Chemistry by OpenStax (2015-05-04)
1st Edition
ISBN: 9781938168390
Author: Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher: OpenStax
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Textbook Question
Chapter 21, Problem 42E
A
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Complete the following table. The only density needed is already given. Show your
calculations in a neat and easy-to-follow manner in the space below the table. All units
should be included and significant figures should be given close attention. Be sure to notice
that the amount of material should be in millimoles rather than moles, and the theoretical
mass of the product should in milligrams rather than grams.
LOCH 3
+
H2SO4
HNO 3
O=C-OCH 3
NO2
x
H₂O
F.W.
4.0 mL 1.3 M
amount
0.50 mL
in H2SO4
mg Theoretical
Theoretical
mmoles
density
1.09
Kumada Coupling:
1. m-Diisobutylbenzene below could hypothetically be synthesized by Friedel-Crafts reaction. Write out the reaction with a
mechanism and give two reasons why you would NOT get the desired product.
Draw the reaction (NOT a mechanism) for a Kumada coupling to produce the molecule above from m-dichlorobenzene.
Calculate the theoretical yield for the reaction in question 2 using 1.5 g of p-dichlorobenzene and 3.0 mL isobutyl bromide.
What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Wintergreen from Aspirin:
1. In isolating the salicylic acid, why is it important to press out as much of the water as possible?
2. Write the mechanism of the esterification reaction you did.
3.
What characteristic absorption band changes would you expect in the IR spectrum on going from aspirin to salicyclic acid and
then to methyl salicylate as you did in the experiment today? Give approximate wavenumbers associated with each functional
group change.
What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Chapter 21 Solutions
Chemistry by OpenStax (2015-05-04)
Ch. 21 - Write the following isotopes in hyphenated form...Ch. 21 - Write the following isotopes in nuclide notation...Ch. 21 - For the following isotopes that have missing...Ch. 21 - For each of the isotopes in Exercise 21.1,...Ch. 21 - Write the nuclide notation, including charge if...Ch. 21 - Calculate the density of the M1224g nucleus in...Ch. 21 - What are the two principal differences between...Ch. 21 - The mass of the atom N1123a is 22.9893 arm.. (a)...Ch. 21 - Which of the following nuclei lie within the band...Ch. 21 - Which of the following nuclei lie within the band...
Ch. 21 - Write a brief description or definition of each of...Ch. 21 - Which of the various particles ( particles, ...Ch. 21 - Complete each of the following equations by adding...Ch. 21 - Complete each 0f the following equations: (a)...Ch. 21 - Write a balanced equation for each of the...Ch. 21 - Technetium-99 is prepared from 98Mo. Molybdenum-SS...Ch. 21 - The mass of the atom F919 is 18.99840 amu.. (a)...Ch. 21 - For the reaction C614N714+?, if 100.0 g of carbon...Ch. 21 - What are the types of radiation emitted by the...Ch. 21 - That changes occur to the atomic number and mass...Ch. 21 - What is the change in the nucleus that results...Ch. 21 - Many nuclides with atomic numbers greater than 83...Ch. 21 - Why is electron capture accompanied by the...Ch. 21 - Explain, in terms of Figure 21.2, how unstable...Ch. 21 - Which of the following nuclei is most likely to...Ch. 21 - The following nuclei do not lie in the band of...Ch. 21 - The following nuclei do not lie in the band of...Ch. 21 - Predict by what mode(s) of spontaneous radioactive...Ch. 21 - Write a nuclear reaction for each step in the...Ch. 21 - Write a nuclear reaction for each step in the...Ch. 21 - Define the term half-life and illustrate it with...Ch. 21 - A 1.00106 -g sample of nobelium, N102254o, has a...Ch. 21 - 239Pu is a nuclear waste byproduct with a...Ch. 21 - The isotope 208Tl undergoes decay with a...Ch. 21 - If 1.000 g of R88226a produces 0.0001 mL of the...Ch. 21 - The isotope S3890r one of the extremely hazardous...Ch. 21 - Technetium-99 is often used for assessing heart,...Ch. 21 - What is the age of mummified primate skin that...Ch. 21 - A sample of rock was found to contain 8.23 mg of...Ch. 21 - A laboratory investigation shows that a sample of...Ch. 21 - Plutonium was detected in trace amounts in natural...Ch. 21 - A B47e atom (mass = 7.0169 amu) decays into a L37i...Ch. 21 - A B58 atom (mass = 8.0246 amu) decays into B48...Ch. 21 - Isotopes such as 26Al (half-life: 7.2105 years)...Ch. 21 - Write a balanced equation for each of the...Ch. 21 - Write a balanced equation for each of the...Ch. 21 - Write the balanced nuclear equation for the...Ch. 21 - How does nuclear fission differ from nuclear...Ch. 21 - Both fusion and fission are nuclear reactions. Why...Ch. 21 - Cite the conditions necessary for a nuclear chain...Ch. 21 - Describe the components of a nuclear reactor.Ch. 21 - In usual practice, both a moderator and control...Ch. 21 - Describe how the potential energy of uranium is...Ch. 21 - The mass of a hydrogen atom (11H) is 1.007825 arm;...Ch. 21 - How can a radioactive nuclide be used to show that...Ch. 21 - Technetium-99m has a half-life of 6.01 hours. If a...Ch. 21 - Iodine that enters the body is stored in the...Ch. 21 - If a hospital were storing radioisotopes, what is...Ch. 21 - Based on what is known about Radon-222’s primary...Ch. 21 - Given specimens uranium-232 (t1/2=68.9y) and...Ch. 21 - A scientist is studying a 2.234 g sample of...Ch. 21 - Given specimens neon-24 (t1/2=3.38min) and...
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Similar questions
- Synthesis of ZybanⓇ: 1. Write a mechanism for the bromination of m-chloropropiophenone. Br₂ CH2Cl2 Cl Br 2. Give the expected m/z (to a round number) for the molecular ion from the product above (including isotopic peaks). 3. What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What other impurities are present in your product and how do you know?arrow_forwardSynthesis of Ibuprofen-Part 2: 1. Some pain relievers including ibuprofen (MotrinⓇ) and naproxen (Aleve®) are "α-arylpropanoic acids." Look up the structure of naproxen (AleveⓇ), another a-arylpropionic acid. Using the same reactions that we used for making ibuprofen, show how to make naproxen from the compound below. Show all intermediates and reagents in your synthesis. Show how you would prepare ibuprofen starting from p-isobutylbenzene rather than p-isobutylacetophenenone. What reaction steps would need to change/add? 3. What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What other impurities are present in your product and how do you know?arrow_forwardAcid Catalyzed Aromatization of Carvone: 1. Starting with the ketone, below, draw a mechanism for the reaction to give the phenol as shown. H2SO4 HO- H₂O 2. Why do we use CDCl instead of CHCl, for acquiring our NMR spectra? 3. Why does it not matter which enantiomer of carvone is used for this reaction? What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What other impurities are present in your product and how do you know?arrow_forward
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