EBK INTRODUCTORY CHEMISTRY: AN ACTIVE L
6th Edition
ISBN: 9780100547506
Author: CRACOLICE
Publisher: YUZU
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Chapter 21, Problem 52E
Interpretation Introduction
Interpretation:
The skeletal formula of all the possible dichloro substitution product of butane is to be drawn and their IUPAC name is to be determined.
Concept introduction:
Structural isomers are the compounds which have the same molecular formula but different structure. In structural isomers, the arrangement of atoms is different.
Steps to determine the IUPAC name of a compound are:
Step 1: Identify the longest continuous carbon chain and number the carbon atoms such that the substituents attached to the parent chain get the lowest possible number.
Step 2: Identify the carbon number to which the substituent is attached.
Step 3: Identify the substituent or branched group attached to the parent chain.
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13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the
molecule depicted below.
Bond B
2°C. +2°C. cleavage
Bond A
•CH3 + 26.← Cleavage
2°C. +
Bond C
+3°C•
CH3 2C
Cleavage
E
2°C. 26.
weakest bond
Intact molecule
Strongest 3°C 20.
Gund
Largest
argest
a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in
appropriate boxes.
C
Weakest
bond
A
Produces
Most
Bond
Strongest
Bond
Strongest Gund
produces least stable
radicals
Weakest
Stable radical
b. (4pts) Consider the relative stability of all cleavage products that form when bonds A,
B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B,
and C are all carbon radicals.
i. Which ONE cleavage product is the most stable? A condensed or bond line
representation is fine.
13°C. formed in
bound C
cleavage
ii. Which ONE cleavage product is the least stable? A condensed or bond line
representation is fine.
• CH3
methyl radical
Formed in Gund A Cleavage
c.…
Br.
COOH Br,
FCH COOH E
FeBr
ASOCI
B
NH
(CH,CO),OD Br₂
2
C
alcKOH
Find A to F (all)
Chapter 21 Solutions
EBK INTRODUCTORY CHEMISTRY: AN ACTIVE L
Ch. 21 - Prob. 1ECh. 21 - Prob. 2ECh. 21 - Prob. 3ECh. 21 - Prob. 4ECh. 21 - Prob. 5ECh. 21 - Prob. 6ECh. 21 - Prob. 7ECh. 21 - Prob. 8ECh. 21 - Prob. 9ECh. 21 - Prob. 10E
Ch. 21 - Prob. 11ECh. 21 - Prob. 12ECh. 21 - Prob. 13ECh. 21 - Prob. 14ECh. 21 - Prob. 15ECh. 21 - Prob. 16ECh. 21 - Prob. 17ECh. 21 - Prob. 18ECh. 21 - Prob. 19ECh. 21 - Prob. 20ECh. 21 - Prob. 21ECh. 21 - Prob. 22ECh. 21 - Is the general formula of a cycloalkanes the same...Ch. 21 - Prob. 24ECh. 21 - Draw the skeleton diagram of cyclopentane.Ch. 21 - Prob. 26ECh. 21 - Prob. 27ECh. 21 - Prob. 28ECh. 21 - Prob. 29ECh. 21 - Prob. 30ECh. 21 - Prob. 31ECh. 21 - Prob. 32ECh. 21 - Prob. 33ECh. 21 - Prob. 34ECh. 21 - Prob. 35ECh. 21 - Prob. 36ECh. 21 - What is the difference in bonding and in the...Ch. 21 - Prob. 38ECh. 21 - Draw the structural formula of trichloroethene, a...Ch. 21 - Prob. 40ECh. 21 - Prob. 41ECh. 21 - Prob. 42ECh. 21 - Prob. 43ECh. 21 - Prob. 44ECh. 21 - Give the IUPAC name of the following molecule:Ch. 21 - Give the IUPAC name of the following molecule:Ch. 21 - Prob. 47ECh. 21 - Prob. 48ECh. 21 - Prob. 49ECh. 21 - Prob. 50ECh. 21 - Prob. 51ECh. 21 - Prob. 52ECh. 21 - Prob. 53ECh. 21 - Prob. 54ECh. 21 - Write an equation for the hydrogenation of...Ch. 21 - Prob. 56ECh. 21 - Prob. 57ECh. 21 - Prob. 58ECh. 21 - Prob. 59ECh. 21 - Explain why the ether with formula C2H6O is very...Ch. 21 - Prob. 61ECh. 21 - Prob. 62ECh. 21 - Prob. 63ECh. 21 - Prob. 64ECh. 21 - Prob. 65ECh. 21 - Prob. 66ECh. 21 - Prob. 67ECh. 21 - Prob. 68ECh. 21 - Prob. 69ECh. 21 - Prob. 70ECh. 21 - Prob. 71ECh. 21 - Prob. 72ECh. 21 - Prob. 73ECh. 21 - Prob. 74ECh. 21 - Prob. 75ECh. 21 - Prob. 76ECh. 21 - Prob. 77ECh. 21 - Prob. 78ECh. 21 - Prob. 79ECh. 21 - Prob. 80ECh. 21 - Prob. 81ECh. 21 - Prob. 82ECh. 21 - Prob. 83ECh. 21 - Prob. 84ECh. 21 - Prob. 85ECh. 21 - Prob. 86ECh. 21 - Prob. 87ECh. 21 - Prob. 88ECh. 21 - Prob. 89ECh. 21 - Prob. 90ECh. 21 - Prob. 91ECh. 21 - Prob. 92ECh. 21 - Prob. 93ECh. 21 - Prob. 94ECh. 21 - Distinguish precisely, and in scientific terms,...Ch. 21 - Prob. 96ECh. 21 - What is the difference in bonding and in general...Ch. 21 - Draw all isomers of C4H8.Ch. 21 - Prob. 99ECh. 21 - Prob. 100ECh. 21 - Prob. 101ECh. 21 - Prob. 102ECh. 21 - Prob. 103ECh. 21 - Prob. 104ECh. 21 - Prob. 105ECh. 21 - Prob. 106ECh. 21 - Prob. 107ECh. 21 - Prob. 21.1TCCh. 21 - Prob. 21.2TCCh. 21 - Prob. 21.3TCCh. 21 - Prob. 21.4TCCh. 21 - Prob. 21.5TCCh. 21 - Prob. 21.6TCCh. 21 - Prob. 21.7TCCh. 21 - Prob. 21.8TCCh. 21 - Prob. 21.9TCCh. 21 - Prob. 21.10TCCh. 21 - Prob. 21.11TCCh. 21 - Prob. 21.12TCCh. 21 - Prob. 1CLECh. 21 - Prob. 2CLECh. 21 - Prob. 3CLECh. 21 - Prob. 4CLECh. 21 - Prob. 5CLECh. 21 - Prob. 6CLECh. 21 - Prob. 7CLECh. 21 - Prob. 8CLECh. 21 - Prob. 9CLECh. 21 - Prob. 10CLE
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