Chemistry by OpenStax (2015-05-04)
1st Edition
ISBN: 9781938168390
Author: Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher: OpenStax
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Textbook Question
Chapter 21, Problem 20E
That changes occur to the
(a) an
(b) a
(c)
(d) a positron is emitted.
(e) an electron is captured
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Students have asked these similar questions
Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below.
Find the following:
(a) The no. of protons corresponding to each signal in the spectra
(6) Give the structure of the compound and assign the signals to each
proton in the compound.
a
70.2
Integration Values
C5H10O2
b
47.7
C
46.5
d
69.5
3.6 3.5
3.4 3.3 3.2 3.1 3.0
2.9 2.8
2.7
2.6 2.5
2.4 2.3 2.2 2.1 2.0
Chemical Shift (ppm)
1.9
1.8
1.7 1.6
1.5
1.4 1.3 1.2
1.1 1.0
0.9 0.8
Part 111. 1 H-NMR spectrum of a compound with integration values in red is given below.
Answer the following:
(a) write the signals in the 'H-NMR spectrum to the corresponding protons on the structure
of the molecule below.
(b) Identify the theoretical multiplicities for each proton in the compound. Also give the possible.
complex splitting patterns assuming J values are not similar.
там
Br
22
2
3
6
4 7.2 7.0 6.8 6.6 6.4 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 3.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0
Chemical Shift (ppm)
ra.
Br
2
3
6
6
2.5
2.4
2.3
2.2
2.1
2.0
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
0.9
0.8
Chemical Shift (ppm)
2
2
Br
7.3
7.2
7.1
7.0 6.9
6.7 6.6 6.5
6.4
6.3
6.2
6.1
6.0
Chemical Shift (ppm)
5.9
5.8 5.7
5.5 5.4 5.3 5.2
5.0 4.9
1600°
1538°C
1493°C
In the diagram, the letter L indicates
that it is a liquid. Indicate its
components in the upper region
where only L is indicated.
The
iron-iron carbide phase
diagram.
Temperature (°C)
1400
8
1394°C
y+L
1200
2.14
y, Austenite
10000
912°C
800a
0.76
0.022
600
400
(Fe)
a, Ferrite
Composition (at% C)
15
1147°C
a + Fe3C
2
3
Composition (wt% C)
L
2500
4.30
2000
y + Fe3C
727°C
1500
Cementite (Fe3C)
1000
4
5
6
6.70
Temperature (°F)
Chapter 21 Solutions
Chemistry by OpenStax (2015-05-04)
Ch. 21 - Write the following isotopes in hyphenated form...Ch. 21 - Write the following isotopes in nuclide notation...Ch. 21 - For the following isotopes that have missing...Ch. 21 - For each of the isotopes in Exercise 21.1,...Ch. 21 - Write the nuclide notation, including charge if...Ch. 21 - Calculate the density of the M1224g nucleus in...Ch. 21 - What are the two principal differences between...Ch. 21 - The mass of the atom N1123a is 22.9893 arm.. (a)...Ch. 21 - Which of the following nuclei lie within the band...Ch. 21 - Which of the following nuclei lie within the band...
Ch. 21 - Write a brief description or definition of each of...Ch. 21 - Which of the various particles ( particles, ...Ch. 21 - Complete each of the following equations by adding...Ch. 21 - Complete each 0f the following equations: (a)...Ch. 21 - Write a balanced equation for each of the...Ch. 21 - Technetium-99 is prepared from 98Mo. Molybdenum-SS...Ch. 21 - The mass of the atom F919 is 18.99840 amu.. (a)...Ch. 21 - For the reaction C614N714+?, if 100.0 g of carbon...Ch. 21 - What are the types of radiation emitted by the...Ch. 21 - That changes occur to the atomic number and mass...Ch. 21 - What is the change in the nucleus that results...Ch. 21 - Many nuclides with atomic numbers greater than 83...Ch. 21 - Why is electron capture accompanied by the...Ch. 21 - Explain, in terms of Figure 21.2, how unstable...Ch. 21 - Which of the following nuclei is most likely to...Ch. 21 - The following nuclei do not lie in the band of...Ch. 21 - The following nuclei do not lie in the band of...Ch. 21 - Predict by what mode(s) of spontaneous radioactive...Ch. 21 - Write a nuclear reaction for each step in the...Ch. 21 - Write a nuclear reaction for each step in the...Ch. 21 - Define the term half-life and illustrate it with...Ch. 21 - A 1.00106 -g sample of nobelium, N102254o, has a...Ch. 21 - 239Pu is a nuclear waste byproduct with a...Ch. 21 - The isotope 208Tl undergoes decay with a...Ch. 21 - If 1.000 g of R88226a produces 0.0001 mL of the...Ch. 21 - The isotope S3890r one of the extremely hazardous...Ch. 21 - Technetium-99 is often used for assessing heart,...Ch. 21 - What is the age of mummified primate skin that...Ch. 21 - A sample of rock was found to contain 8.23 mg of...Ch. 21 - A laboratory investigation shows that a sample of...Ch. 21 - Plutonium was detected in trace amounts in natural...Ch. 21 - A B47e atom (mass = 7.0169 amu) decays into a L37i...Ch. 21 - A B58 atom (mass = 8.0246 amu) decays into B48...Ch. 21 - Isotopes such as 26Al (half-life: 7.2105 years)...Ch. 21 - Write a balanced equation for each of the...Ch. 21 - Write a balanced equation for each of the...Ch. 21 - Write the balanced nuclear equation for the...Ch. 21 - How does nuclear fission differ from nuclear...Ch. 21 - Both fusion and fission are nuclear reactions. Why...Ch. 21 - Cite the conditions necessary for a nuclear chain...Ch. 21 - Describe the components of a nuclear reactor.Ch. 21 - In usual practice, both a moderator and control...Ch. 21 - Describe how the potential energy of uranium is...Ch. 21 - The mass of a hydrogen atom (11H) is 1.007825 arm;...Ch. 21 - How can a radioactive nuclide be used to show that...Ch. 21 - Technetium-99m has a half-life of 6.01 hours. If a...Ch. 21 - Iodine that enters the body is stored in the...Ch. 21 - If a hospital were storing radioisotopes, what is...Ch. 21 - Based on what is known about Radon-222’s primary...Ch. 21 - Given specimens uranium-232 (t1/2=68.9y) and...Ch. 21 - A scientist is studying a 2.234 g sample of...Ch. 21 - Given specimens neon-24 (t1/2=3.38min) and...
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Similar questions
- Nonearrow_forwardPart II. Given below are the 'H-NMR spectrum at 300 MHz in CDC13 and mass spectrum using electron ionization of compound Brian. The FTIR of the said compound showed a strong peak at 1710 cm"). Determine the following: (a) molecular Formula and Degree of unsaturation of compound Brian (b) Basing on the given H-NMR spectrum tabulate the following (i) chemical shifts (ii) integration, ciii) multiplicity and (iv) interferences made for each signal (c) Draw the structure of compound Brian. ) ΕΙ 43 41 27 71 114 (M+) Hmmm 20 30 40 50 60 70 80 90 100 110 120 1H NMR spectrum 300 MHz in CDCl3 2.0 alle 1.0arrow_forwardThe iron-iron carbide phase diagram. In the diagram, the letter L indicates that it is a liquid. Indicate what its components are. Temperature (°C) 1600 10 Composition (at% C) 15 25 1538°C -1493°C 8 1400 1200 1394°C y+L L 2500 1147°C y. Austenite 2.14 4.30 2000 1000 912°C y + Fe3C 800ㅏ 0.76 0.022 600 a, Ferrite a + Fe3C 400 0 (Fe) Composition (wt% C) 727°C 1500 Cementite (Fe3C) 1000 6 6.70 Temperature (°F)arrow_forward
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