Chemistry the Central Science 13th Edition Custom for Lamar University
13th Edition
ISBN: 9781269962667
Author: Theodore L. Brown, H. Eugene LeMay Jr., Bruce E. Bursten, Batherine J. Murphy, Patrick M. Woodward, Matthew W. Stoltzfus
Publisher: Pearson Learning Center
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Chapter 21, Problem 5E
Interpretation Introduction
To determine: The molar mass of adrenaline in the given solution.
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Using the bond energy values, calculate the energy that must be supplied or is released upon the polymerization of 755 monomers. If energy must be supplied, provide a positive number; if energy is released, provide a negative number. Hint: Avogadro’s number is 6.02 × 1023.
-AG|F=2E|V
3. Before proceeding with this problem you may want to glance at p. 466 of your textbook
where various oxo-phosphorus derivatives and their oxidation states are summarized.
Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14:
Acidic solution
-0.93
+0.38
-0.51 -0.06
H3PO4 →H4P206 H3PO3 H3PO2 → P→ PH3
-0.28
-0.50
→
-0.50
Basic solution
3-1.12
-1.57
-2.05 -0.89
PO HPO →→H2PO2 P PH3
-1.73
a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the
formation and reduction of H4P2O6 (-0.93/+0.38V). Calculate the values of AG's for both
processes; comment.
(3 points)
0.5 PH,
0.0
-0.5-
2 3 9 3
-1.5
-2.0
Pa
H,PO
H,PO
H,PO
-3
-1 0
2
4
Oxidation state, N
2
b) Frost diagram for phosphorus under acidic
conditions is shown. Identify possible
disproportionation and comproportionation processes;
write out chemical equations describing them. (2 points)
c) Elemental phosphorus tends to disproportionate under basic conditions. Use data in…
These two reactions appear to start with the same starting materials but result in different products. How do the chemicals know which product to form? Are both products formed, or is there some information missing that will direct them a particular way?
Chapter 21 Solutions
Chemistry the Central Science 13th Edition Custom for Lamar University
Ch. 21.1 - Prob. 21.1.1PECh. 21.1 - Prob. 21.1.2PECh. 21.1 - Prob. 21.2.1PECh. 21.1 - Prob. 21.2.2PECh. 21.2 - Which aqueous solution will have the lowest...Ch. 21.2 - Prob. 21.3.2PECh. 21.3 - Prob. 21.4.1PECh. 21.3 - Prob. 21.4.2PECh. 21.4 - Prob. 21.5.1PECh. 21.4 - Practice Exercise 2
Camphor (C10 H16 O) melts at...
Ch. 21.4 - Prob. 21.6.1PECh. 21.4 - Prob. 21.6.2PECh. 21.4 - Prob. 21.7.1PECh. 21.4 - Rank the contents of the following containers in...Ch. 21.6 - Prob. 21.8.1PECh. 21.6 - Consider two ionic solids, both composed of singly...Ch. 21 - Prob. 1DECh. 21 - Would you expect stearic acid, CH3 (CH2)16COOH, to...Ch. 21 - 13.43 Calculate the morality of the following...Ch. 21 - Commercial aqueous nitric acid has a density of...Ch. 21 - Prob. 4ECh. 21 - Prob. 5ECh. 21 - Prob. 6ECh. 21 - Prob. 7ECh. 21 - If the experiment in Figure 14.2 is run for 60 s,...Ch. 21 - Prob. 9ECh. 21 - Indicate the principal type of solute-solvent...Ch. 21 - When ammonium chloride dissolves in water, the...Ch. 21 - Prob. 12ECh. 21 - KBr is relatively soluble in water, yet its...Ch. 21 - The solubility of MnSO4 . H2 O in water at 20 C is...Ch. 21 - Prob. 15ECh. 21 - Prob. 16ECh. 21 - Prob. 17ECh. 21 - Prob. 18ECh. 21 - Prob. 19ECh. 21 - Prob. 20ECh. 21 - Prob. 21ECh. 21 - Indicate whether each statement is true or false:...Ch. 21 - 13.36 Indicate whether each statement is true or...Ch. 21 - Prob. 24ECh. 21 - Prob. 25ECh. 21 - Prob. 26ECh. 21 - Prob. 27ECh. 21 - Prob. 28ECh. 21 - Prob. 29ECh. 21 - Calculate the molality of each of the following...Ch. 21 - (a) What is the molality of a solution formed by...Ch. 21 - Prob. 32ECh. 21 - Prob. 33ECh. 21 - Prob. 34ECh. 21 - The density of toluene (C7H8) is 0.867 g\mL, and...Ch. 21 - Calculate the number of moles of solute present in...Ch. 21 - Prob. 37ECh. 21 - Prob. 38ECh. 21 - Describe how you would prepare each of the...Ch. 21 - Prob. 40ECh. 21 - Prob. 41ECh. 21 - Prob. 42ECh. 21 - Prob. 43ECh. 21 - Prob. 44ECh. 21 - Prob. 45ECh. 21 - Prob. 46ECh. 21 - Prob. 47ECh. 21 - Prob. 48ECh. 21 - (a) Calculate the vapor pressure of water above a...Ch. 21 - Prob. 50ECh. 21 - Prob. 51ECh. 21 - Prob. 52ECh. 21 - Prob. 53ECh. 21 - Using data from Table 13.3, calculate the freezing...Ch. 21 - Prob. 55ECh. 21 - Prob. 56ECh. 21 - Prob. 57ECh. 21 - Prob. 58ECh. 21 - Prob. 59ECh. 21 - Prob. 60ECh. 21 - Prob. 61ECh. 21 - The osmotic pressure of a 0.010 M aqueous solution...Ch. 21 - Prob. 63ECh. 21 - (a) Do colloids made only of gases exist? Why or...Ch. 21 - Prob. 65ECh. 21 - An “emulsifying agent” is a compound that helps...Ch. 21 - Aerosols are important components of the...Ch. 21 - Prob. 68ECh. 21 - Soaps consist of compounds such as sodium state,...Ch. 21 - Most fish need at least 4 ppm dissolved O2 in...Ch. 21 - The presence of the radioactive gas radon (Rn) in...Ch. 21 - Prob. 72AECh. 21 - Prob. 73AECh. 21 - The maximum allowable concentration of lead in...Ch. 21 - Prob. 75AECh. 21 - Prob. 76AECh. 21 - Prob. 77AECh. 21 - Prob. 78AECh. 21 - The normal boiling point of ethanol, is 78.4 0C....Ch. 21 - Prob. 80AECh. 21 - Prob. 81AECh. 21 - Prob. 82AECh. 21 - Prob. 83AECh. 21 - Prob. 84AECh. 21 - Prob. 85AECh. 21 - Prob. 86AECh. 21 - Prob. 87AECh. 21 - Prob. 88AECh. 21 - Prob. 89IECh. 21 - Prob. 90IECh. 21 - Prob. 91IECh. 21 - Prob. 92IECh. 21 - Prob. 93IECh. 21 - Prob. 94IE
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- Iarrow_forwardDraw the anti-Markovnikov product of the hydration of this alkene. this problem. Note for advanced students: draw only one product, and don't worry about showing any stereochemistry. Drawing dash and wedge bonds has been disabled for esc esc ☐ Explanation Check F1 1 2 F2 # 3 F3 + $ 14 × 1. BH THE BH3 2. H O NaOH '2 2' Click and drag to start drawing a structure. F4 Q W E R A S D % 905 LL F5 F6 F7 © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Accessibility < & 6 7 27 8 T Y U G H I F8 F9 F10 F11 F12 9 0 J K L P + // command option Z X C V B N M H H rol option commandarrow_forwardAG/F-2° V 3. Before proceeding with this problem you may want to glance at p. 466 of your textbook where various oxo-phosphorus derivatives and their oxidation states are summarized. Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14: -0.93 +0.38 -0.50 -0.51 -0.06 H3PO4 →H4P206 →H3PO3 →→H3PO₂ → P → PH3 Acidic solution Basic solution -0.28 -0.50 3--1.12 -1.57 -2.05 -0.89 PO HPO H₂PO₂ →P → PH3 -1.73 a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the formation and reduction of H4P206 (-0.93/+0.38V). Calculate the values of AG's for both processes; comment. (3 points) 0.5 PH P 0.0 -0.5 -1.0- -1.5- -2.0 H.PO, -2.3+ -3 -2 -1 1 2 3 2 H,PO, b) Frost diagram for phosphorus under acidic conditions is shown. Identify possible disproportionation and comproportionation processes; write out chemical equations describing them. (2 points) H,PO 4 S Oxidation stale, Narrow_forward
- 4. For the following complexes, draw the structures and give a d-electron count of the metal: a) Tris(acetylacetonato)iron(III) b) Hexabromoplatinate(2-) c) Potassium diamminetetrabromocobaltate(III) (6 points)arrow_forward2. Calculate the overall formation constant for [Fe(CN)6]³, given that the overall formation constant for [Fe(CN)6] 4 is ~1032, and that: Fe3+ (aq) + e = Fe²+ (aq) E° = +0.77 V [Fe(CN)6]³ (aq) + e¯ = [Fe(CN)6] (aq) E° = +0.36 V (4 points)arrow_forward5. Consider the compounds shown below as ligands in coordination chemistry and identify their denticity; comment on their ability to form chelate complexes. (6 points) N N A B N N N IN N Carrow_forward
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY