
Chapter 21, Problem 62E
Given specimens neon-24
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Draw the structure of the product of this reaction.
H CH2CH3
Br
H-...
H
H3C
KOH
E2 elimination product
• Use the wedge/hash bond tools to indicate stereochemistry where it exists.
•
If there are alternative structures, draw the most stable one.
• If no reaction occurs, draw the organic starting material.
O
+
98
//
n
?
4.
a) Give a suitable rationale for the following cyclization, stating the type of process involved
(e.g. 9-endo-dig), clearly showing the mechanistic details at each step.
H
CO₂Me
1) NaOMe
2) H3O®
CO₂Me
2. Platinum and other group 10 metals often act as solid phase hydrogenation catalysts for
unsaturated hydrocarbons such as propylene, CH3CHCH2. In order for the reaction to be
catalyzed the propylene molecules must first adsorb onto the surface. In order to completely
cover the surface of a piece of platinum that has an area of 1.50 cm² with propylene, a total
of 3.45 x 10¹7 molecules are needed. Determine the mass of the propylene molecules that
have been absorbed onto the platinum surface.
Chapter 21 Solutions
Chemistry by OpenStax (2015-05-04)
Ch. 21 - Write the following isotopes in hyphenated form...Ch. 21 - Write the following isotopes in nuclide notation...Ch. 21 - For the following isotopes that have missing...Ch. 21 - For each of the isotopes in Exercise 21.1,...Ch. 21 - Write the nuclide notation, including charge if...Ch. 21 - Calculate the density of the M1224g nucleus in...Ch. 21 - What are the two principal differences between...Ch. 21 - The mass of the atom N1123a is 22.9893 arm.. (a)...Ch. 21 - Which of the following nuclei lie within the band...Ch. 21 - Which of the following nuclei lie within the band...
Ch. 21 - Write a brief description or definition of each of...Ch. 21 - Which of the various particles ( particles, ...Ch. 21 - Complete each of the following equations by adding...Ch. 21 - Complete each 0f the following equations: (a)...Ch. 21 - Write a balanced equation for each of the...Ch. 21 - Technetium-99 is prepared from 98Mo. Molybdenum-SS...Ch. 21 - The mass of the atom F919 is 18.99840 amu.. (a)...Ch. 21 - For the reaction C614N714+?, if 100.0 g of carbon...Ch. 21 - What are the types of radiation emitted by the...Ch. 21 - That changes occur to the atomic number and mass...Ch. 21 - What is the change in the nucleus that results...Ch. 21 - Many nuclides with atomic numbers greater than 83...Ch. 21 - Why is electron capture accompanied by the...Ch. 21 - Explain, in terms of Figure 21.2, how unstable...Ch. 21 - Which of the following nuclei is most likely to...Ch. 21 - The following nuclei do not lie in the band of...Ch. 21 - The following nuclei do not lie in the band of...Ch. 21 - Predict by what mode(s) of spontaneous radioactive...Ch. 21 - Write a nuclear reaction for each step in the...Ch. 21 - Write a nuclear reaction for each step in the...Ch. 21 - Define the term half-life and illustrate it with...Ch. 21 - A 1.00106 -g sample of nobelium, N102254o, has a...Ch. 21 - 239Pu is a nuclear waste byproduct with a...Ch. 21 - The isotope 208Tl undergoes decay with a...Ch. 21 - If 1.000 g of R88226a produces 0.0001 mL of the...Ch. 21 - The isotope S3890r one of the extremely hazardous...Ch. 21 - Technetium-99 is often used for assessing heart,...Ch. 21 - What is the age of mummified primate skin that...Ch. 21 - A sample of rock was found to contain 8.23 mg of...Ch. 21 - A laboratory investigation shows that a sample of...Ch. 21 - Plutonium was detected in trace amounts in natural...Ch. 21 - A B47e atom (mass = 7.0169 amu) decays into a L37i...Ch. 21 - A B58 atom (mass = 8.0246 amu) decays into B48...Ch. 21 - Isotopes such as 26Al (half-life: 7.2105 years)...Ch. 21 - Write a balanced equation for each of the...Ch. 21 - Write a balanced equation for each of the...Ch. 21 - Write the balanced nuclear equation for the...Ch. 21 - How does nuclear fission differ from nuclear...Ch. 21 - Both fusion and fission are nuclear reactions. Why...Ch. 21 - Cite the conditions necessary for a nuclear chain...Ch. 21 - Describe the components of a nuclear reactor.Ch. 21 - In usual practice, both a moderator and control...Ch. 21 - Describe how the potential energy of uranium is...Ch. 21 - The mass of a hydrogen atom (11H) is 1.007825 arm;...Ch. 21 - How can a radioactive nuclide be used to show that...Ch. 21 - Technetium-99m has a half-life of 6.01 hours. If a...Ch. 21 - Iodine that enters the body is stored in the...Ch. 21 - If a hospital were storing radioisotopes, what is...Ch. 21 - Based on what is known about Radon-222’s primary...Ch. 21 - Given specimens uranium-232 (t1/2=68.9y) and...Ch. 21 - A scientist is studying a 2.234 g sample of...Ch. 21 - Given specimens neon-24 (t1/2=3.38min) and...
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